• Title/Summary/Keyword: UV spectrophotometer

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Layout of Long-pass-edge Filter Correspond with the Optical Transmission in Crystalline (수정체 광투과에 대응하는 LPE Filter 설계)

  • Kim, YongGeun
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.57-63
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    • 1999
  • The optical absorption and transmittance of cow' crystalline were measured by spectrophotometer in the 200~800nm wavelength regions. The optical absorptions of crystalline composed of a high absorption band in the UV-A, UV-B, and appeared the light transmittance edge in the 400nm wavelength region, and completely transmitted without the absorption in the high wavelength regions than 400nm. Also, the optical absorption and transmittance had no temperature dependence. The optical transmittance spectrum of crystalline concord with the thin film structure of $n_0/(0.5H)L(LH)^6(0.5H)/n_s$ and $n_0{\mid}(0.5LH0.5L)^kL/1.25{\mid}4.0$ of long-pass edge filter form. In the artificial crystalline and inter lens layout, long-pass edge filter layout can UV cut off.

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Analysis on capacity loss caused by air oxidation of $V^{2+}$ ion using UV-Visible spectrophotometer for vanadium redox flow battery (공기 중 바나듐 2가 이온 산화에 의한 바나듐 레독스 흐름전지의 내구성 영향 분석)

  • Kwon, Soonkwan;Kim, Hansung
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.175.2-175.2
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    • 2011
  • 바나듐 3, 4, 5가 이온은 공기 중에서 안정하지만, 바나듐 2가 이온은 쉽게 산화된다. 그러므로 바나듐 2가 이온이 담겨져 있는 음극 탱크가 공기와 접촉하지 않게 하는 것이 중요하다. 충전 중 음극 탱크에 공기가 침투되면, 바나듐 2가 이온은 3가 이온으로 산화되기 때문에 음극과 양극의 전해질에 불균형을 초래한다. 이러한 불균형은 바나듐 레독스 흐름전지 용량저하의 원인이 된다. 본 연구에서는 공기 중 2가 이온 산화에 의한 전해질의 불균형 현상을 쉽게 보여주기 위해, 공기노출과 차단조건에서 충방전 중에 발생한 음극과 양극의 바나듐 이온 상태변화량을 UV-Visible spectrophotometer를 이용해 정량적으로 분석하였다. 분석 결과, 공기노출 조건에서 음극의 충전 시, 충방전 cycle이 진행 될수록 바나듐 2가 이온의 양이 현격히 줄어들었지만, 공기차단 조건에서는 2가 이온의 양이 공기노출 조건보다 훨씬 더 적게 줄어들었다. 즉, 공기차단 조건에서는 바나듐 2가 이온이 3가로 산화되지 않아서 음극의 충전 후 바나듐 3가에서 2가로 전환되는 양이 공기노출 조건보다 더 많은 것을 확인할 수 있었다. 이러한 영향으로 인해, 충방전 10th cycle을 진행해 본 결과, 공기차단 조건에서는 충방전 용량감소가 거의 없었지만 공기노출 조건에서는 현격한 충방전 용량 감소를 보였다.

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Analysis of Toxic Substance (Indotoxin) by Gas Chromatography (기체 크로마토그래피에 의한 독성 물질(내독소)의 분석)

  • 이봉헌;박흥재
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.555-560
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    • 1996
  • The toxic substances (endotoxins) from the bacterial cell walls were extracted by using incubator, centrifuge, UV-Vis spectrophotometer, and their fatty acid compositions were analyzed by Gas Chromatography. The lethal toxicities and pyrogenic activities of toxic substances were tested and the results were compared each other. The results of fatty acid analyses showed that the major fatty acid of the toxic substance was tetradecanoic acid for Vibrio vulnificus, dodecanoic acid for Escherichia coli, and decanoic acid for Salmonella typhimurium. These three fatty acids were the main fatty acids ofr three toxic substances (more, than 70%). The unique points in the fatty acid compositions were that tetradecanoic acid was composed as important one (37.15%) for V. vulnificus and that the amount of hexadecanoic acid was very small (below 2%) for three toxic substances. The lethal toxicity in ICR mice of toxic substance from V. vulnificus (LD50 was 52.5 mg/kg) was similar to that of E. coli (56.5mg/kg), but weaker than that of S. typhimurium (37.5mg/kg). Toxic substance from V. vulnificus was more pyrogenic in rabbit than that from E. coli, but less than that from S. typhimurium.

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A Study on the Coloring of 304 Stainless Steel Screen for Reducing Light Reflectivity (304스테인리스강 스크린의 광 반사율 감소를 위한 착색 처리에 관한 연구)

  • Kim, Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.4
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    • pp.187-193
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    • 2010
  • The colored films formed on 304 stainless steel plates by immersion treatment and electrochemical one in a solution containing sulphuric acids and chromic acids were studied by SEM, AES, and spectrophotometer. The thicknesses of the films by 20 minutes treatment were about 200 nm and it became thinner as the treatment times were increased. The surface texture showed a tortuous network of interlinking pathways. The color of the 304 steel surface changed from metallic white to gray, black, red, yellow-green, and green-blue, gradually, by the treatment time was increased. The reflectivity measured by UV-VIS-NIR spectrophotometer was reduced from max. 38% of basis metal to min. 3.5% of colored surface.

A Study on the Optical Properties by Material of Soft Contact Lens (소프트콘택트렌즈의 재료에 따른 광학적 특성에 관한 연구)

  • Son, Byeong-Ho;Jeong, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.14 no.2
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    • pp.27-30
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    • 2009
  • Purpose: Transmittance at UV-visible spectra range was measured to confirm the effect of wet/dry state of commercially available SCL on human eyes. Method: Commercially available five SCLs fabricated by different materials were selected to measure optical properties according to humidity. Results: A relatively high transmittance above about 80% in the visible spectra range of the SCLs were observed. In the UV spectra range, the wet samples showed higher transmittance than those dried except an unusual case. Conclusions: All the samples having a high optical properties in the visible spectra range exhibit a high transmittance in the UV region. Further research will be needed to develop new materials having a sharp absorption edge in the UV spectra range.

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The Effects of Concentration of HAuCl4 Solution and UV Irradiation Time on Generation of Nano Gold Particles (나노 금 입자생성에 HAuCl4 용액의 농도와 UV 조사시간이 미치는 영향)

  • An, Jeong-Min;Lee, Chang-Whan;Kim, Joo-Yong
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.39-45
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    • 2009
  • The importance of nano gold particles has been increased in the field of bio physics and medicine, recently. In this regard, the study aims to analyze how the harmless nano gold particles can be transformed by respective variables. In this study, electrospun PU nano-webs were impregnated with aqueous $HAuCl_4$ solution and UV light was irradiated on the webs. Au-ions were reduced to nano particles by photocatalytic reduction and these nano gold particles were characterized by SEM, UV-vis, Zetasizer, Spectrophotometer, EDS. $HAuCl_4$ solution concentration and UV irradiation time have heen examined to change the amount of absorption. Nano gold particles size and UV-Vis absorbances were increased with $HAuCl_4$ solution concentration and UV irradiation time.

Determination of C3G Content in Blackish Purple Rice using HPLC and UV-Vis Spectrophotometer

  • Ryu, Su-Noh;Park, Sun-Zik;Kang, Sam-Sik;Han, Sang-Jun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.5
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    • pp.369-371
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    • 2003
  • Cyanidin 3-glucoside (C3G) content contained in the grains of blackish purple rice varieties, Heugjinjubyeo, Kilimheugmi, Heugnambyeo, Sanghaehy-anghyeolla, and the progenies derived from their crosses was evaluated by HPLC and UV-Vis spectroscopy. C3G content was higher in the range of 10-30% by using UV-Vis method compared to HPLC method. A significant linear relationship was, however, observed between two analytical methods. The correlation coefficient was 0.98. Thus, this results suggested that it would be able to use UV-Vis spectroscopy to determine C3G content which does not demanded precise value like selection.

Photochromic Lens development to use Nano particle (1) - Photochromic Lens' estimation method and application - (Nano 입자를 이용한 Photochromic Lens 개발(1) - Photochromic Lens의 평가방법 및 적용 -)

  • Kim, Yong Geun;Seong, Jeong Sub
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.2
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    • pp.169-174
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    • 2002
  • Make Photochromic lens Photochromism estimation method, and gouge photochromic lens and investigated UV light source to apply. UV light source irradiation ago and after wavelength dependence of photo-transmittance (T%) of darkening and fading state by do optical equipment which is consisted of spectrophotometer, light source, power meter and detecter. Use relative ratio value of maximum $T%{\times}{\lambda}$ area and saturated state area in light off. Dependences estimation introduced darkening efficiency $(K_d)=(1-C_1/A_1)/t_{on}$ relationship value course fading efficiency$(K_f)=(C_2/A_2)/t_{on}$ value during Photochromism's irradiation time in Photochromic lens. Wavelength dependence of transmittance (T%) has form of $T_m+T_1{\exp}[-(x_0-t)/a]$ in Darkening course fading state. Can receive each estimation parameter value as result that apply Photochromism's estimation parameter Z, $K_d$, $K_f$ in Photochromic lens.

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Synthesis and Characterizations of Manganese and Iron Dopped Titania Pigment (망간과 철이 도핑된 이산화티탄 안료의 합성과 특성)

  • Kang, Kuk-Hyoun;Choi, Ji-Sik;Lee, Jin-Hee;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.393-401
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    • 2012
  • Inorganic pigment is excellent at stability to human body and compatibility with different materials and has been used in a variety of field such as cosmetics, printing inks, paints, and construction materials for improving the aesthetic features. In this paper, hydrothermal synthesis method was used to prepare the manganese and iron dopped with titania pigment. As process parameters, the amount of manganese precursor and iron precursor, and calcined temperature was changed. Optimum amounts of manganese and iron dopped with titania precursor to give excellent color index was manganese 1.0wt% and iron 1.5wt% for dopped titania, and Optimum calcination temperature was $550^{\circ}C$. The synthesized pigments were analyzed by XRD, SEM, EDS, Spectrophotometer and UV-Vis Spectrometer.

Analysis on Red-colored Dyeing by using Non-destructive UV-visible and Fluorescence Spectrophotometry (비파괴 자외-가시 및 형광 분광 분석법을 이용한 적색계 전통 염료 분석)

  • Yun, Eunyoung;Kim, Yuran
    • Conservation Science in Museum
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    • v.12
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    • pp.9-17
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    • 2011
  • This study examined non-destructive UV-Vis spectrophotometry as well as 3-D fluorescence spectrophotometry of textile that made use of red dye such as Sappan wood, madder, Safflower, Gromwell. The authors produced two textile specimen that were dyed by not only two kinds of textile (cotton and silk) but also three kinds of mordanting (no-mordanting, alumen and iron), and they investigated effects of each dye material upon investigation results. At analysis with UV-Vis spectrophotometry of dyed textile specimen, dyeing made by sappan wood, madder and gromwell had significant difference depending upon mardant regardless of kinds of textile, and safflower had no significant difference depending upon textile and mordant. At analysis with 3D-fluorescence spectrophotometry, specimen dyed with sappan wood had difference with mordants, and with madder, there were difference with textiles, and safflower had inherent fluorescence spectrum regardless of textiles and mordants, while gromwell had no fluorescence spectrum.