• Title/Summary/Keyword: UV deterioration

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Amorphous-to-Crystalline Phase Transition of (InTe)x(GeTe) Thin Films ((InTe)x(GeTe) 박막의 비정질-결정질 상변화)

  • Song, Ki-Ho;Beak, Seung-Cheol;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.3
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    • pp.199-205
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    • 2010
  • The crystallization speed (v) of amorphous (InTe)$_x$(GeTe) (x = 0.1, 0.3 and 0.5) films and their thermal, optical and electrical behaviors have been investigated using nano-pulse scanner (wavelength = 658 nm, laser beam diameter < 2 ${\mu}m$), X-ray diffraction (XRD), 4-point probe and UV-vis-IR spectrophotometer. These results were compared with those of $Ge_2Sb_2Te_5$ (GST) film, comprehensively utilized for phase-change random access memory (PRAM). Both v-value and thermal stability of (InTe)$_{0.1}$(GeTe) and (InTe)$_{0.3}$(GeTe) films could be enhanced in comparison with those of the GST. Contrarily, the v-value in the (InTe)$_{0.5}$(GeTe) film was so drastically deteriorated that we could not quantitatively evaluate it. This deterioration is thought because amorphous (InTe)$_{0.5}$(GeTe) film has relatively high reflectance, resulting in too low absorption to cause the crystallization. Conclusively, it could be thought that a proper compositional (InTe)$_x$(GeTe) films (e.g., x < 0.3) may be good candidates with both high crystallization speed and thermal stability for PRAM application.

Comparative Analysis of the Optical Aging Patterns in Different Partitions of the Beeswax-Treated Volume during Dry Heating Aging at $105^{\circ}C$ (건식 인공열화 시 밀랍본 시제품의 제본부위별 광학적 특성변화 비교분석)

  • Choi, Kyoung-Hwa;Jeong, Hye-Young;Kang, Yeong-Seok;Cho, Jung-Hye
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.98-105
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    • 2011
  • Patterns and levels of aging vary between the book volume and sheets, even though both are made from the same paper materials. In case of book format, the outside is more easily affected than inner side by environmental factors such as temperature, humidity and air. In this study, the change in optical properties after dry heating accelerated aging was comparatively analyzed to understand the difference of the optical aging characteristics between outside and inner side of the duplicated beeswax-treated volume. It is found that the cover pages of the beeswax-treated volumes were more optically deteriorated than their middle pages. This indicates that outer sides of aging book volume directly exposed to the air is more vulnerable to serious deterioration than inner sides. Also, aromatic compounds such as benzoic acid and cinnamic acid were observed in the investigation of UV/VIS absorbance of the beeswax in each aged sample.

Durability of Photocatalytic Cementitious Materials Exposed to Nitrogen Dioxide (광촉매 시멘트의 이산화질소 분해에 따른 내구성에 관한 연구)

  • Lee, Bo Yeon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.248-249
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    • 2014
  • Photocatalytic cement is receiving attention due to its high oxidation power that oxidizes nitrogen oxides (NOx), thus contributing to clean atmospheric environment. However, there has not been a thorough investigation on durability of a parent material, cementitious material, as a result of photocatalytic reactions. In this study, durability of photocatalytic cementitious materials exposed to nitrogen dioxide (NO2) gas was examined. Titanium dioxide (TiO2) nanoparticles containing cement paste samples were exposed to cycles of NO2 with UV light, followed by wetting and drying to simulate environmental condition. The surface of samples was characterized mechanically, chemically, and visually during the cycling. The results indicate that the photocatalytic efficiency decreased with continued NO2 oxidation due to calcium carbonate formation. The pits found from SEM demonstrate that chemical deterioration have occurred, such as acid attack or leaching. In conclusion, the photocatalytic reactions and its product could alter cementitious materials chemically and mechanically which could further affect long-term durability.

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Color Change of Major Wood Species Planted in Indonesia by Ultraviolet Radiation (자외선 조사에 의한 인도네시아 주요 조림수종 목재의 재색변화)

  • Park, Se-Hwi;Jang, Jae-Hyuk;Qi, Yue;Hidayat, Wahyu;Hwang, Won-Joong;Febrianto, Fauzi;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.9-18
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    • 2016
  • This study was performed to understand wood durability to climate deterioration of planted Indonesian wood specie such as Albizia, Gmelina, Mangium and Mindi. Wood samples were exposed to indoor and outdoor condition. $L^*a^*b^*$ and Color changes (${\Delta}E*ab$) were determined by a spectrophotometer. As a result, color of all samples was changed more markedly by ultraviolet radiation. In indoor test with UV, brightness of wood specimens from four species was not changed and all samples were changed into more reddish and yellowish. In accelerated weathering test, all samples were bleached and changed into more greenish and blueish. In outdoor test, brightness of wood specimens decreased in Albizia and Gmelina and increased in Mangium and Mindi. All wood specimens in outdoor test were changed into more greenish and blueish. Albizia and Gmleina woods showed greater color change than those of Mangium and Mindi. Especially, color change of wood samples might be influenced greatly by moisture. In conclusion, wood color changed into more clearly by UV radiation. Therefore, exposing woods to UV radiation could be one of reasonable methods to improve wood quality on visual characteristic.

Component Analysis and Reproduction of a Brown Solid Cosmetic Excavated from Tomb of Princess Hwahyeop (화협옹주 출토 화장품(갈색 고체) 성분 분석 및 재현연구)

  • Lee, Chaehoon;You, Song-e;Lee, Hanhyoung;Kim, Hyoyun;Kim, Seongmi;Chung, Yongjae
    • Journal of Conservation Science
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    • v.36 no.5
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    • pp.430-439
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    • 2020
  • This study focused on analyzing solid brown cosmetic residues that were excavated from the tomb of the Hwahyeop princess. The cosmetics had been buried in 1752 in Cheonghwa Baekja (small porcelain jars) within a Huigwakham (a stone box sealed with lime). A literature search and chemical analyses of the relics were conducted at the National Palace Museum of Korea. Based on the results of these analyses, raw materials and manufacturing methods for reproduction of the cosmetic were selected and then cream-form cosmetics were prepared. Aging tests using heat, ultraviolet (UV) radiation, and CO2 were carried out to emulate the deterioration of the excavated cosmetics. Further chemical analyses and functionality tests were performed to evaluate changes from the tests and the effect as a cosmetic. As heat aging progressed, among the reproduced cosmetics, the one which has a high proposition of oil showed a color difference value of 32; the oxidation of oils involved chemical changes in O-H and C=C groups. As the cosmetic cream deteriorated under UV aging, the pH value became acidic. The result of the functional coverage test of the reproduced cosmetic cream was lower than the standard coverage ratio of modern cosmetics.

Whitening Effect of 3-O-Cetyl-L-Ascorbic Acid (3-O-Cetyl-L-Ascorbic Acid의 미백 개선 효과)

  • Park, Chang-Min;Bae, Ji-Young;Joung, Min-Seok;Choi, Jong-Wan
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.1
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    • pp.91-96
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    • 2011
  • Deficiency of collagen regeneration, denaturalization of fibers, increased melanin synthesis and reactive oxygen species are important factors inducing deterioration of healthy skin function. They induce freckles and decrease in skin elasticity. Vitamin C, vitamin A and their derivatives have been used as cosmetic ingredients for improvement of these problems but they have various problems. We have been developing the various derivatives of these ingredients. In this study, we investigated whitening effect of 3-o-cetyl-L-ascorbic acid (VCCE), a new vitamin C derivative. The VCCE inhibited melanogenesis in a dose dependent manner(44 % at $20\;{\mu}g/mL $) and tyrosinase expression. For 8 weeks, we also investigated skin brightening effect of VCCE on pigmented spots in UV-irradiated human skin. In results, VCCE showed a statistically significant skin whitening effect by mechanical and visual evaluation. Taken together, our findings suggest that the VCCE has potential benefits as an active ingredient for whitening cosmetics.

Effects of U.V. Irradiation on the Physical Properties of Fabrics Treated with Eco-friendly Persimmon Juice -Silk and Nylon Fabrics- (친환경 감물가공 소재의 자외선 조사에 의한 물리적 특성변화에 대한 연구 -견 및 나일론 직물-)

  • Kim, Jimin;Kim, Jongjun
    • Journal of Fashion Business
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    • v.19 no.4
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    • pp.120-134
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    • 2015
  • This study aimed to determine the physical properties of silk and nylon fabrics that are treated with persimmon juice in accordance with irradiation time of ultraviolet spectrum. Persimmon juice dyeing has the advantage of using the tannin component of the persimmon. Tannin plays an important role in inhibiting photodegradation of fibers or polymers. Among fibrous materials, silk and nylon are prone to deterioration by light. Hence, this study aimed to reduce these weaknesses of silk and nylon by applying persimmon juice treatment. We accordingly carried out investigation and experiments on ultraviolet irradiation, and physical characteristics of treated fabrics. The persimmon juice treatment process led to increased weight and thickness. In addition, the air permeability of silk fabric was increased, as compared to the control specimen; whereas, that of nylon fabric was decreased. Both drape stiffness and flex stiffness of silk and nylon tended to be high in textiles processed with persimmon juice treatment, as compared to the control textile. Peak load and elongation at peak load of untreated samples clearly decreased in both silk and nylon fabrics with the increase of ultraviolet irradiation time, while those of persimmon juice treated samples increased. Furthermore, ultraviolet blocking ratio measurement indicated that the fabric specimens treated with persimmon juice blocked U.V. spectrum better than the control specimen.

Durability Performance Evaluation of PolyUrea for Seismic Retrofitting of RC Structures (구조물 내진 보강용 폴리우레아의 내구 성능 평가)

  • Cho, Chul-Min;Kim, Jang Jay Ho;Lee, Doo-Sung;Kim, Tae-Kyun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.1-8
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    • 2017
  • An experimental study is needed a reinforcing method for seismic load to apply for RC structures because a lot of earthquakes have frequently happened in the world and those also collapsed infrastructures or damaged human lives. The reinforcing effect of PolyUrea (PU) appeared to be excellent under blast and impact about RC structures. In this study, Stiff Type PolyUrea (STPU) had developed by manipulating the ratio of the components of prepolymer and hardener of PU. And the durability performance evaluation of STPU for deterioration and chemical resistance has been performed. Acid environmental exposure test and ultraviolet (UV) exposure test have been performed as the durability performance evaluation for STPU. Concrete carbonation exposure test and freezing and thawing test for concrete coated with STPU have been performed. The experimental result showed that STPU has high resisting capacity and durability in all tests. Therefore, STPU would be used as seismic reinforcement materials.

Effect of β-Carotene and Vitamin C on Chlorophyll-Induced Photooxidation (클로로필의 광산화에 미치는 β-카로텐과 비타민 C의 영향)

  • Ryu, Seung-Hee;Lee, Hye-Suk;Lee, Young-Soon;Kwon, Tai-Wan;Song, Young-Sun;Moon, Gap-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.1
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    • pp.99-106
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    • 2005
  • Skin is continously exposed to ultraviolet (UV) radiation, the major cause of skin disorders including skin aging. Chlorophylls were well known as photosensitizer initiating subsequent chemical reactions such as photooxidative deterioration of cellular structures. This experiment was designed to elucidate the effects of $\beta$-carotene and ascorbic acid with chlorophylls on UVB-induced photooxidation in linoleic acid emulsion model system and skin homogenate of ICR mouse. In linoleic acid emulsion model system, the addition of chlorophyll and $\beta$-carotene accelerated the photooxidation, while high concentration of ascorbic acid prevented. The combination of chlorophylls, $\beta$-carotene and ascorbic acid, which concentrations are simplified from mustard leaf kimchi, prevented UVB-induced photooxidation. Although single treatment of $\beta$-caretene accelerated photooxidaiton, $\beta$-caretene acted as antioxidant in the combination with ascorbic acid. Similarly the addition of individual chlorophylls and $\beta$-carotene accelerated the UVB-induced photooxidation in skin homogenate of ICR mouse. 50 ppm of ascorbic acid did not show the any preventive effect, however 500 ppm of ascorbic acid effectively prevented the oxidation. Photooxidation was prevented in the combination of chlorophylls and $\beta$-carotene with 500 ppm of ascorbic acid and concentration rate of ascorbic acid plays an important role in the prevention of UVB-induced photooxidation.

Experimental Evaluation of Weathering Performance for Duplex Coating Systems Combining Thermal Spraying Metals and Painting (금속용사와 도장의 복합피복방식법에 대한 실험적 내후성능평가)

  • Kim, In Tae;Jun, Je Hyong;Cha, Ki Hyuk;Jeong, Young Soo;Ahn, Jin Hee
    • Journal of Korean Society of Steel Construction
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    • v.28 no.5
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    • pp.373-382
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    • 2016
  • Painting or thermally sprayed metal coating is often used in corrosion protection of steel structures. In recently, duplex coating system which combines thermally sprayed metals with paint is selected as a new generic type of coatings on steel structures under the highly corrosive environments. In this study, the structural steel specimens were surface treated, thermally sprayed with zinc, zinc-15%aluminum alloy, aluminum and aluminum-5%magnesium alloy, and finally sealing or painted with acrylic urethane. And as a reference specimens, steel specimens were painted with acrylic urethane after surface treatment. Circular defects with 1.0, 3.0 and 5.0 mm in diameters and line defect with 2.0 mm width, which reach the steel substrate were created on all specimens. The specimens were exposed into an environmental testing chamber controlled by the ISO 20340, which is a laboratory cyclic accelerated exposure test condition of spraying/UV/low temperature, for up to 175 days. Based on the corrosion tests, corrosion deterioration from the initial defects were evaluated and weathering performance of the specimens are compared.