• 제목/요약/키워드: U/F

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태양전지용 실리콘 생산을 위한 금속급 실리콘 제조와 슬래그 정련 연구 (Study metal-grade silicon manufacturing and slag refining for the production of silicon solar cell)

  • 이상욱;김대석;박동호;문병문;민동준;류태우
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.111.2-111.2
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    • 2011
  • 야금학적 방법을 통한 태양전지용 실리콘 제조를 위하여 아크로(Arc furnace)에서 제조된 용융 상태의 금속급 실리콘을 슬래그와 직접 반응시켜 불순물을 제거하는 공정에 관한 연구를 수행하였다. 이를 위해 아크로와 고주파 유도용해로(High-frequency induction furnace)를 이용하여 금속급 실리콘을 제조와 정련 특성 실험을 수행하였다. 본 연구에서 금속급 실리콘을 제조하기 위한 장비로 150kW급-DC 아크로와 300kW급-AC 아크로를 사용하였다. 원재료로 규석, 코크스(Cokes), 숯, 그리고 우드칩(Wood chip)을 실험 비율에 맞춰 아크로 내부에 장입하고, 이를 용융환원 방법을 통해 반응을 시켰다. 이때 생산된 금속급 실리콘의 순도는 약 99.2~99.8% 이었으며, 원재료의 순도, 장입 비율 및 아크로 운전 특성에 따라 편차가 있다. 아크로에서 생산된 금속급 실리콘의 경우 인(phosphorus), 붕소(boron)를 다량 함유하고 있고, 이를 제거하기 위하여 50kW급 고주파 유도용해로 장비를 사용하여 슬래그 정련 실험을 수행하였다. 슬래그 정련시 사용한 성분은 SiO2, CaO 그리고 CaF2 이며, 금속급 실리콘과 슬래그의 질량비 및 반응 시간에 따른 실리콘 불순물 특성을 평가하였다. 실험결과 인과 붕소는 각각 1 ppm 이하, 5 ppm 이하 였으며, 칼슘을 제외한 대부분의 금속 불순물의 경우 0.1~0.2% 임을 확인하였다.

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Isoconversional Cure Kinetics of Modified Urea-Formaldehyde Resins with Additives

  • Park, Byung-Dae
    • Current Research on Agriculture and Life Sciences
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    • 제30권1호
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    • pp.41-50
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    • 2012
  • As a part of abating formaldehyde emission of urea-formaldehyde resin, this study was conducted to investigate the rmalcure kinetics of both neat and modified urea-formaldehyde resins using differential scanning calorimetry. Neat urea-formaldehyde resins with three different formaldehyde/urea mol ratios (1.4, 1.2 and 1.0) were modified by adding three different additives (sodium bisulfite, sodium hydrosulfite and acrylamide) at two different levels (1 and 3wt%). An isoconversional method at four different heating rates was employed to characterize thermal cure kinetics of these urea-formaldehyde resins to obtain activation energy ($E{\alpha}$) dependent on the degree of conversion (${\alpha}$). The $E{\alpha}$ values of neat urea-formaldehyde resins (formaldehyde/urea = 1.4 and 1.2) consistently changed as the ${\alpha}$ increased. Neat and modified urea-formaldehyde resins of these two F/U mol ratios did show a decrease of the $E{\alpha}$ at the final stage of the conversion while the $E{\alpha}$ of neat urea-formaldehyde resin (formaldehyde/urea = 1.0) increased as the ${\alpha}$ increased, indicating the presence of incomplete cure. However, the change of the $E{\alpha}$ values of all urea-formaldehyde resins was consistent to that of the Ea values. The isoconversional method indicated that thermal cure kinetics of neat and modified urea-formaldehyde resins showed a strong dependence on the resin viscosity as well as diffusion control reaction at the final stage of the conversion.

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PMSM 전류제어기의 속응성 향상에 관한 연구 (A Study of Improvement on the Quickness of Current controller for Permanent Magnet Synchronous Motor)

  • 조수억;이정환;김철우
    • 조명전기설비학회논문지
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    • 제21권8호
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    • pp.136-143
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    • 2007
  • 개선된 지령치 변경부를 가지는 전류제어기는 과도 상태에서의 빠른 응답성과 정상 상태에서의 고정밀도를 가진다. 이 논문에서는 개선된 지령치 변경부가 빠른 과도 응답성을 위하여 동기 PI 제어기를 사용하였다. 전류 제어기의 과도 응답특성은 DC 링크 제어 전압의 부족으로 인해 높은 역기전력 영역에서 많은 문제를 가지고 있다. 이 논문은 지령 전압과 한계 전압을 가지는 개선된 지령치 변경부를 제안하였다.

저항-전압변환회로를 이용한 $WO_3$ 박막의 수소검지 특성 측정 (Hydrogen Detecting Characteristics of the $WO_3$ Films Using the R/V Converting Circuit)

  • 이동희;고중혁;김영환;성영권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.767-769
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    • 1998
  • Using the R/V converting circuit, hydrogen detecting characteristics of the $WO_3$ films were investigated. The R/V converting circuit is configured with the equivalently constant current driving method connecting an unknown resistor to be measured in the feedback loop of the or-amr rather than using a separated constant current circuit. The response time of the reference voltage for the R/V converting circuit was simulated by the circuit simulator "SABER", and it was found that the response time in the high resistance range become longer and the error amounts to 10%. From the simulation results. replacing the capacitor in the feedback loop of the second stage or-amp with a 0.001uF capacitor, when measuring in the high resistance range, the response characteristics are remarkably improved. The response time was shortened from about 10 seconds to below 1 second. Using this circuit, the effect of $WO_3$ films deposited by sputtering method on hydrogen was measured.

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Phylogenetic position of Carex splendentissima, a Korean endemic sedge (Cyperaceae)

  • CHUNG, Kyong-Sook;YANG, Sungyu;NAM, Bo-Mi
    • 식물분류학회지
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    • 제50권3호
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    • pp.253-261
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    • 2020
  • Carex splendentissima U. Kang & J. M. Chung, endemic to the Korean peninsula, is characterized by staminate terminal spikes and glabrous elliptic perigynia. Based on its broad leaves, androgynous spikes, and tri-stigmatic features, the species has been placed in Carex sect. Siderostictae Franch. ex Ohwi, an East Asian section and a basal group in the genus. To clarify the monophyly and phylogenetic position of the species, a molecular study using the internal transcribed spacer region of nuclear ribosomal DNA and chloroplast DNA (trnL-F) data was conducted. The DNA sequence data of ten taxa in sect. Siderostictae and closely related taxa (two taxa in sect. Surculosae) with outgroups were analyzed based on maximum parsimony and maximum likelihood (ML) criteria. In the analyses, C. splendentissima was monophyletic and placed within the Siderostictae clade (sect. Siderostictae + two species of sect. Surculosae), forming a clade with C. ciliatomarginata and C. pachygyna (endemic to Japan). The clade (C. splendentissima + C. ciliatomarginata + C. pachygyna) shows evidence of diploidy. Furthermore, C. splendentissima is a sister to C. ciliatomarginata in the ML tree, and the two taxa have staminate terminal spikes. This study also updates the distribution of C. splendentissima and provides keys to the four Korean taxa in sect. Siderostictae. To conserve the endemic species C. splendentissima, further research on its genetic and ecological features should be conducted at the population level.

창호통합형 배열회수 환기시스템의 열성능 및 경제성 평가 (An Analysis on Thermal Performance and Economic of Heat Recovery Ventilation System Integrated with Window)

  • 성욱주;조수;송규동
    • 설비공학논문집
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    • 제24권8호
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    • pp.646-655
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    • 2012
  • This study is intended to analyze the thermal performance and evaluate the applicability about non-duct type heat recovery ventilation system integrated with window. Eventually, economic analysis of the system is conducted according to building energy saving ratio of it. As results of the thermal performance, the U-factor of the window conducted on the basis of KS F 2278 appears to $1.8W/m^2K$, and the effective heat exchange efficiency of the ventilator conducted on the basis of KS B 6879 appears 49.95% for cooling, 66.89% for heating. In the applicability evaluated by TRNSYS 16, the caes of applying the heat recovery ventilator integrated with window is found to reduce the cooling or heating load by 2.9% or 13.5% than the non-ventilator case. The results of economic analysis taking a side of consumer is verified as the payback is 3 years, and the accumulated earning is 1,408,133 won in terms of '600,000 won/unit' for initial cost, 10 years for useful life of the system.

Analog용 PIN-Photodiode의 광 패키징 기술 및 특성 연구 (Optical packaging technology and characterization of analog PIN-Photodiode)

  • 이창민;권기영
    • 대한전자공학회논문지SD
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    • 제42권3호
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    • pp.17-24
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    • 2005
  • 본 논문에서는 단일모드 광섬유를 부착한 analog용 PIN-Photodiode를 제작하고 소자의 특성을 분석하였다. 제작된 analog 용 PIN-photodiode의 대역폭은 1.5 GHz이였으며, 암전류는 20 pA이고, 정전용량은 0.48 pF이였으며, 응답도(responsivity)는 0.9 V/W 이고, 2차 상호변조(IM2, second order distortion)는 -72 dBc이였다. 본 논문에서는 응답도와 IM2 특성을 실시간으로 모니터링하며 정렬하는 새로운 광 패키징 기술을 개발하였다. 그 결과 응답도는 0.03 V/W 향상되었으며, IM2는 $3\~5dBc$ 향상 되었고, 부적합 발생률도 $3.5\%$ 감소하였다.

4-크로로-4'-메톡시-2-니트로디페닐아민의 X-선 결정 및 분자구조 결정 (The Crystal and Molecular Structure of the 4-Chloro-4'-Methoxy-2-NitroDi phenylamino $(C_{13}H_{11}N_2O_3CL)$)

  • 남궁해;유재혁;이현미
    • 한국결정학회지
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    • 제2권2호
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    • pp.28-31
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    • 1991
  • 4-크로로-4'-메톡시-2-니트로디페닐아민, (C12H11N2O3CL, FW=278.70)의 단것세포 상수는 a=8,169(3), b=8.883(1), c=9.150(1) h, α =82. 98(1), β=104.80(2), y=101.43(2)", V=627.3 A3, F(000)=288.0, Dc=1.48g/cm3, u=3.06cm-1, 7=295" K, 공간군 Pi, 번호 2, 삼사 정계 이며, Z=2이다. λ (Mo-Ka)=0.7107A을 사용 하여 수집한 독립적인 회절 반점 1541개로 구조분 석한 최종 신뢰도 값은 각각 R=0.032, Rw=0.033 이며, S=0.46이다. 본 화합물은 암모니아의 두개 의 수소 대신에 4-크로로-페닐기와 4-메톡시-페닐기로 치환된 물질로써, 질소와 두 페닐기 사이의 각과 결합거리 들은 각각 125.42", 1.362 및 1.428 A 인바 수소와 함께 SP2_혼성결합을 하고있다. 질소를 포함한 두 면간 각은 63.29"이다. 분자간 어 떠 한 수소결합을 하고 지지 않다.

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개심수술 환자의 불안과 대처 정도와의 관계에 과한 조사연구 (A Study on the relationship between anxiety and coping in open heart surgery patients.)

  • 김금순
    • 한국보건간호학회지
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    • 제3권1호
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    • pp.67-73
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    • 1989
  • The purpose of this study was to identify relationship between anxiety and. coping in open heart surgery patients to provide basic information for nursing intervention in stress-coping paradigm. Data were collected from Aug. 1st to Aug. 31st, 1988 through individual interview for about 30 minutes. Tools for this study were 'Spielberger's state anxiety scale and Billings & Moos' coping scale. The subjects were 29 male and 27 female patients who had open heart surgery at S.N.U.H. The data were analyzed by Mean score, Percentage, Pearson product moment correlation coefficient T-test, ANOVA test, and Cronbach's reliability test. The results were as follows. (1) The reliability of coping scale was 0.751 by Cronbach's reliability test. (2) Average coping score of those patients was 2,53 (maximum score:4) and they used equally problem focused coping and emotion focused coping. (3) There was significant difference according to religion in stress·coping(F=2,495, P<0.05) (4) The high anxieties were, the more coping were, and there was significant negative correlation in stress-coping (r=-0.2807, P<0.05)

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해조류 중의 Anti-Tumor Initiator 및 Promoter의 해석-4: 발암성 Heterocyclic Amine에 대한 곰피 추출물 중의 돌연변이원성 억제인자 (Elucidation of Anti-Tumor Initiator and Promoter Derived from Seaweed-4: Desmutagenic Principles of Ecklonia stolonifera Extracts against Carcinogenic Heterocyclic Amines)

  • 김선봉;박영범;안종관;유승재;박덕천;김인수;박영호
    • 한국식품영양과학회지
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    • 제27권3호
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    • pp.537-542
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    • 1998
  • The present study was performed to elucidate desmutagenic principles from Ecklonia stolonifera extracts against 2-amino-1-methyl-6-phenylimidazo[4,5-b] pyridine(PhIP) and 2-amino-3,8-dime-thylimidazo[4,5-f]duinoxaline(MeIQx) with Salmonella/mammalian-microsome mutagenicity test. Alginate, phenols, chlorophyll and carotenoids from Ecklonia stolonifera were extracted and their desmutagenicities were assayed. Alginate hydroysates showed desmutagenic activities against PhIP and MeIQx at high level dose. Phenol fractions and bromophenol showed desmutagenic activity of about MeIQx at high level dose. Phenol fractions and bromophenol showed desmutagenic activity of about 90% per 0.5mg against PhIP and MeIQx. Chlorophyllin among chlorophyll derivatives exhibited remarkable desmutagenic activities of 92.9% and 82.7% at 20uM against PhIP and MeIQx, respectively. Carotenoids, such as lutein and $\alpha$-cryptoxanthin isolated from Ecklonia stolonifera exerted also high desmutagenic activity. Major desmutagenic substances from Ecklonia stolonifera are considered to be chlorophyllin, phenols, lutein, $\alpha$-cryptoxanthin and low molecular alginates.

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