• 제목/요약/키워드: UV Intensity

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Study on UV Opto-Electric Properties of ZnS:Mn/ZnS Core-Shell QD

  • Lee, Yun-Ji;Cha, Ji-Min;Yoon, Chang-Bun;Lee, Seong-Eui
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.55-60
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    • 2018
  • In this study, quantum dots composed of $Mn^{2+}$ doped ZnS core and ZnS shell were synthesized using MPA precursor at room temperature. The ZnS: Mn/ZnS quantum dots were prepared by varying the content of MPA in the synthesis of ZnS shells. XRD, Photo-Luminescence (PL), XPS and TEM were used to characterize the properties of the ZnS: Mn/ZnS quantum dots. As a result of PL measurement using UV excitation light at 365 nm, the PL intensity was found to greatly increase when MPA was added at 15 ml, compared to the case with no MPA; the PL peaks shifted from 603 nm to 598 nm. A UV sensor was fabricated by using a sputtering process to form a Pt pattern and placing a QD on the Pt pattern. To verify the characteristics of the sensor, we measured the electrical properties via irradiation with UV, Red, Green, and Blue light. As a result, there were no reactions for the R, G, and B light, but an energy of 3.39 eV was produced with UV light irradiation. For the sensor using ZnS: Mn/ZnS quantum dots, the maximum current (A) value decreased from $4.00{\times}10^{-11}$ A to $2.62{\times}10^{-12}$ A with increasing of the MPA content. As the MPA content increases, the PL intensity improves but the electrical current value dropped because of the electron confinement effect of the core-shell.

Purification and Characterization of a Novel 21 kD Calcium Binding Protein from Dunaliella salina

  • Ko, Jae-Heung;Lee, Sun-Hi
    • Journal of Plant Biology
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    • v.39 no.3
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    • pp.173-177
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    • 1996
  • A novel calcium binding protein (CaBP) was purified to electrophoretic homogeneity from Dunaliella salina. In the course of purification experiment, this CaBP was identified as a monomer and its molecular weight was about 21 kDand isoelectric point (pI) value was about 4.1 using isoelectrofocusing. This CaBP was able to bind Ca2+ even in the pressence of an excess MgCl2 and KCI both in solution. In the SDS-PAGE, the Ca2+-bound form was slower than the Ca2+-free form in the nondenaturing PAGE. This means that the CaBP undergoes conformational change in the Ca2+-bound condition. Furthermore, UV absorption spectrum and fluorescence intensity of this CaBP was investigated. UV absorption peak was appeared at about 258 nm and decreased somewhat in Ca2+-bound condition. In the measurement of fluorescence, maximum intensity was appeared at 303 nm and decreased in Ca2+-bound state, similarly as UV absorption spectrum. These show distinct changes upon Ca2+-binding, which indicate of structural and/or dynamic changes largely reminiscent of other members of the EF-hand Ca2+-binding protein family.

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MODEL CALCULATIONS OF THE UV - EXCITED MOLECULAR HYDROGEN IN INTERSTELLAR CLOUDS

  • Lee, Dae-Hee;Pak, Soo-Jong;Seon, Kwang-Il
    • Publications of The Korean Astronomical Society
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    • v.20 no.1 s.24
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    • pp.7-10
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    • 2005
  • We have calculated 2448 interstellar cloud models to investigate the formation and destruction of high rotational level $H_2$ according to the combinations of five physical conditions: the input UV intensity, the $H_2$ column density, cloud temperature, total density, and the $H_2$ formation rate efficiency. The models include the populations of all the accessible states of $H_2$ with the rotational quantum number J < 16 as a function of depth through the model clouds, and assume that the abundance of $H_2$ is in a steady state governed primarily by the rate of formation on the grain surfaces and the rates of destruction by spontaneous fluorescent dissociation following absorption in the Lyman and Werner band systems. The high rotational levels J = 4 and J = 5 are both populated by direct formation into these levels of newly created molecules, and by pumping from J = 0 and J = 1, respectively The model results show that the high rotational level ratio N(4)/N(0) is proportional to the incident UV intensity, and is inversely proportional to the $H_2$ molecular fraction, as predicted in theory.

The Synthesis of (Y,Gd)$BO_3:Eu^{3+}$Phosphor by Ultrasonic Spray and Their Photoluminance Properties (초음파 분무에 의한 (Y,Gd)$BO_3:Eu^{3+}$ 형광체의 제조와 이의 발광 특성)

  • 김대수;김성우;이임렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.107-110
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    • 1999
  • The ultrasonic spray method was employed to make (Y,Gd)BO$_3$:Eu Phosphor, and its optical properties under 147nm VUV and 254 nm UV excitations were characterized and then compared with that produced by the solid-state reaction. The mixed solution of acetate hydrates of Y, Gd, Eu and boric acid diluted in water or methanol was used as the precursor fur the spray. It was found that (Y,Gd)BO$_3$:Eu phosphor made by this ultrasonic spray had a spherical shape and fine particle size of 1${\mu}{\textrm}{m}$. The crystalline structure for the as-sprayed phosphor was amorphous, but it converted into the same polycrystalline phase of solid state reaction after post heat treatment at 110$0^{\circ}C$ for 2hr. The emitting intensity under VUV and UV excitations for the spray-formed (Y,Gd)BO$_3$:Eu phosphor, however, was inferior to the later one. The excitation spectra were also studied and compared under VUV and UV excitations to explain the change of emitting intensity with Gd substitution in (Y$_{1-x}$ Gd$_{x}$)BO$_3$:Eu Phosphors made by spray and solid state reaction.on.

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Morphological Changes of Hair Structure by UV Irradiation (자외선 조사에 의한 모발구조의 형태학적 변화)

  • Kim, Jung-Hoan;Lee, Ok-Sub;Han, Ji-Sook;Shin, Sung-Yeon;Baek, Doo-Hyun;Ha, Byung-Jo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.4
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    • pp.311-316
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    • 2008
  • In this study, we have investigated the effects of ultraviolet (UV) irradiation on the external and internal structure of human hair. For changes in morphological and chemical structure of UV-exposed hair, we utilized several microscopic techniques such as scanning electron microscope (SEM), transmission electron microscope (TEM), confocal laser scanning microscope (CLSM), and etc. The SEM showed the scales of UV-exposed hair appeared to be rough and bulkier because of chemical oxidation during UV irradiation. Small bulgy area of UV_exposed hair surface was appeared as a result of the decomposition in cysteic acid. In the TEM picture the UV-exposed hair showed the cleaved aperture of hair and destruction of melanin granules. Three dimensional topographical images were obtained by using CLSM. In the optical single section, high fluorescent intensity appeared in virgin hair. In the case of UV-exposed hair, low fluorescence intensity appeared. This means the aromatic amino acids in virgin hair were more abundant than UV-exposed hair.

A Study on the Dye Wastewater Treatment Using TiO2 Photocatalyst/Ozonation (광촉매/오존을 이용한 염색폐수처리에 관한 연구)

  • Kim, Chang-Kyun;Chung, Ho-Jin;Kim, Jong-Suk
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.663-670
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    • 2007
  • This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis and ozonation for the treatment of dye wastewater. The treatability of dye wastewater by $UV/TiO_2$ and $UV/TiO_2/O_3$ advanced oxidation process (AOP) was investigated under various conditions. The experiments were conducted in a batch reactor of 50 liters equipped with twelve UV Lamps of 16W. In $UV/TiO_2$ AOP, the removal efficiency of TCODMn and Color increased to 58% and 67% respectively with increasing UV intensity. Also, The removal efficiency of TCODMn and Color increased to 97% and 99% respectively with increasing $H_2O_2$. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and pH 5 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, TCODMn was removed faster than Color.

Spectral-shape-controllable Chirped Fiber Bragg Grating with a Photomechanical Microactuator: Simulation and Experiment

  • Moon, Jong-Ju;Ko, Youngmin;Park, Su-Jeong;Ahn, Tae-Jung
    • Current Optics and Photonics
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    • v.4 no.6
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    • pp.477-482
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    • 2020
  • Recently, one of the authors has been reported an optically tunable fiber Bragg grating (FBG) with a photomechanical polymer. It was based on a typical FBG with a downsized diameter of 60 ㎛, coated with azobenzene-containing polymer material. Azobenzene is a well-known reversibly photomechanical stretchable material under ultraviolet (UV) light. The small part of the functional-coating region on the FBG absorbed UV light, which pulled the UV-exposed part of the grating. It was selectable as tunable FBG or tunable chirped FBG, by adjusting the position of UV exposure on the grating. As proof of concept for the tunable FBG device, the characteristics just including UV-induced center-wavelength shift and spectral-width changes of the device were reported. In this paper, we report for the first time that the microactuator makes it possible to control the spectral shape of the FBG reflection, according to the specifications (shape and intensity) of the UV beam that reaches the FBG coated with the azobenzene polymer. In addition, we provide the group-delay profiles for the chirped FBG, so that the sign of its dispersion (normal or anomalous) can be tailored by simply selecting the moving direction of the UV light's displacement in the experiment.

Inactivation Effect of Cryptosporidium by Ozone and UV (Ozone과 UV를 이용한 Cryptosporidium의 불활성화 효과)

  • Kim, Yun-Hee;Lee, Chul-Hee;Lee, Shun-Hwa
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.1
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    • pp.31-39
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    • 2007
  • The objective of this study was to investigate the inactivation characteristics of Cryptosporidium oocysts by ozone and UV and to suggest the better, disinfection method. The inactivation CT value of 1 log(90%) and 2 log(99%) in of one disinfection, which is an index of disinfection for inactivation effect by ozone, were respectively 5.77 $mg{\cdot}min/L$ and 21.30 $mg{\cdot}min/L$. The inactivation in UV disinfection was not affected by pHs(5, 7 and 9), low turbidity(5 and below NTU) and UV intensity(0.2 and 0.6 $mWs/cm^2$) but obviously decreased at high turbidity over 20 NTU. Therefore UV disinfection capacity can be obtained when a good turbidity removal in drinking water treatment process is achieved. And if oocysts is exposed by high UV over 0.6 mWs/cm2 during enough time, the better inactivation effect will be obtained.

A Comprehensive Study for Two Damage Sites of Human Hair upon UV-B Damage

  • Song, Sang-Hun;Son, Seongkil;Kang, Nae Gyu
    • Korea Journal of Cosmetic Science
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    • v.2 no.1
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    • pp.1-10
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    • 2020
  • Protection mechanisms for skin damage of ultraviolet (UV) absorbers in personal care products for protection against UV are well studied, but not for hair protection. The purpose of this study is to describe and compare the changes of physical property produced in human hair by doses of the UV-B exposure causing protein degradation. To observe the change of physical properties in hair, the experimental intensity of UV-B exposure has been established on the basis of statistical data from official meterological administration as daily one hour sunlight exposure for two weeks. Polysilicone-15, ethylhexyl methoxycinnamate (OMC), and octocrylene were employed for UV-B absorber, and those were treated to hair swatch by rubbing wash through shampoo and conditioner. Bending rigidity displayed kinetically successive reduction at high doses of UV exposure up to the 8,000 s, and exhibited different level at each sample of UV-B absorber. However, the values of Bossa Nova Technologies (BNT) for shinning factor were already saturable at the 2,000 s exposure except that treated with polysilicone-15. The differential scanning calorimetry (DSC) to measure a strength of inner protein produces a successive reduction of enthalpy as like a reduction of bending rigidity upon UV exposure. Surface roughness from lateral force microscope (LFM) acquired immediately after UV exposure show a saturable frictional voltage which has been also found in a saturable BNT data as the time of UV exposure increases. Through researching the DSC and the LFM, shinning of hair was much correlated to the protein damage at the surface, and bending rigidity could be regulated by the protein structural damage inside hair. Therefore, the optimization of efficient strategy for simultaneous prevention of hair protein on the surface and internal hair was required to maintain physical properties against UV.

Removal of Bisphenol-A using Rotating Photocatalytic Oxidation Drum Reactor (RPODR)

  • Son, Hee-Jong;Jung, Chul-Woo;Kim, Seung-Hyun
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.197-202
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    • 2008
  • This study evaluated the photocatalytic oxidation of BPA using the RPOD reactor under various conditions. This study found that the RPOD was effective for BPA degradation. It could reduce 1 mg/L of BPA by half within 5 min under the optimum conditions. According to the study results, $TiO_2$ coating was important for the BPA oxidation. As the coating thickness increased, the removal efficiency improved. The light source, the light intensity and the drum rotating speed were important for the oxidation. The UV light was more effective for the BPA degradation than the visible light. The removal efficiency improved with increasing intensity. As the drum speed increased, the removal efficiency improved. The maximum speed was 240 rpm in this study. Addition of air and nitrogen was not beneficial for the BPA degradation in this study probably due to enough oxygen in the water.