• Title/Summary/Keyword: UF cycle

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UF pretreatment at elevated temperature within the scheme of hybrid desalination: Performance and environmental impact

  • Agashichev, Sergey;Kumar, Jayesh
    • Membrane and Water Treatment
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    • v.8 no.3
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    • pp.279-292
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    • 2017
  • This study was aimed at ultrafiltration (UF) as a pretreatment before reverse osmosis (RO) within the scheme of hybrid reverse osmosis-multistage flush (RO-MSF) desalination. Seawater at elevated temperature (after MSF heat-exchangers) was used as a feed in this process. The pretreatment system was represented as a set of functionally-linked technological segments such as: UF filtration, backwashing, chemical- enhanced backwashing, cleaning, waste disposal, etc. The process represents the sequences of operating cycles. The cycle, in turn, consists of the following unit operations: filtration, backwashing and chemical-enhanced backwashing (CEB). Quantitative assessment was based on the following indicators: normalized permeability, transmembrane pressure, specific energy and water consumption, specific waste generation. UF pre-treatment is accompanied by the following waste streams: $W1=1.19{\times}10$ power of $-2m^3$ (disposed NaOCl with 0.0044% wt.)/$m^3$ (filtrate); $W2=5.95{\times}10$ power of $-3m^3$ (disposed $H_2SO_4$ with 0.052% wt.)/$m^3$(filtrate); $W3=7.26{\times}10$ power of $-2m^3$ (disposed sea water)/$m^3$ (filtrate). Specific energy consumption is $1.11{\times}10$ power of $-1kWh/m^3$ (filtrate). The indicators evaluated over the cycles with conventional (non-chemical) backwashing were compared with the cycles accompanied by CEB. A positive impact of CEB on performance indicators was demonstrated namely: normalized UF resistance remains unchanged within the regime accompanied by CEB, whereas the lack of CEB results in 30% of its growth. Those quantitative indicators can be incorporated into the target function for solving different optimization problems. They can be used in the software for optimisation of operating regimes or in the synthesis of optimal flow- diagram. The cycle characteristics, process parameters and water quality data are attached.

Protein Expression of Matrix Metalloproteinases of Mouse Reproductive Organs During Estrous Cycle (생식주기에 따른 자성 생쥐의 생식기관의 Matrix Metalloproteinase의 단백질 발현)

  • Kim, Moon-Young;Lee, Ki-Won;Kim, Hae-Kwon;Kim, Moon-Kyoo;Cho, Dong-Jae
    • Clinical and Experimental Reproductive Medicine
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    • v.25 no.2
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    • pp.161-170
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    • 1998
  • Protein expression patterns of matrix metalloproteinases (MMPs) were examined in mouse reproductive organs during estrous cycle. Estrous cycle was classified into diestrus, proestrus, estrus or metestus and MMP expression was analyzed by zymography using gelatin as a substrate. Uterine fluid (UF) obtained both at diestrus and proestrus exhibited 4 major MMPs including 106kDa, 64kDa, 62kDa and 59kDa gelatinases. However, in UF at estrus, the gelatinolytic activity of 64kDa MMP disappeared and that of 106kDa and 62kDa MMPs dramatically decreased. At metestrus, 64kDa MMP activity reappeared and 106kDa and 62kDa MMP exhibited increased activities such that the band intensity of 106kDa was comparable to that in UF at diestrus. Gelatinolytic activity of 59kDa MMP was not changed throughout the cycle. Both ovarian and oviductal tissue homogenate revealed 4 MMPs which corresponded to the 4 MMPs of UF. However, unlike UF MMPs, gelatinolytic activity of these MMPs did not show distinct changes throughout the cycle. Either an inhibitor of MMP, 1,10-phenanthroline, or a metal chelator, EDTA, abolished the appearance of the above MMP activities in gelatinated gel whereas a serine proteinase inhibitor, phcnylmethylsulfonyl fluoride, failed to inhibit the appearance of MMP activities, proving that gelatinolytic activity of the above reproductive tissues were due to the enzymatic activity of MMP. When gclatinolytic activity of mouse serum was examined, it revealed 5 MMPs (131kDa, 106kDa, 89kDa, 64kDa and 62kDa bands) and one gelatinase (84kDa) band. From these results, it is concluded that the protein expression of MMPs of mouse reproductive organs, particularly uterus, is temporally regulated during estrous cycle and uterine 106kDa, 64kDa and 62kDa MMPs are suggested to play an important role in cyclic tissue remodeling of mouse uterus.

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Application of Ceramic MF Membrane at the Slow Sand Filtration Process (완속모래여과 공정에서 세라믹 MF 막의 적용)

  • Choi, Kwang-Hun;Park, Jong-Yul;Kim, Su-Han;Kim, Jeong-Sook;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.12
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    • pp.877-882
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    • 2013
  • The application of ultrafiltration (UF) and microfiltration (MF) membranes has been increased for drinking water purification. The advantages of UF/MF membrane process compared to conventional treatment processes are stable operation under varying feed water quality, smaller construction area, and automatic operation. Most membrane treatment plants are designed with polymeric membranes. Recently, some studies suggested that the process of treating surface water with ceramic membranes is competitive to the application of polymeric membranes. Higher water flux, less frequent cleaning, and much longer lifetime are the advantages of ceramic membrane comparing to polymeric membrane. Therefore, this research focused on the application of ceramic MF membrane pilot plant at the slow sand filtration plant. The ceramic membrane pilot plant has three trains that used raw water and sand filtered water as a feed water, respectively. For optimizing the pilot plant process, the coagulation with PACl coagulant was used as a pretreatment of ceramic membrane process. In addition, CEB (Chemical Enhanced Backwash) process using $H_2SO_4$ and NaOCl was used for 1.5 days, respectively. The experimental results showed that applying the optimum coagulant dose before membrane filtration showed enhancing membrane fluxes for both raw water and sand filtered water. Also, when using raw water as a feed of membrane, minimum fouling rate was 2.173 kPa/cycle with 25 mg/L of PACl and when using sand filtered water, the minimum fouling rate was 0.301 kPa/cycle with 5 mg/L of PACl.

Comparison and application method of seawater desalination pre-treatment process (해수담수화 전처리공정 비교 및 적용 방법)

  • Lim, Hwankyu;Kim, Seunghyun
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.6
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    • pp.437-446
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    • 2019
  • Reverse osmosis seawater desalination facilities can extend the cleaning cycle and replacement time of the reverse osmosis membrane by pretreatment process. Selection of pretreatment process depends on water quality. It was attempted in this study to select approriate pretreatment process for the Masan bay, which was high in particles and organic content. For this purpose, performances of pretreatment processes such as filter adsorber (FA), pore controllable fiber (PCF), and ultrafiltration (UF) were compared based on the silt density index (SDI). The SDI value of the filtrate should be less than 3. The study results showed that UF can produce the filtrate quality satisfying the requirement. However, the transmembrane pressure (TMP) of UF increased quickly, reaching 0.6 bar within 4 days. In order to secure stable operation, FA and PCF were combined with UF. The study results showed that combination of PCF and UF was able to extend the filtration duration (more than 2 months) until to reach TMP of 0.6 bar.

Investigation of the hydrogen production of the PACER fusion blanket integrated with Fe-Cl thermochemical water splitting cycle

  • Medine Ozkaya;Adem Acir;Senay Yalcin
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4287-4294
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    • 2023
  • In order to meet the energy demand, energy production must be done continuously. Hydrogen seems to be the best alternative for this energy production, because it is both an environmentally friendly and renewable energy source. In this study, the hydrogen fuel production of the peaceful nuclear explosives (PACER) fusion blanket as the energy source integrated with Fe-Cl thermochemical water splitting cycle have been investigated. Firstly, neutronic analyzes of the PACER fusion blanket were performed. Necessary neutronic studies were performed in the Monte Carlo calculation method. Molten salt fuel has been considered mole-fractions of heavy metal salt (ThF4, UF4 and ThF4+UF4) by 2, 6 and 12 mol. % with Flibe as the main constituent. Secondly, potential of the hydrogen fuel production as a result of the neutronic evaluations of the PACER fusion blanket integrated with Fe-Cl thermochemical cycle have been performed. In these calculations, tritium breeding (TBR), energy multiplication factor (M), thermal power ratio (1 - 𝜓), total thermal power (Phpf) and mass flow rate of hydrogen (ṁH2) have been computed. As a results, the amount of the hydrogen production (ṁH2) have been obtained in the range of 232.24x106 kg/year and 345.79 x106 kg/year for the all mole-fractions of heavy metal salts using in the blanket.

Performances of the Used Frying Oil on a Small Diesel Engine (폐식용유를 이용한 소형 디젤기관의 성능)

  • 김성태;정형길;김영복
    • Journal of Biosystems Engineering
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    • v.26 no.3
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    • pp.209-220
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    • 2001
  • This study was carried out to investigate the usability of the used frying oil, which was extracted from soybean, as one of the alternative fuel of a small diesel engine. For the experiment, NO. 2 diesel oil [D], used frying oil [UF], and their volumetric blends were applied and analysis of the properties and compositions of the experimental fuels were conducted. A four cycle diesel engine with single cylinder, water cooling system, maximum output 8.1 ㎾/2,200 rpm was selected and a direct injection chamber and a precombustion chamber were attached alternately. The results obtained were as follows: 1. Engine power (BHP) were increased from 4.13~4.27㎾ to 9.08~9.15㎾ for diesel oil, from 4.05~4.19㎾ to 8.44~8.92㎾ for UF, and from 4.01~4.48㎾ to 8.69~9.16㎾ for blend fuel, as the engine speed increased from 1,000 rpm to 2,200 rpm. The BHP in case of the direct combustion chamber were fluctuated higher than those of the pre-combustion chamber. 2. With the engine speed increased, torque of the engine were increased from 39.50~40.80 N.m to 42.89 N.m, then decreased to 39.44~39.77 N.m for diesel oil, and increased from 38.73~40.04 N.m to 40.12~40.82 N.m then decreased as 36.53~38.76 N.m for UF. Torque of the blend fuels were increased from 38.75~41.76 N.m to 40.47~42.89 N.m then decreased to 37.73~39.78 N.m. There is no significant difference of torque between the type of combustion chambers. 3. The specific fuel consumption of the UF was increased about 20 percent depending on the engine speed variations. And in case of direct injection chamber, about 12 percent lower fuel consumption was observed than that of precombustion chamber. 4. NOx emission of the UF was higher than that of diesel oil at above 1,800rpm of the engine speed. In case of the direct injection chamber, NOx emission was revealed higher about 59 percent than that of the precombustion chamber, depending on the range of the engine speeds. 5. Smoke emission was decreased in case of UF compared with diesel oil on direct injection chamber. When using precombustion chamber smoke emission was a little higher than that of the direct injection chamber were showed at the engine speed range. 6. At all the engine speed range, exhaust gas temperatures were decreased 2~3$^{\circ}C$ for UF used engine compared with those of the diesel oil. The exhaust gas temperature of the direct injection chamber was higher than that of the precombustion chamber by 72$^{\circ}C$. 7. Unburnt materials remained in the cylinder in case of the pre-combustion chamber was smaller and softer than that of the direct combustion chamber. 8. The feasibility of the blend fuel B-1 and B-2 were verified as a direct combustion chamber was attached to the diesel engine, with respect to the power performance of the engine.

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A Literature Review on Application of Signature Materials in Nuclear Forensics according to Domestic Nuclear Facilities and Fuel Cycle (국내 원자력시설 및 핵연료 주기에 따른 핵감식 표지물질 활용에 대한 고찰)

  • Jeon, Yeoryeong;Gwon, Da Yeong;Han, Jiyoung;Choi, Woo Cheol;Kim, Yongmin
    • Journal of the Korean Society of Radiology
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    • v.15 no.1
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    • pp.37-43
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    • 2021
  • Republic of Korea has many nuclear facilities in the country, and Democratic People's Republic of Korea(North Korea) locates in the surrounding country. Therefore, it is necessary to construct the target facility's nuclear forensic data in a preemptive response to the changing international situation. For this reason, this study suggests "signature" materials used to understand the origins and sources of nuclear and other radioactive materials, taking into account domestic nuclear facilities and the nuclear fuel cycle. In domestic, pressurized light water reactors and pressurized heavy water reactors are in operation, and enriched and natural uranium are used as fuels. In the front-end fuel cycle, the signature materials can be nature uranium and UF6 in the uranium enrichment process. The domestic back-end fuel cycle adopts a non-circulating cycle excluding the reprocessing process, and the primary signature material is spent nuclear fuel. According to IAEA recommendation, the importance of these materials as the signature and characteristic contents are suggested in this study. To prove the integrity of nuclear material and build a national nuclear forensics library, it is necessary to grasp the signature material and acquire the characteristic data considering the domestic nuclear facilities and the nuclear fuel cycle.

Process Analysis on the Decontamination of Internal Surface of $UF_6$ Cylinder ($UF_6$ 실린더 내부표면 제염에 관한 공정분석)

  • Chun, Kwan-Sik;Yoo, Sung-Hyun;Cho, Young-June;Hong, Jang-Pyo;Han, Wook-Jin;Choi, Beong-Soon;Kang, Pil-Sang;Cho, Suk-Ju
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.3
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    • pp.161-165
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    • 2009
  • To evaluate the efficiency of the decontamination plant for the removal of uranium compounds deposited on the internal surface of $UF_6$ cylinder for its reuse, two demonstration tests of the plant with different ratio of ${Na_2}{CO_3}$ and ${H_2}{O_2}$ were carried out, and each test had 5 steps. The main chemical form removed by the tests was to be identified as ${Na_4}{UO_2}(CO_3)_3$. More than 50% of uranium was removed by water of the first step, and at the following steps the removal amounts were exponentially decreased. On the other hand, the result shows that the injected amount of ${Na_2}{CO_3}$, compared with that of the removed uranium, was stoichiometrically excessed. This suggests that the injected amounts of ${Na_2}{CO_3}$, the generation rate of decontaminated waste, and the decontamination steps could be reduced by a process optimization of the plant.

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Reprocessing of fluorination ash surrogate in the CARBOFLUOREX process

  • Boyarintsev, Alexander V.;Stepanov, Sergei I.;Chekmarev, Alexander M.;Tsivadze, Aslan Yu.
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.109-114
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    • 2020
  • This work presents the results of laboratory scale tests of the CARBOFLUOREX (CARBOnate FLUORide EXtraction) process - a novel technology for the recovery of U and Pu from the solid fluorides residue (fluorination ash) of Fluoride Volatility Method (FVM) reprocessing of spent nuclear fuel (SNF). To study the oxidative leaching of U from the fluorination ash (FA) by Na2CO3 or Na2CO3-H2O2 solutions followed by solvent extraction by methyltrioctylammonium carbonate in toluene and purification of U from the fission products (FPs) impurities we used a surrogate of FA consisting of UF4 or UO2F2, and FPs fluorides with stable isotopes of Ce, Zr, Sr, Ba, Cs, Fe, Cr, Ni, La, Nd, Pr, Sm. Purification factors of U from impurities at the solvent extraction refining stage reached the values of 104-105, and up to 106 upon the completion of the processing cycle. Obtained results showed a high efficiency of the CARBOFLUOREX process for recovery and separating of U from FPs contained in FA, which allows completing of the FVM cycle with recovery of U and Pu from hardly processed FA.

Phenol-Formaldehyde (PF) Resin Bonded Medium Density Fiberboard

  • Park, Byung-Dae;Riedl, Bernard;Park, Sang-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.1
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    • pp.64-71
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    • 1999
  • This study was conducted to manufacture MDF panels bonded with PF resins which provide excellent durability and dimensional stability with panels, and to identify benefits and weaknesses of using PF resins for MDF panels that have been manufactured with urea-formaldehyde (UF) resins for interior applications due to its low dimensional stability under moisture conditions. The results showed that the performance of PF-bonded MDF panels satisfied the performance requirement. A six-cycle aging test also revealed that PF-bonded MDF panels had high durability. Thickness swelling after 24 hours submersion in cold water was less than 2 percent, showing good dimentioanl stability. The identified weaknesses of using PF resins were relatively high resin content and long hot-pressing time. An acceptable resin content appeared to be 8 percent which can increase the production cost of PF-bonded MDF panels. The hot-pressing time (7 minutes) used in this study is relatively long compared to that of UF-bonded MDF panels. This result also indicates that hot-pressing process has to be optimized to control various pressing variables.

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