• 미생물학회지
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• 제25권2호
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• pp.117-121
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• 1987

오존가스에 감수성이 있는 균주와 저항성을 갖는 여러 종류의 E. coli B를 숙주로 사용하여 T3파아치에 자외선 혹은 오존을 처리하므로서 획득된 재활성 요인에 대하여 실험하였다. 그 결과 오존가스는 소위 SOS기능 단위의 하나인 Weigle효과 (=자 외선 회복)의 유도원우로서 전연 작용하지 못하꺼냐 작용이 미약함을 알 수 있었는데 이 분야의 다륜 보문에서도 일치된 경향을 나타내고 있음을 확인하였다.

• 한국환경보건학회지
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• 제29권1호
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• pp.74-83
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• 2003

Microcystin, stable compounds with circular heptapeptides, is presented inside cyanobacterial cell. So far, over 30 types have been known to exist and microcystin-LR, RR among them are the most potent toxin compound. By this reason, a strong oxidant, ozone was used in this study to remove the microcystins produced by cyanobacteria. Removal efficiency of microcystin at M water treatment plant was also evaluated. Microcystin concentration was determined by protein phosphatase inhibition assay. The results showed that dissolved microcystin in raw water detected in the range of 0.011-0.028 ㎍ Microcystin-RR equivalent/l. Above 98% of microcystin was removed through overall treatment system. Therefore, the water treatability of M treatment plant seemed to be excellent. Removal efficiency of microcystin according to unit process varied as characteristics of raw water such as DOC, UV/sub 254/ and turbidity. Removal efficiency of microcystin by ozonation was investigated in laboratory according to contact time and ozone dose. Dissolved microcystin was increased by twice fold according to ozone contact time, but increased by fifth fold according to ozone dose. So, changing of ozone dose more affected microcystin release than changing of ozone contact time. Behavior of microcystin by ozonation was similar to that of DOC, and residual ozone concentration gave influence to removal ratio of microcystin. In conclusion, single ozone treatment wasn't effective on microcystin removal in case of water containing a lot of cells. Therefore, it's more effective to use ozonation process after the removal of cyanobacterial cells in advance.

• 펄프종이기술
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• 제34권4호
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• pp.22-29
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• 2002

This research was conducted to investigate the morphological characteristics of fine fibers produced during beating process of high yield pulp treated with ozone and the distribution of lignin in the produced fine fibers. Thermomechanical(TMP) pulp and chemithermomechanical(CTMP) pulp of spruce and CTMP of white birch were beaten to reach 200$m\ell$ CSF, and then the fine fibers were observed using ultraviolet microscope. The fine fibers produced from TMP and CTMP of spruce using treated with ozone for 15 minutes were fragments of fiber surfaces or cell corners, and most of them contained lignin. However, lignin was not observed in the fibers after 15 minutes of ozone treatment. The fine fibers produced from CTMP of white birch were broken pieces or fragments of fiber surfaces or cell corners. The lignin was observed in the fibers until 5min of ozone treatment but no lignin was observed after 5 minutes of ozone treatment. Different morphological characteristics of TMP and CTMP explained both the different morphological characteristics and the distribution of lignin observed in the fine fibers produced from the beating process of TMP and CTMP treated with ozone.

• 한국물환경학회지
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• 제22권6호
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• pp.1137-1143
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• 2006

In this study we investigated the removal characteristics of NOM and bromate formation characteristics in SOMT reactor. The system was recently developed as a novel ozone reactor and installed in SJ pilot plant. DOC values were decreased within 3% after treatment of 0.5~2.0 mg/L ozone dosage in SOMT reactor while the $UV_{254}$ value was 69% decreased at 2.0 mg/L ozone dosage. The composition of NOM was analysed by LC-OCD (Organic Cabon Detector) after ozone treatment in SOMT reactor to elucidate the variation of NOM character. Polysaccharide (more than 20,000 g/mol) fraction of NOM was decomposed while building blocks (350~500 g/mol) and neutral (less than 350 g/mol) fraction increased. Spiked bromide reacted with 0.5~2.0 mg/L ozone dosage in the SOMT reactor. The bromate formation was proportional to the ozone dosage ($R^2=0.978$) but not proportional to reaction time. The maximum concentration of formated bromate was not exceeded to 10% of spiked bromide concentration.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2004년도 춘계학술발표회 논문집
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• pp.180-185
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• 2004

• Ocean and Polar Research
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• 제26권3호
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• pp.439-451
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• 2004

Total solar irradiance (750), total UV irradiunce (TUV) and erythemal UV irradiance (EUV) measured at King Sejong station $(62.22^{\circ}S,\;58.78^{\circ}W)$ in west Antarctica have been used together with total ozone, cloud amount and snow cover to examine the effects of ozone, cloud and snow surface on these surface solar inadiunce over the period of 1998-2003. The data of three solar components for each scan were grouped by cloud amount, n in oktas $(0{\leq}n<3,\;3{\leq}n<4,\;4{\leq}n<5,\;5{\leq}n<6,\;6{\leq}n<7\;and\;7{\leq}n<8)$ and plotted against solar zenith angle (SZA) over the range of $45^{\circ}\;to\;75^{\circ}$. The radiation amplification factor (RAE) is used to quantify ozone effect on EUV. RAF of EUV decreases from 1.51 to 0.94 under clear skies but increases from 0.94 to 1.85 under cloudy skies as SZA increases, and decreases from 1.51 to 1.01 as cloud amount increases. The effects of cloud amount and snow surface on EUV are estimated as a function of SZA and cloud amount after normalization of the data to the reference total ozone of 300 DU. In order to analyse the transmission of solar radiation by cloud, regression analyses have been performed for the maximum values of solar irradiance on clear sky conditions $(0{\leq}n<3)$ and the mean values on cloudy conditions, respectively. The maximum regression values for the clear sky cases were taken to represent minimum aerosol conditions fur the site and thus appropriate for use as a normalization (reference) factor for the other regressions. The overall features for the transmission of the three solar components show a relatively high values around SZAs of $55^{\circ}\;and\;60^{\circ}$ under all sky conditions and cloud amounts $4{\leq}n<5$ and $5{\leq}n<6$. The transmission is, in general, the largest in TUV and the smallest in EUV among the three components of the solar irradiance. If the ground is covered with snow on partly cloudy days $(6{\leq}n<7)$, EUV increases by 20 to 26% compared to snow-free surface around SZA $60^{\circ}-65^{\circ}$, due to multiple reflections and scattering between the surface and the clouds. The relative difference between snow surface and snow-free surface slowly increases from 9% to 20% as total ozone increases from 100 DU to 400 DU under partly cloud conditions $(3{\leq}n<6)$ at SZA $60^{\circ}$. The snow effects on TUV and TSO are relatively high with 32% and 34%, respectively, under clear sky conditions, while the effects changes to 36% and 20% for TUV and TSO, respectively, as cloud amount increases.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제3권1호
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• pp.41-56
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• 1999

Since UV-B radiation measuring networks have not been established, numerical models which calculate the flux from other readily available meteorological measurements may play an important role. That is, such a problem can be solved by using parameterization models such as two stream approximation, the delta-Eddington method, doubling method, and discrete ordinate method. However, most UV-B radiative transfer models have not been validated with measurements, because such models are not intended as practical computational schemes for providing surface estimates of UV-B radiation. The main concern so far has been to demonstrate model sensitivity for cloudless skies. In particular, few have been concerned with real cloud information. Clouds and aerosols have generally been incorporated as constituents of particular atmospheric layers with specified optical depths and scattering properties. The parameterization model presented here is a combination of a detailed radiative transfer algorithm for a coludless sky radiative process and a more approximate scheme to handle cloud effects. The model input data requires a daily measurement of the total ozone amount plus a daily record of the amount and type of cloud in the atmosphere. Measurements for an examination of the models at the Department of Atmospheric Sciences, Pusan National University have been takenfrom February, 1995. These models can be used to calculate present and future fluxes where measurements have not been taken, and construct climatologies for the period before ozone depletion began.

• Journal of Korean Society for Atmospheric Environment
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• 제24권E2호
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• pp.74-82
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• 2008

We have examined seasonal and annual means of clear-sky solar noon and daily erythemal ultraviolet-B irradiances measured in Anmyeon. The intensity of the EUV-B irradiance is mainly dependent on solar zenith angle (SZA) and total ozone amounts on clear day conditions. The daily maximum occurs near solar noon time and the highest monthly accumulated EUV-B is seen in July in Anmyeon. The maximum daily variation occurs in June and July due to precipitation and clouds. The 7-year trend of EUV-B irradiance shows that it is slightly increasing. Additionally, we could confirm that aerosol effects such as Asian Dust decreases the EUV-B irradiance reaching the ground surface by 35% to 60%. For more than 45% of the summer days, EUV-B irradiacne was high enough that the UV index registered higher than category Extremely High. This information will be very important for evaluation of the UV index for prevention of both skin cancer and ecosystem damages as well as to understand UV climatology over the Korean Peninsula.

• 공업화학
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• 제24권1호
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• pp.87-92
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• 2013

광촉매 혼성 저온 플라즈마는 폐수에 함유된 유기물을 분해시키는 효과적인 기술이다. 본 연구에서는 광촉매가 결합된 특별히 설계된 유전체 방전 시스템을 골프장이나 감귤농가에서 흔히 살포되는 디크로보스, 카보퓨란 및 메치다치온 살충제의 분해에 적용하였다. 단독 및 병합 시스템에서 살충제의 분해를 평가하였다. 단독 시스템은 UV의 차폐 유무 및 산소기체와 공기에 의한 오존(각종 반응 활성종들 포함) 플라즈마를 이용하였다. 혼성 시스템은 UV로 활성화된 산화아연, 이산화티타늄과 그래파이트 옥사이드와 결합하여 공기에 의한 플라즈마 반응에 적용하였다. 그래파이트 옥사이드는 모사 허머스 법으로 제조하여 FT-IR 분광기로 성능을 측정하였다. 반응시간 60 min에서 UV를 차폐하고 공기를 이용한 플라즈마 반응에 의한 분해성능과 비교하였으며, UV로 활성화된 그래파이트 옥사이드(0.01 g/L)와 결합된 플라즈마 반응은 디크로보스와 카보퓨란의 각각 100% 분해도를 보였다. UV를 활용한 광촉매 혼성 플라즈마는 살충제를 분해시키는 효과적인 대안으로 입증되었다.

• 한국대기환경학회지
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• 제20권4호
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• pp.483-491
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• 2004

The purpose of this study is to develop an ozone passive sampler and to evaluate its performance p-Acetamidophenol using as the reagent for ozone reacts specifically with the ambient ozone to produce a fluorescence material (p-acetamidopheonl dimer). The volume of absorbent solution and the extraction time determined at suitable conditions for measuring ozone were 100$\mu$L and 60 min, respectively. The changes of fluorescence were observed with incresing the storage period of passive samplers in ambient air. but the cool storage in a refrigerator did not remarkably influence the increase of fluorescence. The measurement for the precision oi the passive sampling was carried out with duplicate measurement of passive samplers. The intra-class correlation coefficients of passive samplers using dry and wet filters were 0.992 and 0.962, respectively The results from field validation tests indicated practical agreement (dry filter: r=0.963, wet filter: r=0.995) between the passive sampler and an UV photometric $O_3$ analyzer. The limit of quantification of ozone passive samplers with sampling time of 8 hr (wet filter) and 24 hr (dry filter) were 8.0 ppb and 2.7 ppb, respectively.