• Title/Summary/Keyword: UV absorbance

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A Review of the Efficacy of Ultraviolet C Irradiation for Decontamination of Pathogenic and Spoilage Microorganisms in Fruit Juices

  • Ahmad Rois Mansur;Hyun Sung Lee;Chang Joo Lee
    • Journal of Microbiology and Biotechnology
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    • v.33 no.4
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    • pp.419-429
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    • 2023
  • Ultraviolet C (UV-C, 200-280 nm) light has germicidal properties that inactivate a wide range of pathogenic and spoilage microorganisms. UV-C has been extensively studied as an alternative to thermal decontamination of fruit juices. Recent studies suggest that the efficacy of UV-C irradiation in reducing microorganisms in fruit juices is greatly dependent on the characteristics of the target microorganisms, juice matrices, and parameters of the UV-C treatment procedure, such as equipment and processing. Based on evidence from recent studies, this review describes how the characteristics of target microorganisms (e.g., type of microorganism/strain, acid adaptation, physiological states, single/composite inoculum, spore, etc.) and fruit juice matrices (e.g., UV absorbance, UV transmittance, turbidity, soluble solid content, pH, color, etc.) affect the efficacy of UV-C. We also discuss the influences on UV-C treatment efficacy of parameters, including UV-C light source, reactor conditions (e.g., continuous/batch, size, thickness, volume, diameter, outer case, configuration/arrangement), pumping/flow system conditions (e.g., sample flow rate and pattern, sample residence time, number of cycles), homogenization conditions (e.g., continuous flow/recirculation, stirring, mixing), and cleaning capability of the reactor. The collective facts indicate the immense potential of UV-C irradiation in the fruit juice industry. Existing drawbacks need to be addressed in future studies before the technique is applicable at the industrial scale.

Changes in Molecular Weight of Dissolved Organic Matter by Photodegradation and their Subsequent Effects on Disinfection By-Product Formation Potential (광분해에 의한 용존 유기물질의 분자량 변화가 소독부산물 생성능에 미치는 영향)

  • Lim, Jung-Hee;Hur, Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.769-775
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    • 2013
  • UV-induced transformations in the characteristics of dissolved organic matter (DOM) and the subsequent effects on the disinfection by-product formation potential (DBPFP) were investigated using the mixtures of the two humic substances with different sources, and two different size fractions of Suwannee River fulvic acid (SRFA). 7 day-photodegradation resulted in the decrease of specific ultraviolet absorbance (SUVA) of the mixtures as well as the specific DBPFP. After the irradiation, however, higher specific DBPFP values were consistently observed at the same range of the SUVA values. This suggests that non UV-absorbing components, generated by the UV-irradiation, may contribute to the formation of DBPs. Two different molecular size fractions of SRFA showed dissimilar responses to photodegradation. The behavior was also influenced by the types of the DBPs generated. Higher levels of trihalomethenes (THMs) were formed per organic carbon for the high molecular fraction compared to the low molecular fraction, whereas no differences were found in the formation of haloacetic acids (HAAs) between the two different size fractions. The formation of the two types of DBPs also differed by the irradiation times. Specific formation potential of THMs consistently increased upon the irradiation, whereas HAAs showed the initial increase followed by the decrease in their specific formation potential.

Dyeability and Functionality of Chaenomelis Fructus Extract (모과 추출물의 염색성과 기능성)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Fashion & Textile Research Journal
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    • v.14 no.3
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    • pp.478-485
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    • 2012
  • The dying properties of fabrics with Chaenomelis Fructus extract were studied through an investigation of the characteristic of Chaenomelis Fructus colorants, the effect of dyeing conditions (dye temperature, dyeing concentration, and times on dye uptakes), effect of mordant, effect of UV irradiation, and color change in addition, antimicrobial ability and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of maximum absorption of Chaenomelis Fructus extract was 280 nm and showed that tannin is the major pigment component. From the increase of absorbance by UV irradiation, it was assumed that catechol tannin color was developed through UV irradiation. An increased dyeing concentration resulted in a larger dye uptake. Dye uptake increased as the dyeing time and temperature increased. Chaenomelis Fructus extract showed relatively good affinity to silk than cotton. Mordant, Fe and Cu were effective to increase the dye uptake of cotton fabric in addition, the dye uptake of silk fabric mordanted with Fe and K improved. UV irradiation let the color of dyed fabrics develop regardless of the UV irradiation stage however, UV irradiation on the dyed fabric was more effective than on the extract for the color development. Dyed silk fabric showed very good antimicrobial abilities of 99.9% in addition, deodorant ability improved in the fabric dyed with Chaenomelis Fructus extract.

Physical Properties of UV curable coating on plastic (플라스틱용 자외선경화형 도료의 물성연구)

  • 김일재;문명준
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.61-80
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    • 1998
  • To investigate in influence of photosensitizer used with benzophenone(BP) in the curing rate and physical properties of UV curable hard coating on plastic, we prepared UV curable clear and pigmented coatings with DEA, DMA, NPM and TEA as photosensitizer, respectively. The curing rate calculated from the decrease of the absorbance of acrylic double bond measured by FT-IR spectroscopy increased s follows; DEA>DMA>NPM>TEA. this order could be explained by the reactivity of diethylamino group of DEA and the ease of formation of activated complex between BP and photosensitizer during the curing process. In UV curable pigmented coatings, the order of curing rate increased as follows; DEA>DMA>TEA>NPM. It was found that the curing rate of the pigmented coating can be increased by light scattering of TiO$_2$. The hardness of coating film cured by photosensitization of DEA and DMA is higher than other photosensitizers due to the crosslinking reaction of DEA and DMA radical bound to polymer backbone.

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Impact of Water Quality on the Formation of Bromate and Formaldehyde during Water Ozonation

  • Lee, Chung-Youl;Lee, Yoon-Jin
    • Journal of Environmental Health Sciences
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    • v.33 no.5
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    • pp.441-450
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    • 2007
  • 본 연구는 humic acid 및 bromide를 함유한 상수 원수에 오존 처리를 수행함에 있어 수질 특성 및 공정조건에 따른 bromate 및 formaldehyde 의 생성을 고찰하였다 . 회분식 실험장치를 이용하여 오존의 주입농도, DOC 농도, bromide 농도, pH, 알칼리도 및 반응 시간을 변화시키면서 오존처리 시 생성되는 대표적인 부산물인 bromate 및 formaldehyde의 거동을 파악하였다. 본 연구에서 검토된 영향 인자 중 수중의 pH조건은 bromate 및 formaldehyde의 생성에 가장 중요한 인자로 나타났다. DOC(dissolved organic carbon) 농도가 증가할수록 bromate 생성은 감소하였고 formaldehyde 의 생성은 증가하였다. 오존처리를 통해 UV254 는 효율적으로 감소되었고, UV254의 감소율 및 오존 농도는 선형 관계를 나타냈다.

Determination of Memantine HCl by UV Spectrophotometry using MPCN as an UV-labelling Reagent (자외부 유도화제인 MPCN을 이용한 memantine HCl의 정량)

  • Jang, Sun-Sook;Choi, Jung-Kap;Yoo, Gyurng-Soo
    • Analytical Science and Technology
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    • v.6 no.4
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    • pp.405-409
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    • 1993
  • Spectrophotometric assay for memantine HCl was developed by using sodium 1-(4-methoxypheyl) cinnamonitrile-2-sulfonate (MPCN) as an UV labelling reagent. The optimum derivatizing condition was obtained by incubation for 30 min at pH 5.0 in the presence of 20-fold molar excess of the labelling reagent. The absorbance of reaction product was measured at 324.5 nm and detection limit was $0.43{\mu}g/ml$. A linear range was $5.0{\times}10^{-6}{\sim}6.5{\times}10^{-5}M$ of memantine HCl. The linear regression analysis of absorbance at various drug concentration was r=0.9998 (n=6). When applied to memantine HCl ampule and tablet, it gave the mean contents of $100.08{\pm}0.72%$ and $99.75{\pm}0.77%$, respectively.

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Characterization of Humic Acid in the Chemical Oxidation Technology(II) - Characteristics by Ozonation - (화학적 산화법에 의한 부식산의 분해처리 기술에 관한 연구(II) - 오존처리에 따른 분해특성 분석 -)

  • Rhee, Dong Seok;Jung, Young-Rim
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.241-249
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    • 2000
  • In this paper, ozonation of humic acid in water was characterized using $UV_{254}$ absorbance, TOC, Ultra Filtration and $^{13}C-NMR$. Also, carbonyl compounds in ozonated water were analyzed by GC/MS using PFBOA method. Ozonation by-products of water containing humic acid were determined as formaldehyde, acetaldehyde, acetone, glyoxal and methylglyoxal. Results of $UV_{254}$ absorbance and TOC with ozonation time at humic acid 20, 100ppm represent that decrease rate of 80% within ozonation time is 20 min and TOC removal rate of 40-50% within ozonation time is 30 min. Results for $^{13}C-NMR$ and Ultra Filtration, humic acid of high molecular weight by ozonation are oxidated and decomposed so that it was conversed low molecular weight such as aldehydes, carboxylic acid.

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Advanced Water Treatment of High Turbidity Source by Hybrid Process of Ceramic Microfiltration and Activated Carbon Adsorption: Effect of Organic Materials in $N_2$-back-flushing (세라믹 정밀여과 및 활성탄 흡착 혼성공정에 의한 고탁도 원수의 고도정수처리: 질소 역세척 시 유기물의 영향)

  • Park, Jin-Yong;Park, Gil-Yong
    • Membrane Journal
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    • v.19 no.3
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    • pp.203-211
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    • 2009
  • In this study, we used the hybrid module that was composed of granular activated carbons (GAC) packing between module inside and outside of tubular ceramic microfiltration membrane for advanced drinking water treatment. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, modified solution was prepared with humic acid and kaolin. $N_2$-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling and to improve permeate flux (J). As a result, resistance of membrane fouling ($R_f$) decreased and J increased as concentration of humic acid changed from 10 mg/L to 2 mg/L step by step, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiencies of turbidity and $UV_{254}$ absorbance were excellent above 99.36% and 97.19%, respectively, but that of $UV_{254}$ absorbance for only microfiltration without GAC at 10 mg/L of humic acid was decreased a little as 90.84%.

Advanced Water Treatment by Hybrid Process of Multi-channel Ceramic MF and Photocatalyst: Effect of Organic Materials (광촉매 및 다채널 세라믹 정밀여과 혼성공정에 의한 고탁도 원수의 고도정수처리: 유기물의 영향)

  • Amarsanaa, Bolor;Park, Jin-Yong
    • Membrane Journal
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    • v.21 no.4
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    • pp.351-359
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    • 2011
  • For advanced drinking water treatment of high turbidity water, we used the hybrid process that was composed of photocatalyst packing in space of between outside of multi-channel ceramic microfiltration membrane and membrane module inside. Photocatalyst was polypropylene (PP) beads coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, standard NOM solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) increased and J decreased as concentration of humic acid changed from 2 mg/L to 10 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiency of turbidity and $UV_{254}$ absorbance were above 96.4% and 78.9%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in (MF), (MF + $TiO_2$), (MF + $TiO_2$ + UV) processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of $UV_{254}$ absorbance by adsorption (MF + $TiO_2$) and photo-oxidation (MF + $TiO_2$ + UV) at humic acid of 4 mg/L and 6 mg/L were above 9.0, 9.5 and 8.1, 10.9%, respectively.

Comparison of flux and natural sapphire after heat-treatment (열처리 후 플럭스 사파이어와 천연 사파이어의 비교 분석)

  • Kim, Ki-In;Ahn, Yong-Kil;Seo, Jin-Gyo;Park, Jong-Wan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.3
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    • pp.152-158
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    • 2009
  • Various fabrication methods have been used to synthesize sapphire which has qualities of jewelry well beyond the industrial class. Among them, the flux sapphire of Chatham Company which has as high value as jewelry was selected in order to compare natural and synthetic sapphire. First, the WD-XRF (Wavelength dispersive x-ray fluorescence spectrometer) was used to analyze the chemical composition of natural and synthetic sapphire. Although natural sapphire had very diverse chemical compositions, flux sapphire had small quantities of Mo, Pt and Pb elements in addition to the similar chemical ingredients to natural one. Pt is decisive proof of flux sapphire. Next, by investigating spectroscopic characteristics using UV-VIS Spectrophotometer after heat treatment at high temperatures of $1300^{\circ}C$ and $1500^{\circ}C$, the variation of 690 nm absorbance related to $Cr^{3+}$ was detected in the natural sapphire while those of the 690 nm absorbance (related to $Cr^{3+}$) as well as absorbance of 376 nm and 388 nm ($Fe^{3+}$) were seen in the flux sapphire. It was found that the difference in the absorbance variation of flux sapphire is greater than that of natural sapphire after heat treatment. The chemical composition and spectrum analysis were utilized to compare the natural sapphire and the flux synthetic sapphire.