• 제목/요약/키워드: Type G processes

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Photocatalytic and Sonophotocatalytic degradation of alachlor using different photocatalyst

  • Bagal, Manisha V.;Gogate, Parag R.
    • Advances in environmental research
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    • 제2권4호
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    • pp.261-277
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    • 2013
  • The degradation of alachlor has been investigated using sonolysis (US), photocatalysis (UV) and sonophotocatalysis (US/UV) using three photocatalyst viz. $TiO_2$ (mixture of anatase and rutile), $TiO_2$ (anatase) and ZnO. The effect of photocatalyst loading on the extent of degradation of alachlor has been investigated by varying $TiO_2$ (both types) loading over the range of 0.01 g/L to 0.1 g/L and ZnO loading over the range of 0.05 g/L to 0.3 g/L. The optimum loading of the catalyst was found to be dependent on the type of operation i.e., photocatalysis alone or the combined operation of sonolysis and photocatalysis. All the combined processes gave complete degradation of alachlor with maximum rate of degradation being obtained in the case of sonophotocatalytic process also showing synergistic effect at optimized loading of photocatalyst. About 50% to 60% reduction in TOC has been obtained using the combined process of sonophotocatalysis depending on the operating conditions. The alachlor degradation fitted first order kinetics for all the processes under investigation. It has been observed that the $TiO_2$ (mixtrure of anatase and rutile) is the most active photocatalyst among the three photocatalysts studied in the current work. The effect of addition of radical enhancers and scavengers on sonophotocatalytic degradation of alachlor has been investigated in order to decipher the controlling mechanism. The alachlor degradation products have been identified using LC-MS method.

울릉도, 독도 초종용에서 형태 변이와 지리적 분포 양상 (Morphological variation and aspects of the geographic distribution of Orobanche coerulescens Stephan ex Willd. (Orobanchaceae) on Ulleung-do and Dok-do Islands)

  • 이웅;정금선;최경;김진석;조성호;박재홍
    • 식물분류학회지
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    • 제46권4호
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    • pp.405-412
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    • 2016
  • 한국내의 초종용은 한반도의 서해, 남해, 동해의 해안가 및 도서지역에 제한적으로 분포한다. 본 연구는 울릉도와 독도를 중심으로 12개 자생지에서 초종용의 종내 형태형질 변이를 관찰하고 지리적 분포 양상을 조사하였다. 그 결과, 외부 형질(줄기, 잎, 포엽, 꽃받침 그리고 화관)에서 털의 유무에 의하여 두 개의 type (G-type, glabrous; P-type, pilose)을 확인하였다. 확인된 두 개의 형태학적 type은 확인된 자생지에서 뚜렷한 지리적 분포 양상을 보여주었다. 한반도와 제주도에는 P-type, 울릉도에는 G-type과 P-type 그리고 독도의 동도에는 G-type만이 관찰되었다. 초종용은 외부 형태 형질에 의하여 서로 다른 두 개의 type이 확인되고 뚜렷한 지리적 분포 양상을 보여주기 때문에, 털이 없어지는 형태적 변이가 단순히 일시적인 우연의 결과물이 아니라 초종용 내에 이주 및 군체 형성의 과정을 동반하는 진화적으로 서로 다른 계통이 있음을 추정할 수 있다. 제한된 지역에서 분포하는 독도의 초종용은 유일하게 G-type 으로 확인되었으며 이는 독도 자생종의 의미와 함께 중요한 식물지리학적 가치를 가지고 있기 때문에 자생지 보전을 위한 노력이 필요하다.

Comparison of Structural Types of Proline Pentamer by Quantum Chemical Calculation (QCC)

  • Jae-Ho Sim
    • International Journal of Advanced Culture Technology
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    • 제11권2호
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    • pp.323-329
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    • 2023
  • In this study, Proline pentamer model was used to investigate change in the dihedral angle, intramolecular hydrogen bonding and formation energies during structural optimization. L-Proline (LP, as an imino acid residue) pentamers having four conformation types [β: φ/ψ=t−/t+, α: φ/ψ=g−/g−, PPII: φ/ψ=g−/t+ and Plike: φ/ψ= g−/g+] were carried out by QCC [B3LYP/6-31G(d,p)]. The optimized structure and formation energy were examined for designated structure. In LP, P-like and PPII types did not change by optimization, and β types were transformed into PPII having no H-bond independently of the designated ψ values. PPII was more stable than P-like by about 2.2 kcal/mol/mu. The hydrogen bond distances of d2(4-6) type H-bonds were 1.94 - 2.00Å. In order to understand the processes of the transformations, the changes of φ/ψ, distances of NH-OC (dNH/CO) and formation energies (ΔE, kcal/mol/mu) were examined.

슬러리형 돈사폐수에서 자원회수와 질소제거를 위한 순차적 결합공정 제안 (A Proposal of Sequencing the Combined Processes for Resources Recovery and Nitrogen Removal from Piggery Waste)

  • 황인수;민경석;배진연
    • 대한환경공학회지
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    • 제28권1호
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    • pp.61-66
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    • 2006
  • 슬러리 형태의 돈사폐수로부터 자원회수와 질소제거를 위하여 순차적으로 ADEPT(Anaerobic digestion elutriated phased treatment) 공정과 SHARON(Single reactor system High Ammonium Removal Over nitrite)-ANAMMOX(Anaerobic ammonium oxidation)공정을 결합하여 운전하였다. ADEPT 공정은 부하율 3.95 gSCOD/L-day에서 운전되었고, SCOD 생성율과 산생성율은 각각 5.3 gSCOD/L-day와 3.3 gVFAs/L-day(as COD)였다. 가수분해에 의한 VS감소와 SCOD생성율은 각각 13%와 0.19 $gSCOD_{prod}/gVS_{feeding}$였으며, 산생성율은 0.80 $gVFAs/gSCOD_{prod.}$였다. 메탄발효조에서 가스생성율과 메탄함량은 각각 2.8 L/day($0.3m^3CH_4/kgCOD_{removal}\;@STP$) 및 77%였다. 운전조건에서 $NH_4-N$ 94.1% (TKN으로서 86.5%) 및 T-P 87.3%가 제거되었다.

초고강도 범퍼 빔의 롤 포밍 공정을 위한 플라워 패턴 설계 (Design of Flower Pattern in Roll Forming Process for Ultra High Strength Bumper Beam)

  • 차태원;김재홍;김근호;김병민
    • 소성∙가공
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    • 제25권5호
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    • pp.319-324
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    • 2016
  • Recently, the roll forming process is one of the most widely used processes for manufacturing automotive part. In this study, flower patterns of roll forming process were designed to manufacture an ultra high strength bumper beam using the finite element analysis. Three types of flower patterns such as the basic type, the rotation type and the split type were designed based on the constant arc length forming method using the design software, UBECO Profil. Finite element analysis was performed to evaluate the suitability of designed flower patterns in terms of the longitudinal strain and the bow defect. The analytical results show that the split type represents more uniform longitudinal strain distributions and a good dimensional accuracy than other types of flower patterns.

Inhibition by Hyaluronan of Collagen-Induced Activation of Hepatic Stellate Cells

  • Lee, Gum-Hwa;Cho, Min-Kyung;Kim, Sang-Geon
    • 한국독성학회:학술대회논문집
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    • 한국독성학회 2003년도 추계학술대회
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    • pp.120-120
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    • 2003
  • Synthesis and distribution of extracellular matrix (ECM) components are dynamically altered in response to the pathophysiological processes including infection, inflammation and apoptosis. In particular, the levels of hyaluronan (HA) change with concomitant increases in the levels of collagen (e.g. type I collagen) and fibronectin in chronic liver diseases.(omitted)

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국내 하수처리장 활성 슬러지의 침전특성에 관한 연구 (Characterization of Activated Sludge Settlings in Korea)

  • 이환구;김영철;최의소
    • 한국물환경학회지
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    • 제25권6호
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    • pp.964-971
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    • 2009
  • In this paper, activated sludge settling was characterized based on field trip and zone settling tests. Plants used for this study include 5 conventional activated sludge processes and 3 A2O type treatment processes. The treatment capacities are in the range from 12,000 to $250,000m^3$/day. Total number of zone settling tests were 188 set and SVI values representing settling characteristics were from 100 to 300 mL/g. It was found out that zone settling velocity of these examined plant sludges can be approximated by mean values calculated by Keinath and Daigger/Roper models. Based on these three models, solid flux analysis were carried out in order to compare design criteria ($3.96{\sim}6.04kg/m^2-hr$) recommended by Korea Sewage Facility Design Guideline with two models used in USA. The results show that design criteria are only applicable for normal condition in settling characteristics (below SVI 100 mL/g). Solid flux analysis of surveyed plants indicates that most of the plants are operated underload conditions except several plants experiencing poor sludge settling problem. Most of the plants are operated under high sludge blanket depths (SBD).

셀소재를 고려한 리튬2차전지 제조공정 위험성 평가 방법 연구 (Research on Risk Assessment of Lithium-ion Battery Manufacturing Process Considering Cell Materials)

  • 김태훈
    • 한국안전학회지
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    • 제37권2호
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    • pp.76-87
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    • 2022
  • Lithium-ion batteries (LIBs) have attracted much interest for their high energy density (>150 mAh/g), high capacity, low self-discharge rate, and high coulombic efficiency. However, with the successful commercialization of LIBs, fire and explosion incidents are likely to increase. The thermal runaway is known as the major factor in battery-related accidents that can lead to a series of critical conditions. Considering this, recent studies have shown an increased interest in countering the safety issues associated with LIBs. Although safety standards for LIB use have recently been formulated, little attention has been paid to the safety around the manufacturing process for battery products. The present study introduces a risk assessment method suitable for assessing the safety of the LIB-manufacturing process. In the assessment method, a compensation parameter (Z-factor) is employed to correctly evaluate the process's safety on the basis of the type of material (e.g., metal anode, liquid electrolyte, solid-state electrolytes) utilized in a cell. The proposed method has been applied to an 18650 cell-manufacturing process, and three sub-processes have been identified as possibly vulnerable parts (risk index: >4). This study offers some crucial insights into the establishment of safety standards for battery-manufacturing processes.

Development of a Fine Digital Sun Sensor for STSAT-2

  • Rhee, Sung-Ho;Lyou, Joon
    • International Journal of Aeronautical and Space Sciences
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    • 제13권2호
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    • pp.260-265
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    • 2012
  • Satellite devices for fine attitude control of the Science & Technology Satellite-2 (STSAT-2). Based on the mission requirements of STSAT-2, the conventional analog-type sun sensors were found to be inadequate, motivating the development of a compact, fast and fine digital sun sensor (FDSS). The FDSS uses a CMOS image sensor and has an accuracy of less than 0.03degrees, an update rate of 5Hz and a weight of less than 800g. A pinhole-type aperture is substituted for the optical lens to minimize its weight. The target process speed is obtained by utilizing the Field Programmable Gate Array (FPGA), which acquires images from the CMOS sensor, and stores and processes the image data. The sensor accuracy is maintained by a rigorous centroid algorithm. This paper describes the FDSS designs, realizations, tests and calibration results.

고내식성 내지문 EGI 강판 개발 (Development of Anti-Fingers Printed EGI Steel Sheet With High Corrosion Resistance)

  • 김형준
    • 한국표면공학회지
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    • 제26권6호
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    • pp.307-315
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    • 1993
  • A study on a new anti-finger printed EGI steel sheet with high corrosion resistance has been carried out to meet the recent requirement of high quality and performance of the pure zinc electrogalvanized steel sheet. The substrate was the pure zinc electrogalvanized sheet with the metallic coating of 20g/$\m^2$. The two differ-ent processes for inorganic(chromating) and organic(resin) coating were applied. One was a two coat/two bake type to separately treat chromating and resin coating which is now widely used. The other was a one coat/one bake type to simultaneously treat them which is newly developed in this study. The solution for the one coat/one bake type was an aqua-base coating agents which was composed of inorganic and organic components. The new anti-finger printed EGI steel sheet with the Cr and resin coating weight of 13mg/$\m^2$ and 800mg/$\m^2$, respectively shows the superior corrosion resistance besides the good paintability, formability fingerprint resistance and earth characteristics properties.

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