• Title/Summary/Keyword: UV curable

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One-side Water-repellent Finish of PET Fabrics using UV/Ozone (UV/Ozone 조사에 의한 PET 직물의 편면 발수가공)

  • Kim, Su-Jin;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.100-106
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    • 2011
  • UV-curable water-repellent finish was carried out to impart one-side repellency to the PET fabrics using a formulation of a UV-active fluorocarbon agent and a water soluble photoinitiator. The aqueous formulation was padded on the PET fabrics and it was subsequently UV-cured. The unirradiated side of the cured fabrics was made to wetteable to water by the prolonged UV/ozone irradiation. The influence of photoinitiator concentration, agent concentration and UV energy for photodegradation on the performance of the finished fabrics were investigated. The difference in the functional property of front and back sides was examined by measuring water repellency at each side of the treated fabrics, which resulted in four rating difference between two-side. The UV-cured and photodegraded PET surfaces were characterized by ATR, ESCA and FE-SEM.

Preparation of UV curable coating solution from multi functional acrylates and characterization of optical properties of coated layer on PET film (다관능 아크릴레이트계 자외선 경화형 코팅액의 제조 및 이를 이용한 PET 필름 도막의 광학 특성 연구)

  • Lee, Soo;Jin, Seok-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.467-472
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    • 2009
  • Ultraviolet curable coating solution was prepared with poly(ethylene glycol) acrylate oligomer and various mono and multi-functional acrylate monomers. The optical properties of UV cured coating layer on PET film with acrylate coating solution containing metal oxides, such as fumed silica and alumina, were also investigated to reduce light reflection on films. Poly(ethylene glycol) diacrylate which has 575 of average molecular weight was used as oligomer acrylate, and pentaerythritol triacrylate and dipentaerythritolpenta-/hexa acrylate were used as multi-functional acrylate monomers. Also, butyl acrylate was used to improve the adhesion as well as to reduce glass transition temperature to give a better flexability. 1-hydroxy cyclohexyl phenyl ketone was used as photoinitiator. We found out the metal oxides in acrylate coating solution showed a homogeneous dispersion from energy dispersive spectroscopy data. Transmittance and light reflection of coated PET film was measured with UV/vis spectrometer and gloss meter, respectively. When 1.00 g of both metal oxides was added into coating solution, the transmittance and the glossiness were reduced from 90% to 30% and from 190 GU to 35 GU, respectively. However, adding up to 1.00 g of the metal oxide into coating solution did not affect on the hardness of coating layer and adhesion between coated layer and PET film. Conclusively, we can control transmittance and light reflection of coated film by adjusting the amounts of metal oxide in coating solution.

Synthesis and Curing Behavior of UV-curable Polycarbonate-based Polyurethane Methacrylate : Effect of Polyol Molecular Weight, Contents of Photoinitiator and Monomers on the Flexibility and Properties (자외선 경화형 폴리카보네이트계 폴리우레탄 메타아크릴레이트의 합성과 경화거동 : 폴리올 분자량, 광개시제 및 모노머 함량이 유연성과 물성에 미치는 영향)

  • Park, Eun-Suk;Hwang, Hyeon-Deuk;Park, Cho-Hee;Lee, Yong-Hee;Moon, Je-Ik;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.12 no.2
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    • pp.47-55
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    • 2011
  • UV-curable coatings have been used in various industries due to their advantages such as high mechanical property, good solvent resistance, fast curing process and low volatile organic compounds. However, a lack of flexibility of UV-cured films is a weak point for the pre-coated system of roll-to-roll process. In this study, UV-curable polycarbonate-based methacrylates were synthesized with polycarbonate diol, isophorone diisocyanate and 2-hydroxyethylmethacrylate to improve flexibility of the UC-cured films. The effects of polyol molecular weight, content of photoinitiator and monomers on the UV-curing behavior, flexibility and properties were investigated. The UV-curing behavior was measured by a photo-DSC, the pendulum hardness, tensile strength, viscoelastic properties were also evaluated.

Sintering process of UV curable ink (UV 경화형 잉크의 최적의 경화 Process 확립)

  • Song, Young-Ah;Oh, Sung-Il;Cho, Sung-Nam
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.532-532
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    • 2007
  • UV 경화형 ink를 inkjet printing을 통해 PCB에 patterning 하는 방법에 관한 연구이다. UV 경화형 ink는 일반적으로 ink의 투명도, 색깔, 두께에 따라 완전경화가 밀어나지 않을 수도 있는데 본 연구에서 사용한 UV ink는 particle이 첨가되어 있고 후막 인쇄를 목적으로 하기 때문에 완전경화가 어려웠다. 일반적으로 이러한 UV 경화형 ink의 문제점들을 해결하기 위하여 열경화성 첨가제를 일부 첨가하여 UV에 의한 표면경화와 얼에 의한 속 경화를 진행하는 hybrid system이 사용되고 있지만 본 연구는 PCB를 target으로 하기 때문에 열에 약한 PCB 내의 많은 소자들 때문에 열처리가 쉽지 않은 문제가 있다. 이러한 여러 제약적인 환경에서 UV ink의 완전경화를 위해 경화 process를 최적화 하였으며 10~20um의 후막 인쇄에도 ink가 완전 경화하여 연필경도 9H를 확보하는데 성공하였다.

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UV Nanoimprint Lithography using an Elementwise Patterned Stamp and Pressurized Air (Elementwise Patterned Stamp와 부가압력을 이용한 UV 나노임프린트 리소그래피)

  • Sohn H.;Jeong J.H.;Sim Y.S.;Kim K.D.;Lee E.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.672-675
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    • 2005
  • To imprint 70-nm wide line-patterns, we used a newly developed ultraviolet nanoimprint lithography (UV-NIL) process in which an elementwise patterned stamp (EPS), a large-area stamp, and pressurized air are used to imprint a wafer in a single step. For a single-step UV-NIL of a 4' wafer, we fabricated two identical $5'\times5'\times0.09'(W{\times}L{\times}H)$ quartz EPSs, except that one is with nanopatterns and the other without nanopatterns. Both of them consist of 16 small-area stamps, called elements, each of which is $10\;mm\;\times\;10\;mm$. UV-curable low-viscosity resin droplets were dispensed directly on each element of the EPSs. The volume and viscosity of each droplet are 3.7 nl and 7 cps. Droplets were dispensed in such a way that no air entrapment between elements and wafer occurs. When the droplets were fully pressed between ESP and wafer, some incompletely filled elements were observed because of the topology mismatch between EPS and wafer. To complete those incomplete fillings, pressurized air of 2 bar was applied to the bottom of the wafer for 2 min. Experimental results have shown that nanopatterns of the EPS were successfully transferred to the resin layer on the wafer.

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Effect of Liquid Isoprene Rubber on the Adhesion Property of UV Curable Acrylic Pressure-Sensitive Adhesive (액상 이소프렌 고무가 자외선 경화형 아크릴 점착제의 점착 특성에 미치는 영향)

  • Lee, Jiye;Chung, Kyungho
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.210-219
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    • 2014
  • In this study, the acrylic pressure sensitive adhesive (PSA) for the optical functionality sheet was prepared by blending liquid isoprene rubber. The acrylic PSA was synthesized with butyl acrylate, acrylic acid, 2-ethylhexyl acrylate and 2-hydroxyethyl methacrylate. Toluene was used to a solvent for polymerization. Liquid isoprene rubber (LIR-50) was blended with the acrylic PSA and blend ratio was 0 ~ 50 wt%. According to the results, the adhesive transfer, which was the big problem of acrylic adhesive, was reduced with the addition of LIR-50. The secondary bonding of LIR-50 with substrate did not occurred due to absence of polar group in LIR-50. The peel strength and adhesive transfer were decreased by UV curing and the degreed of decrease depended on the amounts of photoinitiator and UV irradiation time. On the other hand holding power increased drastically by increasing amounts of photoinitiator and UV irradiation time.