• Title/Summary/Keyword: UV/Vis spectrophotometer

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A Study of the relationship between partition coefficients of oils and antimicrtobial effects (파라벤류에 대한 오일의 분배계수와 실제 방부력과의 상관관계 연구)

  • 한종섭;김종일
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.21 no.2
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    • pp.94-111
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    • 1995
  • In this study, the relationship between partition coefficients(Kw) of oils and antimicrobial effects Ivas investigated. The antimicrobial activity of paraben has been known to be controlled by the concentration of the paraben in the aqueous phase. The concentration of paraben in the aqueous phase was measured by the UV/VIS spectrophotometer at the wavelength of 256nm. It was found that the hydrocarbon oils and silicone oils had the lowest Kw value(<1.0) among the tested oils. Also, the emulsions which were made of oils having low Kw values had a good antimicrobial effects. Thus, the cosmetic safety against microorganisms could be improved by using the oils which have low Kw values.

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The Photoluminescent Properties of ZnAl$_2$O$_4$ Phosphors (ZnAl$_2$O$_4$ 형광체의 광발광 특성)

  • 강병모;정운조;조재절;송호준;박계춘;유용택
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.211-216
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    • 1997
  • ZnO and A1$_2$O$_3$ powders were mixed in 1 : 1 mole ratio and ball-milled with ethanol for 3 h. After the pressing process, the mixtures were sintered at $700^{\circ}C$~130$0^{\circ}C$ for 5 h in air to form ZnA1$_2$O$_4$. Structural properties were analyzed by X-ray diffraction patterns ; optical properties by absorption spectra with UV-VIS-H[R Spectrophotometer ; microstructural properties by SEM ; photoluminescent properties by using PL Measuring System. In result, ZnAl$_2$O$_4$ phosphor is crystallized at 110$0^{\circ}C$ and optical bandgap is calculated at 4.65 eV. PL spectrums were shifted to longer wavelengths with increasing temperature and was appeared around 780nm at 130$0^{\circ}C$ . Additionally, the peak intensity was veil strong at 80$0^{\circ}C$ and was declined with increasing temperature.

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Thermodynamics of Meso substituted Thiacarbocyanines in Solution

  • 손세모
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.2
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    • pp.125-132
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    • 2000
  • To take an information of substitutent effect and thermodynamic of association at thiacarbocyanines, association constant $K_{D}$, free energy of association $\Delta$ $G_{D}$, enthalpies of association $\Delta$ $H_{D}$ were measured by spectrophotometer according to dependence on concentration of dyes and temperature of aqueous MeOH system. With increase of concentration dyes or decrease of temperature of aqueous MeOH system, absorption spectra of dyes exhibited equlilibria shift toward the dimer. Phenyl meso substituted thiacarbicyanine, DyeIII, resulted in higher $K_{D}$ and $\Delta$ $G_{D}$ values than DyeI and DyeII. To easily make an association of thacarbicyanine, meso substutituent group need to be a flat structure, which will make a park as well as lain tiles.tiles.ructure, which will make a park as well as lain tiles.les.

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Synthesis and Properties of Rhodamine Dye Sensor Material toward detection Response (진단감응 로다민 색소센서재료 합성 및 특성 분석)

  • Kim, Hyung-Joo;Lee, Do-Hyun;Son, Young-A
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.34-34
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    • 2011
  • Recently, people have concerned about environmental pollution. This environmental pollution occur due to many reasons such as heavy metal ions and anions. In this regard, many researchers have studied organic materials to monitor above reasons to protect environmental pollution. One of the organic materials for this function is chemosensor. This chemosensor has been studied and reported about monitoring toxic heavy metal ions and anions. In this study, the dye sensor was designed and synthesized through reaction of Rhodamine 6G and 1,3-Indanedion. this dye sensor selective detected $Hg^{2+}$ metal ions while showing red color absorption and yellowish-green strong fluorescence emission compared to other heavy metal ions such as $Cu^{2+}$, $Hg^{2+}$, $Ag^{2+}$, $Zn^{2+}$, $Fe^{2+}$ and $Fe^{3+}$. In this regard, we anticipated that this dye senosr can provide an significant material for monitoring mercury which cause environmental pollution. Thus, We investigated detailed properties of this dye sesnor with using UV-Vis absorption and fluorescent spectrophotometer, Job's plot method for metal binding complex, computational simulated calculation named Material Studio 4.3 suite to approach for electron distribution and HOMO/LUMO.

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Design and Characteristics of Anti-reflection Coating using Multi-layer Thin Film on the Ferrule Facet (다층 박막을 이용한 패럴 단면의 무반사 코팅 설계 및 특성)

  • Ki, Hyun-Chul;Yang, Mung-Hark;Kim, Seon-Hoon;Kim, Tea-Un;Kim, Hwe-Jong;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.11
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    • pp.991-994
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    • 2007
  • In this paper, we have designed the anti-reflection(AR) coating for $1400{\sim}1600$ nm wavelength range on the ferrule facet of optical connector. The low-temperature ion-assisted deposition was applied to AR coating on the ferrule facet in order to avoid damage of optical connector. We have measured the refractive index of coating film($Ta_2O_5\;and\;SiO_2$) using the ellipsometer and optimized the film thickness using the SEM and thickness measurement equipment. UV-VIS-NIR spectrophotometer is used to measure transmissivity of the AR coated ferrule facet. The refractive index of $Ta_2O_5\;and\;SiO_2$ is $2.123{\sim}2.125$ and $1.44{\sim}1.442$, respectively, for $1400{\sim}1600$ nm wavelength range. The transmissivity of the AR coated ferule facet is more than 99.8 % for $1425{\sim}1575$ nm wavelength range and more than 99.5 % for $1400{\sim}1600$ nm wavelength range. The return loss of the AR coated ferrule facet is 30.1 dB.

Properties of ZnO Thin Films Grown by Radio-frequency Magnetron Sputtering in terms of O2/Ar Mixture Flow Ratio (O2/Ar 혼합 유량비를 변수로 갖는 라디오파 마그네트론 스퍼터링으로 성장된 ZnO 박막의 특성)

  • Cho, Shin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.11
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    • pp.932-938
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    • 2007
  • The structural, optical, and electrical properties of ZnO thin films grown on glass by radio-frequency (rf) magnetron sputtering were investigated. The mixture flow ratio of $O_2$ to Ar, which was operated with sputtering gas, was chosen as a parameter for growing high-qualify ZnO thin films. The structural properties and surface morphologies of the thin films were characterized by the X-ray diffraction and the atomic force microscope, respectively. As for the optical properties of the films, the optical absorbance was measured in the wavelength range of 300-1100 nm by using UV-VIS spectrophotometer. The optical transmittance, absorption coefficient, and optical bandgap energy of ZnO thin films were calculated from the measured data. The crystallinity of the films was improved and the bandgap energy was increased from 3.08 eV to 3.23 eV as the oxygen flow ratio was increased from 0 % to 50 %. Furthermore, The ultraviolet and violet luminescences were observed by using photoluminescence spectroscopy. The hall mobility was decreased with the increase of oxygen flow ratio.

The study for phase change properties of Se added $Ge_2Sb_2Te_5$ thin films ($Ge_2Sb_2Te_5$ 박막의 Se 증가에 따른 상변화 특성 연구)

  • Lim, Woo-Sik;Kim, Sung-Won;Lee, Hyun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.166-166
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    • 2007
  • PRAM (phase-change random access memory)은 전류 펄스 인가에 따른 기록매질의 비정질-결정질 간 상변화와 그에 동반되는 저항변화를 이용하는 차세대 비휘발성 메모리 소자로서 연구되어지고 있다. 본 논문에서는 $(Ge_2Sb_2Te_5)_{1-x}Se_x$ (x=0,0.05,0.1,0.15) 조성에 대한 벌크 및 박막시료를 제작하고 각 조성에 대한 상변화 특성을 분석하였다. XRD를 통해 열처리 온도에 따른 구조적 분석을 실시하였고 UV-Vis-IR spectrophotometer를 사용하여 박막의 광학적 특성을 분석하였다. 또한 각 조성의 결정화 속도를 비교하기 위해 static tester를 사용하여 레이저 펄스 시간에 대한 반사도 변화를 측정하였고 DSC를 통해 결정화 온도를 측정하였다.

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The Application of a Laser to the Chemical Characterization of Radionuclides

  • Park, Y.J.;Park, K.K.;M/Y. Suh;S.K. Yoon;Park, Y.S.;Kim, D.Y.;Kim, W.H.
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.446-456
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    • 2000
  • Laser induced photoacoustic, fluorescence, and photon correlation spectroscopies were applied to the chemical characterization of radionuclides in connection with the radiowaste treatment and disposal. Their measuring principles and systems were briefly described together with their advantages over conventional spectroscopies. Also, other applications of lasers are introduced. Laser induced photoacoustic spectra were measured for a P $r^{3+}$ solution with a very low molar absorptivity. The detection sensitivity was 4.3 $\times$10$^{-5}$ c $m^{1}$ and was 100 times better than that of a UV/VIS spectrophotometer. The Eu(III) excitation spectra($^{7}$ $F_{0}$ longrightarrow $^{5}$ $D_{0}$ transition) were measured for Eu(III)-phthalate complexes using laser fluorescence spectroscopy, showing that only two species, 1:1 and 1:2 complexes, are present in the Eu(III)-phthalic acid system. The size and size distribution for colloidal humic acids and Eu(III)-humate colloids was determined using photon correlation spectroscopy. The presence of Eu(III) enhanced the aggregation of humic acids.s.

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Investigation of Improving Texturing Effect by Surface Saw Damage Etching Using Acidic Etchant for Silicon Solar Cells (산성 표면절삭결함 제거 공정에 의한 실리콘 태양전지의 텍스쳐링 효과 개선)

  • Park, Hayoung;Lee, Joon Sung;Kwon, Soonwoo;Yoon, Sewang;Lim, Heejin;Kim, Donghwan
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.835-840
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    • 2008
  • Texturing for crystalline silicon solar cells is one of the important techniques to increase conversion efficiency by effective photon trapping. Generally, incoming wafers or alkali etched wafers are used for texturing. From this conventional etching process, $7{\sim}10{\mu}m$-sized random pyramids are formed. In this study, acid etching for removal of saw damages was practiced before texturing. This improved the resulting surface morphology, which consisted of $2{\sim}4{\mu}m$-sized pyramids. Because these pyramids covered the surface much more extensively, we obtained reduction of optical losses on the surface. In order to compare with conventional texturing, FE-SEM is used for observing surface morphology and reflectance data is analyzed by UV-VIS spectrophotometer.

Identification of Anti-Oxidant and Anti-Tyrosinase Activity of Phenolic Components Isolated from Betula schmidtii (박달나무로부터 분리된 페놀성 화합물의 항산화 및 Tyrosinase 저해 활성 연구)

  • Wang, Da-Hye;Chung, Ha Sook
    • The Korean Journal of Food And Nutrition
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    • v.34 no.5
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    • pp.553-559
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    • 2021
  • The aim of study to investigate the phytochemicals and biological activities the bark of Betula schmidtii. The studies consisted of the solvent extraction, followed by the isolation of phenolic components 1~3 from ethyl acetate-soluble fraction of Betula schmidtii Bark. Their chemical structures were identified as arbutin (1), ρ-coumaric acid (2) and ferulic acid (3) using Ultraviolet-Visible (UV-Vis) Spectrophotometer, Electrospray Ionization Mass Spectrometry (ESI-MS) (negative ion mode), 1H-Nuclear Magnetic Resonance (NMR), 13C-NMR, 1H-1H Correlation Spectroscopy (COSY) and 1H-13C Hetero Nuclear Multiple Quantum Correlation (HMQC) spectral data. Compounds 1~3 shows the anti-oxidant effect with IC50 values of 29.74±1.52, 21.32±1.07 and 34.41±1.24 in 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging activity, respectively. Also, compounds 1~3 exhibited mushroom tyrosinase inhibitory activity with IC50 values of 31.14±1.07, 42.54±1.46 and 69.22±1.43 µM, respectively.