• Title/Summary/Keyword: UV filters

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Enhancement in the Thermal Stability of Microporous UHMWPE Membrane by LED-UV Crosslinking (LED-UV 가교에 의한 UHMWPE 미세다공막의 열 안정성 향상)

  • Jeong-Hwan Kim;Jinho Jang
    • Textile Coloration and Finishing
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    • v.35 no.4
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    • pp.231-238
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    • 2023
  • Microporous gel films of 29 m were prepared by the gel drawing of UHMWPE/soybean oil blend (4:6, w/w) up to 800%. The stretched films containing the optimal photoinitiator concentration, depending on the film thickness, was cross-linked under 365 nm LED-UV irradiation and the oil was extracted with n-hexane, resulting in a gel fraction of 95 % or more. With the formation of the cross-linked structure, the melt-down temperature and melt-down elongation increased by 16 ℃ and by 63% respectively. Also the thermal stability of the crosslinked UHMWPE was proved by the area shrinkage under the heat treatment decreased to 3.8 % compared to 17.4 % for the pristine film, and by the reductions in the combustion heat. The enhanced thermal stability of the crosslinked UHMWPE microporous membranes can be used for various industrial applications such as filters, electric vehicles and energy storage systems.

Characterization of polymer surface of LCD blue color filters using SIMS, XPS and AFM (SIMS, XPS, AFM을 이용한 LCD blue color filter의 고분자 표면 연구)

  • 김승희;김태형;이상호;이종완
    • Journal of the Korean Vacuum Society
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    • v.6 no.4
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    • pp.321-325
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    • 1997
  • Recently, photosensitive color filters have received much attention for their use in the liquid crystal display (LCD) industry. It is well known that chemical and physical properties of polymer surfaces can be modified by special surface treatments. In this work, we have studied the polymer surfaces of LCD blue color filters which were exposed to the UV light during photolithography. A better understanding of the irradiated polymer surfaces is required for the subsequent processes such as plasma etching, ITO electrode deposition, etc. The surface analysis has been undertaken using secondary ion mass spectrometry (SIMS), x-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). A significant enrichment of the pigment component and roughening of surface with bubble-like feature have been observed at the modified polymer surface.

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Studies on the Correlation between SPF Index and Skin Irritation Index of Sunscreens (자외선 차단제의 SPF 지수와 피부자극지수와의 상관성 연구)

  • 김종원;서수경;최주영;박창원;서경원;김규봉;김광진;김재희;이선희
    • Biomolecules & Therapeutics
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    • v.10 no.4
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    • pp.246-252
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    • 2002
  • In recent years, the safety of sunscreens has been challenged based on the reports of their adverse effect on users; dermatitis, allergic contact dermatitis and photo allergic contact dermatitis. The unscientific idea that higher SPF sunsreen is good for health mealeads many users to tend to prefer higher SPF sunscreen. In the toxicological aspect, the need to investigate the safety of sunscreens is steadily increasing. However, there were few studies on the correlation between sun protection factor (SPF) and the safety of sunscreens. The objective of this study was to assess whether there was a correlation between SPF and the safety of sunscreens. We measured in vitro SPF index using homosalate as a standard and examined the toxicity tests such as primary skin irritation tests, ocular irritation test and skin sensitization test. Homosalate (HS), octyl methoxycinnamate (OMC), octyl salicylate (OS), octocrylene (OC) as UVB organic filter and benzophenone-3 (BP3), butyl methoxy dibenzoil methane (BMDM) as UVA organic filter, and titanium dioxide (TD), zinc oxide (ZO) as inorganic filters were used. The skin irritation indexes in rabbits treated with HS, OMC, OS, BP3, and BMDM were significantly increased as SPF indices were increased. Neither ocular irritation in rabbits nor skin sensitization in guinea pigs were increased. It suggests that there might be a good correlation between SPF and the skin irritation indices of organic UV filters and skin irritation might be one of most sensitive index to assess the safety of sunscreens.

Quantitative analysis by derivative spectrophotometry (ll) Derivative spectrophotometry and methods for the reduction of high frequency noises

  • Park, Man-Ki;Cho, Jung-Hwan
    • Archives of Pharmacal Research
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    • v.10 no.1
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    • pp.1-8
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    • 1987
  • One of the problems of derivatie spectrophotometry, the decrease of signal-to-noise ratio by derivative operations, was solved by three concepts of digital filtering, ensemble averaging, least squares polynomial smoothing and Fourier smoothing. The suthors made several compouter programs written in APPLE SOFT BASIC language for the actual applications of the concepts of these digital filters on UV spectrophotometer system. As a result, ensemble averaging could not be used as a routine operation for the spectrophotometer used. The maximum S/N ratio enhancement factors achieved by least squares polynomial smoothing were 6.17 and 7.47 for the spectra of Gaussian and Lorentzian distribution models, and by Fourier smoothing 16.42 and 11.78 for the spectra of two models, respectively.

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The Study of Thermal Effect Suppression and Wavelength Dependence of Azobenzene-coated FBG for UV Sensing Application (UV광 측정용 아조벤젠 코팅된 FBG의 열적 효과 제거 및 파장 의존성에 대한 연구)

  • Choi, Dong-Seok;Kim, Hyun-Kyoung;Ahn, Tae-Jung
    • Korean Journal of Optics and Photonics
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    • v.22 no.2
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    • pp.67-71
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    • 2011
  • In the paper, we have demonstrated an azobenzene-coated fiber Bragg grating (FBG) for monitoring ultraviolet light (UV) intensity in remote measurement. The elasticity of the coated azobenzene polymer is changed by the UV light, which induces a center wavelength change corresponding to the change of the FBG's grating period. The wavelength shift resulting from both UV light and other light with the wavelength out of the UV range was about 0.18 nm. In order to improve the accuracy of the measurement, the center wavelength shift caused by radiant heat of the light source was sufficiently removed by using a thermal filter. The amount of the center wavelength shift was consequently reduced to 0.06 nm, compared to the result without the thermal filter. Also, the FBGs coated by using azobenzene polymer were produced by two different methods; thermal casting and UV curing. Considering temperature dependence, UV curing is more suitable than thermal casting in UV sensor application of the azobenzene-coated FBG. In addition, we have confirmed the wavelength dependence of the optical sensor by means of four different band pass filters. Thus, we found out that the center wavelength shift per unit intensity is 0.029 [arb. unit] as a maximum value at 370 nm wavelength region and that the absorption spectrum of the azobenzene polymer was very consistent with the wavelength dependence of the azobenzene-coated FBG.

Synergistic Effects of UV Absorbance of Nanoemulsions Formed with Organic UV filters and Wax (유기자외선차단제와 왁스를 함유한 나노에멀젼의 자외선 흡광도의 상승효과)

  • Cho, Wan Goo;Cha, Young Kweon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.1
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    • pp.57-62
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    • 2015
  • In this study, we investigated the effect on the increase of UV absorbance using a o/w nanoemulsion containing a blend of surfactants (Tween 80 and Span 80), an organic sunscreen, and wax. The particle size of nanoemulsion produced by PIC (Phase Inversion Composition), in Tween 80/Span 80 system containing candelilla wax was below 50 nm. As the concentration of Tween 80/Span 80/candelilla wax/organic UV filter was fixed at 4.5/0.5/3.0/2.0 wt%, and various organic sunscreens were added to the system, stable nanoemulsion was produced by Parsol MCX and Escalol 587, respectively. In addition, in the same system, when the ratio of Parsol MCX and candelilla wax was less than 2.0, a stable nanoemulsion was obtained. UV absorbance showed a high synergistic effect when Parsol MCX was used with candelilla wax.

Measurement of Color Change of Opaque Resin Materials by Radiation Energy (불투명 수지재료의 복사에너지에 의한 변색 측정)

  • Han, Jong-Sung;Kim, Hong-Beom;Kim, Hoon
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1998.11a
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    • pp.138-141
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    • 1998
  • To evaluate the color change of the opaque resin materials, a measuring system including PAS(photodegradation acceleration system) was constructed. Xenon lamp is used as a light source in the PAS, and the radiant energy from the lamp is irradiated to the samples through serveral high-pass filters with cut-off wavelength in UV and visible region. The color difference of the samples were measured by using the measuring system with a spectrophotometer(CM-2002) and a computer. The result showed that the opaque resin materials changed severely in their color in the wavelength of UV region and changed a little in the wavelength of visible region.

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Lyotropic Chromonic Liquid Crystals in Aligned Films for Applications as Polarizing Coatings

  • Schneider, Tod;Golovin, Andrii;Lee, Jong-Chan;Lavrentovich, Oleg D.
    • Journal of Information Display
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    • v.5 no.2
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    • pp.27-38
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    • 2004
  • We describe dried oriented films with anisotropic structural and optical properties prepared from the aqueous solutions of plank-like molecules, the so-called Lyotropic Chromonic Liquid Crystals (LCLCs). The dried LCLC films may be used as optical elements, such as polarizers, compensators, color filters, or retardation plates in the UV, visible, or infrared parts of spectrums. The optical quality of the films is determined by the uniformity of the molecular alignment, which often distorted by periodic variations of the director field. We describe different ways to improve the alignment properties of the films by using additives. We present compositions capable of polarizing effects in visible and UV parts of spectrum.

Evaluation of Sampling and Analytical Methods for the Determination of Polycyclic Aromatic Hydrocarbons in the Ambient Atmosphere (환경대기중 다환방향족탄화수소의 포집과 분석방법에 관한 연구)

  • 백성옥
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.1-16
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    • 1991
  • In this study, sampling and analytical procedures were evaluated for the determination of ambient levels of atmospheric PAH, both in gaseous and particulate phase. The method involves low-volume sampling and Soxhlet extraction of the filters and Tenax absorbent, followed by a clean-up stage using a silica column prior to analysis by reversed-phase HPLC with wavelength programmable fluorescence and UV detection. A total of 18 PAH were identified and quantified, all of which have been of environmental concern. In order to validate the methodology and to ensure compatibility of the results, the analytical method used for the determination of PAH was evaluated with respect to the efficiencies of extraction and clean-up procedure, HPLC separation, and lower limits of detection. In addition, substrate dependency of PAH recovery was investigated for the two types of fiters, i.e. glass fiber and PTFE filters.

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