• Title/Summary/Keyword: UV-Blocking

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The Synthesis of Nano-sphere Titanium-oxide and Cosmetic Applications (광반사체로 사용되는 $TiO_2$ 나노구형체의 합성과 화장품으로의 적용 연구)

  • Lee, Ji Hye;Kim, Joon Woo;Kim, Ji Man;Choung, Suk-Jin
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.231-238
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    • 2013
  • In this study, the $TiO_2$ nano spheres were synthesized by Sol-gel method to give an excellent UV-blocking effect and increase waste adsorption. The pH value was adjusted to obtain a superb UV-blocking effect and adsorption capacity due to the high surface area which is the characteristics of porosity. Base treated $TiO_2$ showed outstanding characteristics. The adsorption of gycerine onto the $TiO_2$ sample using TGA resulted in a high surface area of 1.16 mg/mg. This also showed a high reflectance in the UV-A region. In order to find the optimum dispersion, inorganic powder particles were maintained their sizes as 180 nm for about 6 months. The size of particles were measured using ester oil and silicon oil. Overall, the results reveal that $TiO_2$ has an excellent capability sunscreen in the UV-A region and skin waste adsorption.

Preparation and Analysis of Functional Hydrogel Lenses Using Cerium Iron Hydroxide Nanoparticles

  • Shin, Su-Mi;Sung, A-Young
    • Journal of Integrative Natural Science
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    • v.13 no.1
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    • pp.13-18
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    • 2020
  • This study used cerium iron hydroxide nanoparticle with HEMA (2-hydroxyethyl methacrylate), the cross-linker EGDMA (ethylene glycol dimethacrylate), NVP (N-vinyl-2-pyrrolidone) and the initiator AIBN (azobisisobutyronitrile) for copolymerization. Also, the physical properties of the prepared lenses were compared, and their applicability as polymers for ophthalmic materials was experimented. The results of the measurement showed that the UV blocking rate and the wettability increased with the cerium iron hydroxide nanoparticles addition ratio, and the refractive index and water content were not affected. Thus, the produced copolymer is expected to be useful as a functional contact lens material while satisfying the basic physical properties of the hydrogel contact lens.

A Study on Blue Light Blocking Performance and Prescription for Blue Light Blocking Lens (청광차단렌즈의 청광차단성능과 처방에 관한 고찰)

  • Yu, Young Guk;Choi, Eun Jung
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.3
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    • pp.297-304
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    • 2013
  • Purpose: To investigate blue light rejection and the percentage of blue light in the visible light of blue light blocking lens according to light source, and to study prescriptions for blue light blocking lens Methods: UV-VIS spectrophotometer was used for blue light rejection and the percentage of blue light in the visible light according to light source, and the percentage of blue light in solar light was used to evaluate the prescription for blue light blocking lens. Results: The blue light rejection and the percentage of blue light in the visible light of each lens were depending on light sources. Through the way to compare the percentages of blue light in the visible light passing through the lens with that in solar light, blue light blocking lenses suitable to each light source could been selected. Conclusions: In the prescription for blue light blocking lens, inquiry for user's display must be preceded. And then the percentages of blue light in the visible light passing through the lens based on that in solar light may be useful as a method of evaluating the prescription for blue light blocking lens.

Properties of Working Electrodes with Diamond Blends in Dye Sensitized Solar Cells

  • Choi, Minkyoung;Noh, Yunyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.384-388
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    • 2015
  • We prepared blocking layers by adding 0.0 ~ 0.6 wt% nano diamond blends (DBs) to $TiO_2$ blocking layers to improve the energy conversion efficiencies (ECEs) of dye sensitized solar cells (DSSCs). TEM and micro-Raman spectroscopy were used to characterize the microstructure and phases of DBs, respectively. Optical microscopy and FE-SEM were used to analyze the microstructure of the $TiO_2$ blocking layer with DBs. UV-VIS-NIR spectroscopy was used to determine the absorbance of the working electrodes. A solar simulator and a potentiostat were used to determine the photovoltaic properties and the impedance of the DSSCs with DBs. From the results of the DBs analysis, we determined a 6.97 nm combination of nano diamonds and graphite. We confirmed that ECE increased from 5.64 to 6.48 % when the added DBs increased from 0.0 to 0.2 wt%. This indicates that the effective surface area and electron mobility increased when DBs were added to the $TiO_2$ blocking layer. Our results indicate that the ECE of DSSCs can be enhanced by adding an appropriate amount of DBs to the $TiO_2$ blocking layers.

Dyeability of Silk Fabrics Using Extracts of Ligustrum Japonicum Thunb Fruit (광나무 열매 추출물을 이용한 견직물의 염색성)

  • Lee, Hye-Sun;Ko, Sung-Mi
    • Textile Coloration and Finishing
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    • v.22 no.1
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    • pp.71-76
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    • 2010
  • In this study the optimum dyeing conditions and blocking effect of UV deodorization efficiency of Ligustrum japonicum Thunb were investigated. Colorants were water-extracted from Ligustrum japonicum Thunb fruit and freeze-drided to obtain colorants powder. The effects of dye concentration, dyeing temperature, dyeing time, and the number of dipping count were studied. Fastness to dry cleaning, rubbing, perspiration, and light were measured according to KS K 0644, KS K 0650, KS K 0715 and KS K 0700, respectively. In order to examine the dyeability according to dyeing conditions, reflectance of fabrics were measured by using UV/VIS spectrophotometer. The bath ratio was 1:20. Dyeing concentration was 100, 200, 300, 400 and 500% on the weight of fiber. Dyeing time was 20, 40, 60, and 80 minutes. Dyeing temperature was 20, 40, 60, 80, and $100^{\circ}C$. The infrared high pressure dying machine was used. As dyeing concentration increased, dye adsorption increased up to 400% and it slowed down. Dye uptake was increased with raising themperature up to $80^{\circ}C$ and it slowed down. Dye adsorption occurred rapidly at first 20 minutes and then it slowed down and reached almost maximum dye uptake at 60 min. Dye uptake increased by repeated dyeing. Therefore, it is considered that optimum dyeing condition is 400%(o.w.f.), $80^{\circ}C$, 60 min. And repeated dyeing improves dye uptake. Color fastness to dry cleaning and rubbing was good, but light fastness and perspiration fastness was not good. Blocking effect of ultraviolet radiation and deodorization efficiency was good.

Study on Ophthalmic Materials Possessing UV-Blocking/Antimicrobial Functions (자외선 차단 기능을 가진 항균성 안 의료용 소재에 관한 연구)

  • Ye, Ki-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.54 no.4
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    • pp.460-464
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    • 2010
  • We manufactured functional contact lens materials using 2-hydroxy-4-methoxy-benzophenone, titanium(VI) isopropoxide and nanogold, nanoplatinum with UV-blocking and antimicrobial effects. Contact lens was manufactured by cast mould method. The resulting mixture was copolymerized by heating at $70^{\circ}C$ for about 40 min, at $80^{\circ}C$ for about 40 min, and finally at $100^{\circ}C$ for about 40 min. The refractive index of 1.434 ~ 1.436, water content of 35.24 ~ 36.32%, and visible transmittance of 88.3 ~ 90.8% were obtained for the contact lens materials. The polymer materials satisfied the physical properties required to make the material suitable to be applied as a functional material for ophthalmological purposes.

Effects of Package Materials on Quality Change of Pine Bud Beverage Under Ultraviolet Light

  • An, Duek-Jun
    • Preventive Nutrition and Food Science
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    • v.14 no.4
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    • pp.349-353
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    • 2009
  • The effects of packaging materials on preserving the functional component of pine bud beverage stored under UV (ultraviolet) light exposure conditions were studied. The order of UV light blocking properties of the selected packages was: opaque can> opaque PET (polyethylene terepthalate) with green lamination=transparent PET with 10% PEN (polyethylene naphthalate) blending> transparent PET, and did not depend on film thickness in specified range. At 20${^{\circ}C}$, the order of preserving degree of original color and endobornyl acetate, which is quality index of pine bud beverage, was the same as above. Exposure to UV light can cause of deterioration of functional food components, but green color lamination and blending of PEN materials with transparent PET help to preserve the UV sensitive pine bud beverage components. However, the treated PET bottles have poorer preservation capabilities than the opaque cans. Transparent PET with PEN blending, in particular, will be very useful packaging material for colorful functional beverage preservation by helping to protect the ingredients while attracting consumer attention.

Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Properties of Dye Sensitized Solar Cells with Adding Nano Carbon Black into Blocking Layer

  • Kim, Kwangbae;Noh, Yunyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.294-298
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    • 2015
  • Blocking layers with nano carbon blacks (NCBs) were prepared by adding 0.0 ~ 0.5 wt% NCBs to the $TiO_2$ blocking layer. Then, dye sensitized solar cells (DSSCs) were fabricated with a $0.45cm^2$ active area. TEM and micro-Raman spectroscopy were used to characterize the microstructure and phases of the NCBs, respectively. Optical microscopy and AFM were used to analyze the microstructure of the $TiO_2$ blocking layer with NCBs. UV-VIS-NIS spectroscopy was used to determine the band gap of the $TiO_2$ blocking layer with NCBs. A solar simulator and potentiostat were used to determine the photovoltaic properties and impedance of DSSCs with NCBs. The energy conversion efficiency (ECE) increased from 3.53 to 6.20 % when the NCB content increased from 0.0 to 0.3 wt%. This indicates that the effective surface area and electron mobility increased in the $TiO_2$ blocking layer with NCBs. However, the ECE decreased when the NCB content was increased to over 0.4 wt%. This change occurred because the effective electron transport area decreased with the addition of excessive NCBs to the $TiO_2$ blocking layer. The results of this study suggest that the ECE of DSSCs can be enhanced by adding the appropriate amount of NCBs to the $TiO_2$ blocking layer.

Convergence study of blue light transmittance comparison between tips for light curing machine and commercially available blue light blocking lenses and yellow tinted lenses (광중합기용 팁과 시판용 청광 차단 렌즈 및 노란색 착색 렌즈의 청광 투과율 비교 융합 연구)

  • Lee, Sook-Jeong
    • Journal of the Korea Convergence Society
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    • v.12 no.7
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    • pp.125-131
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    • 2021
  • Blue light with strong energy is required for light-curing resin treatment, which is being used more frequently in dentistry. To reduce the risk of exposure to scattered light, we tried to use colored lenses. The tips for light curing machine and a commercially available yellow-type blue-light blocking lens and a yellow lens colored with yellow dye, which are expected to be effective in blocking blue light, were placed in a UV-Vis spectrometer device, and transmission and blocking of blue light were tested respectively. As a result, the average blue light blocking rate of the light curing machine tips was 99.49%, and the C lens with the highest color density among commercially available lenses showed a high blue light blocking rate of 99.54%. In the case of lenses tinted with yellow, the yellow tinted C lens with the highest tint concentration showed 87.57% of blue light blocking rate. It is judged that the side effects related to the eyes caused by blue light can be reduced if a yellow-type commercially available or colored lens is worn along with a light curing machine tip during resin treatment.