• Analytical Science and Technology
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• v.23 no.6
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• pp.544-550
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• 2010

Mistaking pink colored thermal oil for grape wine, a victim drank the oil to death which was analyzed to contain 39% of ethylene glycol. Thermal oil could be used for heat transfer to prevent the malfunction due to the high pressure in the boiler operated at high temperature when using water. Main component of thermal oil is known to be mineral oil or ethylene glycol. From the blood and other tissue of the victim from autopsy, ethylene glycol and its metabolite were simultaneously analyzed by GC/MS after extraction under acidic condition with acetonitrile followed by derivatization with BSTFA. About 0.2 g of the specimens were pretreated with 50 uL of 0.5 M HCl solution to keep acidic condition, then dehydrated with anhydrous sodium sulfate followed by concentration under nitrogen stream. Ethylene glycol and glycolic acid concentration in blood was measured to be $2,755\;{\mu}g/mL$ and $174\;{\mu}g/mL$ respectively. In other specimen, the concentration of ethylene glycol and glycolic acid was $860\;{\mu}g/g\sim1,290\;{\mu}g/g$ and $93\;{\mu}g/g\sim134\;{\mu}g/g$. Especially, crystal appeared in kidney which was supposed xalate from the metabolite of ethylene glycol.

• Journal of Oral Medicine and Pain
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• v.34 no.1
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• pp.11-21
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• 2009

This study was conducted to investigate the relationship between systemic diseases and oral malodor. The author measured the volatile sulfur compound(VSC) of the patients who visited Pusan National University Health Promote Center for a comprehensive medical testing. The patients were examined gingival bleeding on probing, CPI index, tongue coating. Their systemic diseases were diagnosed by the specialist. 182 patients consisted of 112 males and 70 females. In this study, Oral $Chroma^{(R)}$ was used to measure oral malodor. This equipment could measure the concentration of intraoral VSC (hydrogen sulfide, methyl mercaptan, dimethyl disulfide). All data were analylized using Statistical Package for the Social Science $12.0^{(R)}$. The result of this study was the followings. 1. There was significant difference of numbers of patient who visited health care center according to the VSC concentration level and the Community Periodontal Index, bleeding on probing, tongue coating. 2. The subjects with hyperlipidemia showed the high level of $CH_3SH$ concentration (p=0.036). The concentration of $H_2S$ tends to be high in the group with abnormal findings on pulmonary fuction test(p=0.086). The concentration of $CH_3SH$ in the groups with abnormal findings on lipid profile test(p=0.130) and bone mineral density test(p=0.099) and abdominal ultrasonograpy(p=0.088) tends to be higher than the other group. 3. The concentration of $(CH_3)_2S$ in the group with abnormal findings on blood pressure test(p=0.113), hepatitis B virus serology(p=0.069), Abdominal ultrasonograpy(p=0.091) tend to be higher than the other group.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.872-877
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• 2011

Cultivation of Korea ginseng in newly reclaimed and paddy-converted fields has been increasing, and evaluation of organic amendment effectiveness is needed in the two soil types. Soil organisms influence organic matter decomposition, and their responses to applications of organic matter were studied. De-oiled cake and compost were applied at $20Mg\;ha^{-1}$ and $40Mg\;ha^{-1}$ in both soil types. Changes in microflora were assessed by analyzing phospholipid fatty acid (PLFA). The abundance of nematodes and microarthropods was measured. Microbial PLFA indicators for microorganisms and microarthropod abundance were greater in reclaimed upland than in paddy-converted soil. There were few differences in the microflora and fauna of reclaimed uplands, regardless of treatment. In paddy-converted soil, the abundance of Oribatida was increased by the application of compost at $20Mg\;ha^{-1}$ and was correlated with PLFA indicators of fungi. The results suggested a minimal influence of organic amendments in reclaimed upland, because the organic matter content and abundance of soil organisms are low in mineral soils. In paddy-converted soil, the effects of organic amendment differ among different soil organisms, and soil properties are important mediators of the effect.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.727-733
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• 2011

A new Korean standard for the determination of Cr(VI) in soils has been officially published as ES 07408.1 in 2009. This analytical method is based on the hot alkaline digestion and colorimetric detection prescribed by U.S. EPA method 3060A and 7196A. The hot alkaline digestion accomplished using 0.28 M $Na_2CO_3$ and 0.5 M NaOH solution (pH 13.4) at $90{\sim}95^{\circ}C$ determines total Cr(VI) in soils extracting all forms of Cr(VI), including water-soluble, adsorbed, precipitated, and mineral-bound chromates. This aggressive alkaline digestion, however, proved to be problematic for certain soils which contain large amounts of soluble humic substances or active manganese oxides. Cr(III) could be oxidized to Cr(VI) by manganese oxides during the strong alkaline extraction, resulting in overestimation (positive error) of Cr(VI). In contrast, Cr(VI) reduction by dissolved humic matter or Fe(II) could occur during the neutralization and acidic colorimetric detection procedure, resulting in underestimation (negative error) of Cr(VI). Futhermore, dissolved humic matter hampered the colorimetric detection of Cr(VI) using UV/Vis spectrophotometer due to the strong coloration of the filtrate, resulting in overestimation (positive error) of Cr(VI). Without understanding the mechanisms of Cr(VI) and Cr(III) transformation during the analysis it could be difficult to operate the experiment in laboratory and to evaluate the Cr(VI) results. For this reason, in this paper we described the theoretical principles and limitations of Cr(VI) analysis and provided useful guidelines for laboratory work and Cr(VI) data analysis.

• Journal of Wetlands Research
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• v.23 no.3
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• pp.213-223
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• 2021

To understand the sedimentary environment of Scirpus planiculmis habitat (Myeongji and Eulsuk tidal flats) in the Nakdong Estuary, this study analyzed the statistical parameters (sorting, skewness, and kurtosis) of grain size data and the major (Al, Fe, Mn, Mg, Ca, Na, K, Ti, and P), minor (Li, Sc, V, Cr, Co, Ni, Cu, Zn, Sr, Zr, Cs, Pb, Th, and U), and rare earth elements (REEs) in sediment cores. For Myeongji, the sediment structure of the upper part of the cores was poorly sorted, more finely skewed, and more leptokurtic due to construction of the West gate. By contrast, the Eulsuk cores all differed due to the contrasting floodgate operation patterns of the West and East gates. The linear discriminate function (LDF) results corresponded to the statistical parameters for grain size. At the Eulsuk tidal flat (sites ES05 and ES11), elemental distributions were representative of Al-, Fe- and Ca-associated profiles, in which the elements are largely controlled by the accumulation of their host minerals (such as Na- and K-aluminosilicate and ferromagnesium silicate) and heavy detrital minerals at the sites. Detrital minerals including the aluminosilicates are major factors in the elemental compositions at ES05, diluting the REE contents. However, clay minerals and Fe-oxyhydroxides, as well as REE-enriched heavy minerals, appeared to be controlling factors of the elemental composition at ES11. Therefore, the mineral fractionation process is important in determining the elemental composition during sedimentation, which reflects the depositional condition of riverine-saline water mixing at both sites.

• Journal of Industrial Convergence
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• v.20 no.10
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• pp.87-94
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• 2022

This paper seeks to raise inflection points of battery manufacturing bases in Korea in the V4 region through the reorganization of new industrial technologies in accordance with ESG. As a result, the global supply chain market is cut off. The Russian-Ukraine war and the U.S.-China hegemony are competing in the economic crisis caused by COVID-19. It is showing diversification of new suppliers in an environment where mineral, grain procurement, gas, and even wheat imports from China and Russia are not possible. As a protective glocal, this area is used as a buffer zone(Pro-Russia, Hungary). to an isolated zone(anti-Russia, Poland) by war. In this paper, economic growth is expected to slow further due to the EU tapering period and high inflation in world countries. Due to these changes, the conversion of new tech industry and the contraction of Germany's structure due to energy supply may lose the driving force for economic growth over the past 20 years. This is caused by market disconnection(chasm) in the nominal indicators in this area. On the other hand, Korea should actively develop into the V4 area as an energy generation export (nuclear and electric hydrogen generation) area as a bypass development supply area due to the imbalance in the supply chain of rare earth materials that combines AI. By linking this industry, the energy platform can be scaled up and reliable supply technology (next generation BT, recycling technology) in diversification can be formed in countries around the world. This paper proves that in order to overcome the market chasm caused by the industries connection, new energy development and platform size can be achieved and reliable supply technology (next-generation battery and recycling technology, Low-cost LFP) can be diversified in each country.

• The Journal of Engineering Geology
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• v.23 no.2
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• pp.171-186
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• 2013

A drilling project was undertaken to characterize the geochemical relationship and the occurrence of radioactive materials at a test site among public-use groundwaters previously known to have high occurrence of uranium and radon-222 in the Daejeon area. A borehole (121 m deep) was drilled and core rocks mainly consist of two-mica granite, and associated with pegmatite and dykes of intermediate composition. The groundwater samples collected at six different depths in the borehole by a double-packed system showed the pH values ranging from neutral to alkaline (7.10-9.3), and electrical conductivity ranging from 263 to 443 ${\mu}S/cm$. The chemical composition of the borehole groundwaters was of the $Ca-HCO_3(SO_4+Cl)$ type. The uranium and Rn-222 contents in the groundwater were 109-1,020 ppb and 9,190-32,800 pCi/L, respectively. These levels exceed the regulation guidelines of US EPA. The zone of the highest groundwater uranium content occurred at depths of 45 to 55m. The groundwater chemistry in this zone (alkaline, oxidated, and high in bicarbonate) is favorable for the dissolution of uranium into groundwater. The dominant uranium complex in groundwater is likely to be $(UO_2CO_3)^0$ or $(UO_2HCO_3)^+$. Radon-222 content in groundwater shows an increasing trend with depth. The uranium and thorium contents in the core were 0.372-47.42 ppm and 0.388-11.22 ppm, respectively. These levels are higher values than those previously been reported in Korea. Microscopic observations and electron microprobe analysis(EPMA) revealed that the minerals containing U and Th are monazite, apatite, epidote, and feldspar. U and Th in these minerals are likely to substitute for major elements in crystal lattice.

• Economic and Environmental Geology
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• v.30 no.5
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• pp.417-431
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• 1997

Characteristics of sedimentary rocks and enrichment of toxic elements in shale and coal from the Chungnam coal field were investigated based upon geochemistry of major, trace and rare earth elements. Shale and coal of the area are interbedded along the Traissic to the Jurassic Daedong Supergroup, which can be subdivided into grey shale, black shale and coal. The coal had been mined, however all the mines are abandonded due to the economic problems. The shale and coal are characterized by relatively low contents of $SiO_2$, and $Al_2O_3$ and high levels of loss-on-ignition (LOI), CaO and $Na_2O$ in comparison with the North American Shale Composite (NASC). Light rare earth elements (La, Ce, Yb and Lu) are highly enriched with the coal. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shale and coal range from 30.0 to 351.8 and from 4.2 to 106.8, which have partly negative correlations against $SiO_2/Al_2O_3$ (1.24 to 6.06), respectively. Those are suggested that controls of mineral compositions in shale and coal can be due to substitution and migration of those elements by diagenesis and metamorphism. Shale and coal of the area may be deposited in terrestrial basin deduced from high C/S (39 to 895) and variable composition of organic carbon (0.39 to 18.40 wt.%) and low contents of reduced sulfur (0.01 to 0.05 wt.%). These shale and coal were originated from the high grade metamorphic and/or igneous rocks, and the rare earth elements of those rocks are slightly influenced with diagenesis and metamorphism on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.38 to 0.85) and Th/U (3.6 to 14.6). Characteristics of trace and rare earth elements as Co/Th (0.07 to 0.86), La/Sc (0.31 to 11.05), Se/Th (0.28 to 1.06), V/Ni (1.14 to 3.97), Cr/V (1.4 to 28.3), Ni/Co (2.12 to 8.00) and Zr/Hf (22.6~45.1) in the shale and coal argue for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (1.36 to 21.68), Th/Yb (3.5 to 20.0) and La/Th (0.31 to 7.89), and their origin is explained by derivation from a mixture of mainly acidic igneous and metamorphic rocks. Average concentrations in the shale and coal are As=7.2 and 7.5, Ba=913 and 974, Cr=500 and 145, Cu=20 and 26, Ni=38 and 35, Pb=30 and 36, and Zn=77 and 92 ppm, respectively, which are similar to those in the NASC. Average enrichment indices for major elements in the shale (0.79) and coal (0.77) are lower than those in the NASC. In addition, average enrichment index for rare earth elements in coal (2.39) is enriched rather than the shale (1.55). On the basis of the NASC, concentrations of minor and/or environmental toxic elements in the shale and coal were depleted of all the elements examined, excepting Cr, Pb, Rb and Th. Average enrichment indices of trace and/or potentially toxic elements (As, Cr, Cu, Ni, Pb, U and Zn) are 1.23 to 1.24 for shale and 1.06 to 1.22 for coal, respectively.

• The Journal of the Petrological Society of Korea
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• v.14 no.2 s.40
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• pp.83-92
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• 2005

It has recently been proposed that granites can be divided into hot and cold ones by absence and presence of inherited zircon, respectively, which is closely related to zircon saturation temperature. The Phanerozoic granites in South Korea are divided into high- and low-Zr groups in a $SiO_2-Zr$ diagram, which appears to be related to their intrusive age. Most Triassic-Jurassic granites belong to low-Zr group, whereas most Cretaceous-Early Tertiary granites belong to the high-Zr group with the exception of geographically distinct Masan and Jinhae granites that belong low-Zr group. Calculated zircon saturation temperatures using major elements and Zr contents indicate that the Cretaceous-Early Tertiary granites $(608-834^{\circ}C,\;average\; 782\pm31^{\circ}C)$ except for the Masan and Jinhae granites $(average\;759\pm16^{\circ}C)$ show higher temperature than the Triassic-Jurassic granites $(642-824^{\circ}C,\;average\;756\pm31^{\circ}C)$. U-Pb zircon isotope data of the Triassic-Jurassic granites reported so far define discordia in a concordia diagram, which indicates presence of inherited zircon and agrees with their low zircon saturation temperatures. So the Triassic-Jurassic granites appear to belong to cold granite. On the other hand, presence or absence of inherited zircon has not been known for the Cretaceous-Early Tertiary granites with relatively high zircon saturation temperature, so that their classification into hot or cold granite awaits further study. Nevertheless, the Creatceous-Early Tertiary granites may have formed at higher temperature than the Triassic-Jurassic granites, since zircon saturation temperature reflects formation temperature of magma to a certain degree.

• Economic and Environmental Geology
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• v.52 no.5
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• pp.427-448
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• 2019

This study reconstructed the paleoenvironments and paleogeography of the Taebaeksan Basin, through a review of the previous researches on sedimentology, paleontology and stratigraphy. This study also carried out a sequence stratigraphic analysis on regional tectonism and sea-level fluctuations on the basin during the Early Paleozoic. The basin broadly occur in the Taebaek, Yeongweol-Jecheon, Jeongseon-Pyeongchang, and Mungyeong areas, Gangwon province, South Korea. The basin-fills are composed mainly of mixed carbonates and siliciclastics, divided into the Taebaek, Yeongweol, Yongtan, Pyeongchang and Mungyeong groups according to lithologies and stratigraphic characteristics. Recently, there are a lot of studies on the provenance and depositional ages of the siliciclastic sequences of the basin. The detrital sediments of the basin would be derived from two separated provenances of the core-Gondwana and Sino-Korean cratons. In the Early Cambrian, the Taebaek and Jeongseon-Pyeongchang platforms have most likely received detrital sediments from the provenance of the Sino-Korean craton. On the other hand, the detrital sediments of the Yeongweol-Jecheon platform was probably sourced by those of the core-Gondwana craton. This separation of provenance can be interpreted as the result of the paleogeographic and paleotopographic separation of the Yeongweol-Jecheon platform from the Taebaek and Jeongseon-Pyeongchang platforms. The analyses on detrital zircons additionally reveal that the separation of provenance was ceased by the eustatic rise of sea-level during the Middle Cambrian, and the detrital sediments of the Taebaeksan Basin were entirely supplied from those of the core-Gondwana craton. During that period, sediment supply from the Sino-Korean craton would be restricted due to inundation of the provenance area of the craton. On the other hand, the Jeongseon-Pyeongchang platform sequences show the unconformable relationship between the Early Cambrian siliciclastic and the Early Ordovician carbonate strata. It is indicative of presence of regional uplift movements around the platform which would be to the extent offset of the effects of the Middle to Late Cambrian eustatic sealevel rise. These movements expanded and were reinforced across the basin in the latest Cambrian and earliest Ordovician. After the earliest Ordovician, the basin was tectonically stabilized, and the shallow marine carbonate environments were developed on the whole-platform by the Early Ordovician global eustatic sea-level rise, forming very thick carbonate strata in the basin. In the Late Ordovician, the Early Paleozoic sedimentation on the basin was terminated by the large-scale tectonic uplift across the Sino-Korean platform including the Taebaeksan Basin.