• Title/Summary/Keyword: UV Efficiency

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Effect of Methyl Ethyl Ketone and Ethyl Acetate Vapor on Photocatalytic Decomposition of n-Pentane Vapor (n-Pentane 증기의 광촉매 분해 시 Methyl Ethyl Ketone 증기와 Ethyl Acetate 증기의 영향)

  • Kam, Sang-Kyu;Jeon, Jin-Woo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.23 no.6
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    • pp.1151-1156
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    • 2014
  • The photocatalytic decomposition characteristics of single n-pentane, n-pentane mixed with methyl ethyl ketone (MEK), and n-pentane mixed with ethyl acetate (EA) by cylindrical UV reactor installed with $TiO_2$-coated perforated plane were studied. The effects of the residence time, the inlet gas concentration, and the oxygen concentration were investigated. The removal efficiency of n-pentane was increased with increasing the residence time and the oxygen concentration, but decreased with increasing the inlet concentration of n-pentane. The photocatalytic decomposition rates of single n-pentane, n-pentane mixed with MEK, and n-pentane mixed with EA fitted well on Langmuir-Hinshelwood kinetics equation. The maximum elimination capacities of single n-pentane, n-pentane mixed with MEK, and n-pentane mixed with EA were obtained to be $465g/m^3{\cdot}day$, $217g/m^3{\cdot}day$, and $320g/m^3{\cdot}day$, respectively. The presence of coexisting MEK and EA vapor had a negative effect on the photocatalytic decomposition of n-pentane and the negative effect of MEK was higher than that of EA.

Preparation of TiO2:Fe,V nanoparticles by flame spray pyrolysis and photocatalytic degradation of VOCs (화염분무열분해법을 이용한 TiO2:Fe,V 나노분말의 제조 및 VOCs 분해 특성)

  • Chang, Han Kwon;Jang, Hee Dong;Kim, Tae-Oh;Kim, Sun Kyung;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.5 no.1
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    • pp.1-7
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    • 2009
  • Fe- and V-doped titanium dioxide nanoparticles consisting of spherical primary nanoparticles were synthesized from a mixed liquid precursor by using the flame spray pyrolysis. The effects of dopant concentration on the powder properties such as morphology, crystal structure, and light adsorption were analyzed by TEM, XRD, and UV-Vis spectrophotometer, respectively. As the V/Ti molar ratio increased, pure anatase particles were synthesized. On the contrary, rutile phase particles were synthesized as the Fe/Ti ratio increased. Photocatalytic property of as-prepared $TiO_2:Fe,V$ nanoparticles was investigated by measuring the removal efficiency for volatile organic compounds (VOCs) under the irradiation of visible light. After 2 hrs under visible light, the removal efficiencies of benzene, p-xylene, ethylbenzene, and toluene were reached to 21.9%, 21.4%, 19.8% and 17.6% respectively.

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UV pumped three color phosphor blend White emitting LEDs

  • Choi, Kyoung-Jae;Park, Joung-Kyu;Kim, Kyung-Nam;Kim, Chang-Hae;Kim, Ho-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1338-1342
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    • 2005
  • We have synthesized an $Eu^{2+}$-activated $Sr_3MgSi_2O_8$ blue phosphor and $Ba_2SiO_4$ green phosphor and $Ba^{2+}$ co-doped $Sr_3SiO_5$ red phosphor investigated an attempt to develop white LEDs by combining it with a GaN blue LED $chip(\lambda_{em}=405 nm)$. Three distinct emission bands from the GaN-based LED and the $(Sr_3MgSi_2O_8:Eu\; +\; Ba_2SiO_4:Eu\; +\; Ba^{2+}\; co-doped\; Sr_3SiO_5:Eu)$ phosphor are clearly observed at 460nm, 520 nm and at around 600 nm, respectively. These three emission bands combine to give a spectrum that appears white to the naked eye. Our results show that GaN (405 nm chip)-based $(Sr_3MgSi_2O_8:Eu\; +\; Ba_2SiO_4:Eu\; +\; Ba^{2+}\; co-doped\; Sr_3SiO_5:Eu) exhibits a better luminous efficiency than that of the industrially available product InGaN (460 nm chip)-based YAG:Ce.

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Synthesis of Spherical Carbons Containing Titania and Their Physicochemical and Photochemical Properties

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Meng, Ze-Da;Choi, Jong-Geun;Zhang, Kan
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.6-13
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    • 2011
  • In this study, we used activated carbon (AC) and charcoal (CH) as carbon sources with $TiO_2$ powder to prepare spherical carbons containing titania (SCCT) by using phenolic resin (PR) as a bonding agent. The physicochemical characteristics of the SCCT samples were examined by BET, XRD, SEM, EDX, iodine adsorption and compressive strength. The photocatalytic activity was evaluated by measuring the removal efficiency of three kinds of organic dyes: methylene blue (MB), methyl orange (MO) and rhodamine B (Rh.B) under a UV/SCCT system. In addition, evaluation of chemical oxygen demand (COD) of piggery waste was done at regular intervals and gave a good idea about the mineralization of wastewater.

Air sterilization using filter and air ions: A review (필터와 이온을 이용한 공기살균법 연구동향)

  • Woo, Chang Gyu;Kim, Hak-Joon;Kim, Yong-Jin;Han, Bangwoo
    • Particle and aerosol research
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    • v.12 no.3
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    • pp.73-80
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    • 2016
  • Bioaerosol inactivation becomes important as people recognize the significance on the health effects of bioaerosols. There are several ways to inactivate such bioaerosols such as antimicrobial filters, UV, etc. For the on-filter-inactivation, proper antimicrobial materials coating should be applied. Recently, air ions are adopted to effectively reduce germ and virus activity. Limitations arise when each method is applied separately. Coating materials can experience chemical instability over time and temperature. Ionizers can generate ozone to prepare high ion concentrations. Combinations of developed techniques to enhance the inactivation efficiency were suggested. Researches on the air sterilization are reviewed and outlook is highlighted. Proper techniques such as combinations of filter material coating and air ion generation can be used to make air quality better for human living.

Dyeing properties of Protein Fabrics by Cassia tara Extracts (결명자 추출액에 의한 단백질계 섬유의 염색성)

  • 문명희
    • Journal of the Korean Society of Costume
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    • v.49
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    • pp.73-84
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    • 1999
  • The purpose of this study was to investigate dyeing properties of silk and wool fabric by Cassia tora extracts according to the conditions such as extraction(temperature time) dyeing(temperature time) condition kinds of mordants temperature of mordanting. The color fastness of laundering irradiation were examined. The results were as follows: The wavelength of maximum absorpthion by extracts appeared at 201, 277, 382nm in UV-Vis spectrum. Absorbance of extracts were increased with temperature and time. The extraction efficiency of Cassia tora was determined as $95^\circ{C}$ of extraction temperature 120 minutes of extraction time. Silk fabric had highest K/S value when dyeing for 90min at $40^\circ{C}$. Wool fabric had highest K/S value when dyeing for 60min at $80^\circ{C}$. Surface color of silk and wool fabric dyed with Cassia tora extracts was 3,9Y and 0.4Y but it was changed from 9.3YR to 7,4Y and from 9.4YR to 5Y by mordants. The fabrics of mordanted by metal ion dyed the depth of color. Laundering and irradiation fastness of mordanted fabrics were improved as compared with nonmordanted fabrics.

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Evaluation of brine reuse on salting of chinese cabbage using electrochemical process (전기화학적 처리에 의한 배추 절임염수 재이용 가능성 평가)

  • Jung, Heesuk;Lee, Eunsil;Han, Seongkuk;Han, Eungsoo
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.5
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    • pp.541-548
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    • 2014
  • The pickling brine generated from the salting process of kimchi production is difficult to treat biologically due to very high content of salt. When pickling brine is treated and discharged, it cannot satisfy the criteria for effluent water quality in clean areas, while resources such as the salt to be recycled and the industrial water are wasted. However, sterilization by ozone, UV and photocatalyst is expensive installation costs and operating costs when considering the small kimchi manufacturers. Therefore there is a need to develop economical process. The study was conducted on the sterilization efficiency of the pickling brine using electrochemical processing. The electrochemical treatment of organic matters has advantages over conventional methods such as active carbon absorption process, chemical oxidation, and biological treatment because the response speed is faster and it does not require expensive, harmful oxidizing agents. This study were performed to examine the possibility of electrochemical treatment for the efficient processing of pickling brine and evaluated the performance of residual chlorine for the microbial sterilization.

Dispersal of Molecular Clouds by UV Radiation Feedback from Massive Stars

  • Kim, Jeong-Gyu;Kim, Woong-Tae;Ostriker, Eve
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.38.1-38.1
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    • 2017
  • We report the results of three-dimensional radiation hydrodynamic simulations of star cluster formation in turbulent molecular clouds, with primary attention to how stellar radiation feedback controls the lifetime and net star formation efficiency (SFE) of their natal clouds. We examine the combined effects of photoionization and radiation pressure for a wide range of cloud masses (10^4 - 10^6 Msun) and radii (2 - 80 pc). In all simulations, stars form in densest regions of filaments until feedback becomes strong enough to clear the remaining gas out of the system. We find that the SFE is primarily a function of the initial cloud surface density, Sigma, (SFE increasing from ~7% to ~50% as Sigma increases from ~30 Msun/pc^2 to ~10^3 Msun/pc^2), with weak dependence on the initial cloud mass. Control runs with the same initial conditions but without either radiation pressure or photoionization show that photoionization is the dominant feedback mechanism for clouds typical in normal disk galaxies, while they are equally important for more dense, compact clouds. For low-Sigma clouds, more than 80% of the initial cloud mass is lost by photoevaporation flows off the surface of dense clumps. The cloud becomes unbound within ~0.5-2.5 initial free-fall times after the first star-formation event, implying that cloud dispersal is rapid once massive star formation takes place. We briefly discuss implications and limitations of our work in relation to observations.

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Effect of Solar Cell Cover Glass on Solar Cell Performance (태양전지 보호유리가 태양전지 성능에 미치는 영향)

  • Choi, Young-Jin;Wang, Jin-Suk
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1421-1423
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    • 1996
  • In this study, the effect of solar cell cover glass on the solar cell performance is evaluated. Silicon solar cell (active area:4*6cm, efficiency:12.6% at AMO condition) is used for this study. ITO(Indium tin Oxide) film thickness of the ITO/AR/substrate glass/solar cell structure samples are $40{\AA}$, $60{\AA}$, $160{\AA}$, $240{\AA}$ respectively. The solar cell maximum output power on the stacking structure variations showed 465mW in the AR/ITO/substrate glass/solar cell, and minimum output power showed 403mW in the AR/substrate glass/solar cell. The maximum output power of the solar cell on the ITO thickness variations of the ITO/AR/substrate glass/solar cell showed 460mW at $40{\AA}$ then decrease output power as ITO thickness increase. For environment tests, all samples are exposed UV light in the vacuum chanber. The output power degradation of AR(UVR)/substrate glass/solar cell stacking structure is small compared with ITO/AR(UVR)/substrate glass/solar cell stacking structure.

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Characterization of Morphology Controlled Fluorine-doped SnO2 Thin Films

  • An, Ha-Rim;An, Hye-Lan;Ahn, Hyo-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.453.1-453.1
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    • 2014
  • Fluorine-doped tin oxide (FTO), which is commonly used in dye-sensitized solar cells (DSSCs), is a promising material of transparent conducting oxides (TCOs) because of advantages such as high chemical stability, high resistance, high optical transparency (>80% at 550nm), and low electrical resistivity (${\sim}10-4{\Omega}{\cdot}cm$). Especially, dye-sensitized solar cells (DSSCs) have been actively studied since Gratzel's research group required FTO substrate as a charge collector. When FTO substrates are used in DSSCs, photo-injected electrons may experience recombination at interface between dye-bonded semiconductor oxides ($TiO_2$) on FTO substrate and the electrolyte. To solve these problems, one is that because recombination at FTO substrate cannot be neglected, thin $TiO_2$ layer on FTO substrate as a blocking layer was introduced. The other is to control the morphology of surface on FTO substrate to reduce a loss of electrons. The structural, electrical, and optical characteristics of morphology controlled-FTO thin films as TCO materials were analyzed by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Hall Effect Measurement, and UV spectrophotometer. The performance of DSSCs fabricated with morphology controlled FTO substrates was performed using Power Conversion Efficiency (PCE). We will discuss these results in detail in Conference.

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