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A Characterization of Pervaporation-facilitated Esterification Reaction with non-perfect Separation (비완전 막분리시 투과증발 막촉진 에스터화 반응 거동 연구)

  • C. K Yeom;F. U. Baig
    • Membrane Journal
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    • v.13 no.4
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    • pp.268-282
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    • 2003
  • Pervaporation-facilitated esterification with slow reaction regime was characterized by using a practical model based on non-perfect separation through membrane. A non-perfect separation in which the membrane is not perfectly permselective to water was applied to the model. Thus, membrane selectivity and membrane capability to remove water were included in the simulation model to explain how they influence the membrane-facilitated reaction process and improve the reactor performance. It was shown by simulation that in the reaction systems with non-perfect separation, reaction completion can hardly be achievable when any reactant at initial molar ratio=1 or the less abundant reactant at initial molar ratio>1 permeates through membrane, and the permeation of ester accelerates the forward reaction md increase reaction conversion at any instant through removal of product species like water. The volume change causes concentrating both reactants and products that affect the reaction with time in opposite ways; reactant-concentrating effect is dominant during the initial stage of reaction, increasing the reaction rate, and then concentrating product influences more reaction by decreasing the reaction rate.

Differential role of endothelium in hawthorn fruit extract-induced relaxation of rat cerebral, coronary, carotid, and aorta

  • Chan, Hoi Yun;Chen, Zhen-Yu;Yao, Xiaoqiang;Lau, Chi-Wai;Zhang, ZeSeng;Ho, Walter Kwok Keung;Huang, Yu
    • Advances in Traditional Medicine
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    • v.2 no.2
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    • pp.87-93
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    • 2002
  • The present study was aimed to examine the role of endothelium in the relaxant effect of hawthorn fruit extract of Crataegus pinnatifida in four different types of rat arteries, posterior cerebral communicating artery, right descending coronary artery, common carotid artery, and aorta. In $9,11-dideoxy-11{\alpha}$, $9{\alpha}-epoxy-methanoprostaglandin$ $F_{2{\alpha}}$ (U46619)-preconstricted arterial rings except for aorta, the extract produced endothelium-independent relaxations with similar potency. This relaxation was unaffected by pretreatment with $100\;{\mu}M\;N^G-nitro-L-arginine$ methylester (L-NAME, the nitric oxide synthase inhibitor), $3\;{\mu}M$ 1H-[l,2,4]oxadiazolo$[4,2-{\alpha}]$quinoxalin-1-one (ODQ, the guanylate cyclase inhibitor), or $10\;{\mu}M$ indomethacin (the cyclooxygenase inhibitor). Putative $K^+$ channel blockers (charybdotoxin plus apamin or glibenclamide) did not affect the extract-induced relaxation in cerebral or coronary artery rings. In contrast, in rat aortic rings the extract produced significantly smaller relaxant response in endothelium-denuded rings than that in endothelium-intact rings. Pretreatment with L-NAME or ODQ abolished the extractinduced endothelium-dependent aortic relaxation, whilst indomethacin $(3\;{\mu}M)$ had no effect. The present results indicate that hawthorn fruit extract possesses a vasorelaxing effect in cerebral, coronary and carotid arteries and this effect is independent of the presence of a functional endothelium. However, the extract-induced endothelium-dependent relaxation in rat aorta was mediated through endothelial nitric oxide and cyclic GMP-dependent mechanisms, suggesting that active components in the extract may act on endothelium to stimulate release of nitric oxide in large conduit arteries of the rats.

Investigation on the effect of vibration frequency on vortex-induced vibrations by section model tests

  • Hua, X.G.;Chen, Z.Q.;Chen, W.;Niu, H.W.;Huang, Z.W.
    • Wind and Structures
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    • v.20 no.2
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    • pp.349-361
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    • 2015
  • Higher-mode vertical vortex-induced vibrations (VIV) have been observed on several steel box-girder suspension bridges where different vertical modes are selectively excited in turn with wind velocity in accordance with the Strouhal law. Understanding the relationship of VIV amplitudes for different modes of vibration is very important for wind-resistant design of long-span box-girder suspension bridges. In this study, the basic rectangular cross-section with side ratio of B/D=6 is used to investigate the effect of different modes on VIV amplitudes by section model tests. The section model is flexibly mounted in wind tunnel with a variety of spring constants for simulating different modes of vibration and the non-dimensional vertical amplitudes are determined as a function of reduced velocity U/fD. Two 'lock-in' ranges are observed at the same onset reduced velocities of approximately 4.8 and 9.4 for all cases. The second 'lock-in' range, which is induced by the conventional vortex shedding, consistently gives larger responses than the first one and the Sc-normalized maximum non-dimensional responses are almost the same for different spring constants. The first 'lock-in' range where the vibration frequency is approximately two times the vortex shedding frequency is probably a result of super-harmonic resonance or the "frequency demultiplication". The main conclusion drawn from the section model study, central to the higher-mode VIV of suspension bridges, is that the VIV amplitude for different modes is the same provided that the Sc number for these modes is identical.

Runoff of Trifluralin from Fields in Louisiana (Louisiana의 농장에서 Trifluralin의 유출)

  • ;S.E. Feagley
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.585-592
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    • 1996
  • Trifluralin (2, 6-dinitro-N, N-dipropyl-4- (trifluormethyl) benzenamine) was applied preemergent to soybean in plots drained or nondrained, in louisiana. Plots 14.6 ha were arranged to give 1683 g/ha of trifluralin. The half life of trifluralin in the top 15 cm of soil was 42.6 darts and f6.0 days in nondrained plot and drained plot, respectively. The concentrations of trifluralin in surface runoff water and subsurface runoff water were 0.62 ng/ml-0.02 ng/ml and 11.06 ng/ml-0.02 ng/ml, respectively. The concentration of trifluralin in runoff water was smaller than 2 ng/ml for trifluralin of U.S. Environmental Protection Agency advisory. Total loss of trifluralin in runoff water was 0.021 % of applied amount at drained plots during three month after application. Trifluralin was moved hardly in the water. Subsurface drainage -reduced trifluralin losses because concentration of trifluralin in the subsurface runoff water in drained fields was low.

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Analysis of Levels of Health-related Quality of Life and Its Related Factors of Traditional Market Merchants (전통시장 상인의 건강 관련 삶의 질 수준 및 관련요인 분석)

  • Shin, Keung-Mi;Bae, Young-Sil
    • Research in Community and Public Health Nursing
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    • v.30 no.4
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    • pp.437-448
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    • 2019
  • Purpose: The purpose of this study was to identify levels of health-related quality of life (EQ-5D) and its related factors among merchants in traditional markets. Methods: A cross-sectional design was used. Data were collected through questionnaires and physical examination on blood pressure, blood glucose, total cholesterol and BMI between February 12 and April 13, 2018. The participants were 175 merchants from two traditional markets in U. Metropolitan city. The data were analyzed with descriptive statistics, t-test, ANOVA and multiple regression analysis using the SPSS/WIN 22.0 program. Results: Levels of health-related EQ-5D were significantly different according to demographic characteristics, smoking status, exercise, total cholesterol, BMI, subjective health status, stress, and depression. The EQ-5D related factors were variables that had significant influence on subjective health status (β=.30, p<.001), gender (β=.27, p<.001), BMI (β=-.16, p=.012), depression (β=-.17, p=.010), and working period (β=-.15, p=.021). They explained 27.2% of the total variance of health-related quality of life (F=13.91, p<.001). Conclusion: The findings of this study indicated that disease prevention and health management is essential for merchants who work in traditional markets to promote their health-related quality of life. For better merchants outcome, the intervention program should consider factors that are subjective health status, gender, BMI, depression, and working period in order to improve levels of EQ-5D.

A Study on Opaque Porcelain for P.F.M Crown - Focused on Paste Opaque - (도재전장관용 Opaque 도재에 관한 연구 - paste opaque을 중심으로 -)

  • Kim, Sa-Hak;Ko, Dae-Jin;Lee, Yong-Keun;Kim, Kwang-Mahn;Kim, Kyoung-Nam
    • Journal of Technologic Dentistry
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    • v.23 no.2
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    • pp.211-221
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    • 2002
  • The purpose of this study was to analyze the commercial paste opaque products currently available in domestic of foreign as well as domestic, such as Duceram Plus(DU; Ducera Dental GmbH, Germany), VMK 95(VM; Vita Co., Germany), Noritake EX-3(EX; Noritake Co., Japan) and Ceramax(CE; Alphadent Co., Korea). They were characterized in thermal expansion coefficient, particle size distribution, viscosity and solvent using thermomechanical analyzer, particle size analyzer, rheometer and infrared spectrophotometer. Experimental results are as follows; Firstly, thermal expansion coefficients were determined $13.9{\times}10-6/^{\circ}C$ for DU, $14.3{\times}10-6/^{\circ}C$ for VM, $13.3{\times}10-6/^{\circ}C$ for EX, and $14.0{\times}10-6/^{\circ}C$ for CE. Secondly, percent of partice size below $1{\mu}m$ were 12% for DU, VM and CE, and 13% for EX, percent between $1{\mu}m$ and $5{\mu}m$ were 42% for DU, 42% for VM, 38% for EX, and 61 % for CE, percent between $5{\mu}m$ and $10{\mu}m$ were 21 % for DU, 24% for VM, 20% for EX, and 18% for CE, and over $10{\mu}m$ were 25% for DU, 22% for VM, 29% for EX, 9% for CE. Thirdly, the basic composition of the solvent in all of the commercial paste opaques were determined as ethylene glycol from FT-IR investigation. Lastly, measured viscosities were 1798 cp for DU, 536 cp for VM, 1110 cp for EX, and 721 cp for CE.

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Effect of Rice Straw Steaming Time and Mixing Ratio between Acacia mangium Willd Wood and Steamed Rice Straw on the Properties of the Mixed Particleboard

  • Tran, Van Chu;Le, Xuan Phuong
    • Journal of Forest and Environmental Science
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    • v.31 no.2
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    • pp.119-125
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    • 2015
  • This study examined the effects of rice straw steaming time and mixing ratio between rice straw and wood particle on the properties of mixed particle board from Acacia mangium Willd wood and rice straw. Rice straw and Acacia mangium Willd wood were collected in Hanoi, Vietnam. The particle board was three-layer particle board with the structural ratio of 1:3:1. The thickness, density and board size of the particle board were 18 mm, $0.7g/cm^3$, and $800{\times}800{\times}18$ (mm, including trimming), respectively. A resin mixture between commercial Urea-formaldehyde (U-F) adhesive and methylene diphenyl isocyanate (MDI) adhesive was used with a dosage of 12% for the core layer and 14% for the surface layer. In this experimental design, the steaming time for rice straw was 15, 30, 45, 60, and 75 minutes at $100^{\circ}C$. The rice straw-wood mixing ratio was 10, 20, 30, 40, and 50%. The results showed that both mixing ratio and steaming time affect the properties of the particleboard, but the mixing ratio has a stronger impact. A higher mixing ratio and a longer steaming time resulted in a better quality of particleboard. The optimal steaming time for rice straw was 46.12 minutes with the straw-wood mixing ratio of 29.85% with the following characteristics of the particle board: the modulus of rupture (MOR) of 14.64 MPa, internal bond strength (IB) of 0.382 MPa, thickness swelling (TS) of 8.83%, and board density of $0.7-0.7g/cm^3$.

Comparative Study of Morphology on Male Sex Comb Variation of the Drosophila Species (Drosophila 수종의 성즐변이에 관한 형태적 비교 연구)

  • Choi, Yung-Hyun;Kwon, Yong-Won;Yoo, Mi-Ae;Lee, Won-Ho
    • Korean journal of applied entomology
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    • v.33 no.4
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    • pp.216-224
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    • 1994
  • Sex combs which lack in females are characteristic of some members of the subgenus Sophophora When present, they can be van/ from a single blistle to very extensive structures, but the meianogaster subgroup of the subgenus Sophophora have only on the f~rst tarsal segments of the fore legs. D mauritiona among the melanogaster compler of the melar~ogaster subgroup have significantly more sex comb teeth (mean 12.75) than other specie& and the yakubo complex (range of the mean 6.84-758) have less than the melanogaster complex (range of the mean 835-12.75). In sex comb tooth number of interspecd~ch ybrids among the melonogoster complex, there appeared difference u;ith parental species Thus, analysis of male sex comb tooth in FI hybrid could not exhibit the direction of hereditan/ nature. On the other hand, D auraria (the montium subgroup), D suzuki (the suzuki subgroup) and D, lutecens (the takohashii subgroup) of the melanogaster species have two sex combs on the first and second tarsal segments, and the mean number were different according to the species.

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The Type of Anemia in Organic Solvent Workers by MCV and RDW (MCV와 RDW를 이용한 복합유기용제 취급 근로자의 빈혈 유형에 관한 조사)

  • Kim, S.J.;Ohm, S.H.;Kim, D.H.;Lee, C.U.;Chun, J.H.;Kim, S.C.;Pae, K.T.;Park, H.J.
    • Journal of Preventive Medicine and Public Health
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    • v.25 no.2 s.38
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    • pp.162-171
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    • 1992
  • The hematologic effect by low-concentration and repeated exposure to mixed organic solvent remains obscure. This study was performed to evaluate the hematologic effect by mixed organic solvent exposure, especially on the type of anemia by mean corpuscular volume(MCV) and red blood cell distribution width(RDW). The subject were 64 organic solvent workers(male 4, female 60) and 78 general workers(male 18, female 60) who showed anemic tendency in worker's health examination which carried out by Pusan Paik Hospital from January to December, 1988. The author gained some hematologic findings(hemoglobin, hematocrit, RBC, WBC, MCV, MCHC, platelet count, ESR, RDW) from auto-analysis method by coulter counter S plus IV, and compared the type of anemia by MCV and RDW. In the pilot study for estimating the prevalence of anemia according to the type of b, the prevalence rate was higher in organic solvent workers than in public officials as 10.9% and 4.1% respectively. There were statistical significance in the value of hemoglobin, hematocrit, MCV, MCHC, platelet count, ESR, RDW between the two study groups with more severe anemic tendency in organic solvent workers. The type of anemia in organic solvent workers was microcytic and anisocytic with the mean value of $68.28{\pm}8.3fL$ of MCV and $19.1{\pm}4.0%$ of RDW.

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The turbulent wake of a square prism with wavy faces

  • Lin, Y.F.;Bai, H.L.;Alam, Md. Mahbub
    • Wind and Structures
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    • v.23 no.2
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    • pp.127-142
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    • 2016
  • Aerodynamic effects, such as drag force and flow-induced vibration (FIV), on civil engineering structures can be minimized by optimally modifying the structure shape. This work investigates the turbulent wake of a square prism with its faces modified into a sinusoidal wave along the spanwise direction using three-dimensional large eddy simulation (LES) and particle image velocimetry (PIV) techniques at Reynolds number $Re_{Dm}$ = 16,500-22,000, based on the nominal width ($D_m$) of the prism and free-stream velocity ($U_{\infty}$). Two arrangements are considered: (i) the top and bottom faces of the prism are shaped into the sinusoidal waves (termed as WSP-A), and (ii) the front and rear faces are modified into the sinusoidal waves (WSP-B). The sinusoidal waves have a wavelength of $6D_m$ and an amplitude of $0.15D_m$. It has been found that the wavy faces lead to more three-dimensional free shear layers in the near wake than the flat faces (smooth square prism). As a result, the roll-up of shear layers is postponed. Furthermore, the near-wake vortical structures exhibit dominant periodic variations along the spanwise direction; the minimum (i.e., saddle) and maximum (i.e., node) cross-sections of the modified prisms have narrow and wide wakes, respectively. The wake recirculation bubble of the modified prism is wider and longer, compared with its smooth counterpart, thus resulting in a significant drag reduction and fluctuating lift suppression (up to 8.7% and 78.2%, respectively, for the case of WSP-A). Multiple dominant frequencies of vortex shedding, which are distinct from that of the smooth prism, are detected in the near wake of the wavy prisms. The present study may shed light on the understanding of the underlying physical mechanisms of FIV control, in terms of passive modification of the bluff-body shape.