• Title/Summary/Keyword: UV stability

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Study on thermal and UV stability of Liquid Crystal Display for Projection TV Application (프로젝션 TV 적용을 위한 액정 디스플레이의 열적 및 UV 안전성에 관한 연구)

  • Choi, Sung-Ho;Hwang, Jeoung-Yeon;Bae, Yu-Han;Lee, Whee-Won;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.287-288
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    • 2005
  • In this study, we have investigated electro-optical characteristics of thermal and UV stressed TN cells on the rubbed polyimide surface. Mono-domain alignments of thermal stressed TN cells over temperature of liquid crystal isotropic phase were almost same that of no thermal stressed TN cells. Also, threshold voltage and response time of thermal stressed TN cells were same that of no thermal stressed TN cells. Finally, the residual DC voltage of the thermal stressed TN cell on the polyimide surface show decrease of characteristics as increasing thermal stress time. Therefore, thermal stability of TN cell was decreased by high thermal stress for the long times.

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Study on characteristics of liquid crystal alignment on photosensitive polyimide having thermal stability (고내열성을 가진 감광성 폴리이미드의 액정배향 특성에 관한 연구)

  • Lee, Sang-Min;Hwan, Jeoung-Yeon;Nam, Ki-Hyung;Seo, Dae-Shik;Suh, Dong-Hack
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.502-505
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    • 2003
  • We synthesized high thermal photoalignment material with hydroxyl aromatic polyimide, and studied the liquid crystal (LC) aligning capabilities on the photopolymer layers. Also, electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photoaligned with linearly polarized UV exposure were investigated. A good LC alignment with UV exposure on the photopolymer surface can be obtained. However, the low pretilt angles were obtained below $1^{\circ}$. The Voltage-transmittance (V-T) curve without backflow bounce in the photoaligned TN cell with UV exposure was observed. The response time of photoaligned TN cell was measured about 24 ms.

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A Study of Functionality and Stability of LDPE-Nano TiO2 Composite Film (LDPE-나노 TiO2 복합 필름의 기능성 및 재질안정성 평가)

  • Lee, Wooseok;Ko, Seonghyuk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.2
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    • pp.67-74
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    • 2017
  • In this work, the effects of nano $TiO_2$ on functionality and stability of low density polyethylene (LDPE) composite films were investigated for food packaging application. LDPE-nano $TiO_2$ composite films were prepared with various $TiO_2$ contents (0, 0.5, 1.0, 3.0 and 5.0wt%) by melt-extrusion and their basic properties such as crystallinity, chemical bonds and surface morphology were examined by XRD, FTIR and SEM. Ultraviolet (UV) light barrier property of as-prepared LDPE-nano $TiO_2$ composite films was also studied and the presence of nano $TiO_2$ resulted in significant improvement of UV light barrier compared to the pure LDPE film. To evaluate influence of nano $TiO_2$ on LDPE properties required as packaging material, thermal, mechanical, gas barrier and optical properties of LDPE-nano $TiO_2$ composite films were characterized with various analytical techniques including TGA, UTM, OTR, WVTR and UV-vis spectroscopy. As a result, except optical property of LDPE, no significant effects were found in other properties. Opacity of pure LDPE was greatly increased with increasing concentration of nano $TiO_2$.

The effect and stability of Retinyl Palmitate(RP) in W/O, W/S, O/W, MLV(Multilamellar Vesicles) cream (W/O, W/S, O/W, MLV(Multilamellar Vesicles) TYPE에서 Retinyl Palmitate(RP)의 열적 안정성과 효능, 효과에 관한 연구)

  • 지홍근;서봉석
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.1
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    • pp.40-59
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    • 1996
  • Retinyl Palmitate, the skin normalzer, is useful to promote greater skin elasticity, to diminish lipid peroxidation and skin roughness following UV exposure, and promote a youthfull general skin appearance. We knew that the reduction of retinyl palmitate in W/O, W/S, O/W, MLV cream was caused by variable compound factors. Among the retinoids, we chose retinyl palmitate and studied the stability behavior of retinyl palmitate is liposomed. Furthermore, HPLC, CHROMA METERS, LASER SIGHT SCATTERING SYSTEM and FREEZE FRACTURE SCANNING ELECTROM MICROSCOPY was used to analyzing the stability and efficacy of UV and heat.

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Improved Thermal Stability of PET Fabrics by Photografting of Methacryloxypropyltrimethoxysilane(MAPTMS) (Methacryloxypropyltrimethoxysilane(MAPTMS)의 광그라프트에 의한 PET직물의 열적 안정성 향상)

  • Jang, Jin-Ho;Son, Jung-A
    • Textile Coloration and Finishing
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    • v.20 no.4
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    • pp.1-7
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    • 2008
  • Methacryloxypropyl trimethoxysilane (MAPTMS), a hybrid organic-inorganic monomer, was photografted onto PET fabric using benzophenone (BP) as a photoinitiator. It was found that a UV energy of 43.2J/$cm^2$ was required to optimally photograft the MAPTMS onto PET fabrics which was applied with an aqueous formulation of 10% MAPTMS, 20% BP and 0.5% N-Methyldiethanol amine (MDEA). The MDEA additive was efficient in reducing atmospheric oxygen inhibition of polymer radicals which eliminated compulsory nitrogen inerting. The surface grafting of PET fabrics was verified by fourier transform infrared spectroscopy (FT-IR) and scanning electron spectroscopy (SEM). The grafted PET fabrics with the hybrid monomer showed higher thermal stability due to the introduced silane component in the monomer as ascertained by higher char content at 800$^{\circ}C$, which increased to 14.5% for the 15.8% grafting compared to 8.2% for the untreated.

Pretilt Angel Generation and Alignment Stability for Nematic Liquid Crystal Using a Photodimerization Method (광중합법을 이용한 네마틱액정의 배향 안정성 및 프리틸트각의 발생)

  • 황정연;서대식;김재형;한은주
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.4
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    • pp.336-340
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    • 2001
  • We have investigated the generation of pretilt angle and alignment stability for a nematic liquid crystal (NLC) with obliquely polarized UV exposure on the three kinds of photo-polymer. High pretilt angle of the NLC was obtained by polarized UV exposure on a PM4Ch surface for 1 min. But, the low pretilt angle of he NLC on a PVCi surface was observed. The pretilt angle generated is attributed ot the photosensitivity by the long side chaining of photo-polymer. Also, a good thermal stability of the three kinds of photo-polymer were obtained by thermogravimetric analysis (TGA) measurement until 300$^{\circ}C$. Finally, the good LC aligning capabilities using the photodimerization method were observed by annealing-treatment until 150$^{\circ}C$.

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Dose-dependent UV Stabilization of p53 in Cultured Human Cells Undergoing Apoptosis Is Mediated by Poly(ADP-ribosyl)ation

  • Won, Jungyeon;Chung, So Young;Kim, Seung Beom;Byun, Boo Hyeong;Yoon, Yoo Sik;Joe, Cheol O.
    • Molecules and Cells
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    • v.21 no.2
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    • pp.218-223
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    • 2006
  • The effect of poly(ADP-ribosyl)ation on the stability of p53 in SK-HEP1 cells treated with UV light was examined. Intracellular levels of p53 increased in cells treated with a low dose of UV light ($20J/m^2$), whereas they increased but then declined after a higher dose of UV ($100J/m^2$). Intracellular levels of p53 in the UV treated SK-HEP1 cells were dependent on the UV dose. Use of proteasome inhibitors revealed that p53 is degraded by proteasomal proteolysis after high doses of UV light. We present evidence that, at low doses, poly(ADP-ribose)polymerase (PARP) poly(ADP-ribosyl) ates p53 and protects it from proteasomal degradation before caspase-3 is activated, whereas at high doses the cells undergo UV induced apoptosis and PARP is cleaved by caspase-3 before it can protect p53 from degradation. Destabilization of p53 by cleavage of PARP may be important in cell fate decision favoring apoptosis.

Oxidative Stability and Antioxidant Changes in Perilla Seeds and Perilla Oil Affected by UV Irradiation (들깨 및 들기름의 자외선 조사 중 지방질 산화와 산화방지제의 변화)

  • Wang, Seon-Yeong;Choe, Eun-Ok
    • Korean Journal of Food Science and Technology
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    • v.44 no.1
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    • pp.8-13
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    • 2012
  • Effects of UV irradiation on lipid oxidation in perilla seeds and perilla oil were evaluated by determining the contents of peroxides, conjugated dienoic acids, and thiobarbituric acid reactive substances, and analyzing fatty acid composition. Tocopherols and polyphenol contents were also determined. Perilla seeds were unroasted or roasted at $180^{\circ}C$ for 20 min, and perilla oil was obtained by pressing the roasted perilla seeds. Lipid oxidation during UV irradiation was higher and faster in perilla oil than that in perilla seeds, with a slight loss of linolenic acid. Unroasted perilla seeds were more oxidation-stable than roasted seeds. Tocopherols and polyphenols were degraded during UV irradiation, with a higher degradation rate observed in unroasted perilla seeds than in roasted ones. Antioxidant concentration dependency of the lipid oxidation during UV irradiation was higher in perilla oil than that in perilla seeds, and the contribution of polyphenols to oxidative stability was higher than that of tocopherols in all samples.

Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Investigation of pretilt generation by UV light irradiation during imidization of polyimide (폴리이미드 소성 시에 UV 광조사를 이용한 프리틸트 발생에 대한 연구)

  • 서대식;김형규
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.1
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    • pp.75-79
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    • 2000
  • In this study, we investigated the pretilt angle generation and liquid crystal (LC) alignment by ultravi-olet (UV) light irradiation during imidization of polymide. The generated pretilt angle of nematic (N) LC by using the in-situ photo-alignment method was smaller than that of the conventional UV photo-alignment method. Also, generated pretilt angle of NLC tends to increase by annealing. In case of using the polymer(AL-3046), we found that the in-situ Uv photo-alignment method has higher thermal stability of LC alignment, but it has a disadvantage to control pretilt angle.

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