• Title/Summary/Keyword: Type G processes

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Photocatalytic and Sonophotocatalytic degradation of alachlor using different photocatalyst

  • Bagal, Manisha V.;Gogate, Parag R.
    • Advances in environmental research
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    • v.2 no.4
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    • pp.261-277
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    • 2013
  • The degradation of alachlor has been investigated using sonolysis (US), photocatalysis (UV) and sonophotocatalysis (US/UV) using three photocatalyst viz. $TiO_2$ (mixture of anatase and rutile), $TiO_2$ (anatase) and ZnO. The effect of photocatalyst loading on the extent of degradation of alachlor has been investigated by varying $TiO_2$ (both types) loading over the range of 0.01 g/L to 0.1 g/L and ZnO loading over the range of 0.05 g/L to 0.3 g/L. The optimum loading of the catalyst was found to be dependent on the type of operation i.e., photocatalysis alone or the combined operation of sonolysis and photocatalysis. All the combined processes gave complete degradation of alachlor with maximum rate of degradation being obtained in the case of sonophotocatalytic process also showing synergistic effect at optimized loading of photocatalyst. About 50% to 60% reduction in TOC has been obtained using the combined process of sonophotocatalysis depending on the operating conditions. The alachlor degradation fitted first order kinetics for all the processes under investigation. It has been observed that the $TiO_2$ (mixtrure of anatase and rutile) is the most active photocatalyst among the three photocatalysts studied in the current work. The effect of addition of radical enhancers and scavengers on sonophotocatalytic degradation of alachlor has been investigated in order to decipher the controlling mechanism. The alachlor degradation products have been identified using LC-MS method.

Morphological variation and aspects of the geographic distribution of Orobanche coerulescens Stephan ex Willd. (Orobanchaceae) on Ulleung-do and Dok-do Islands (울릉도, 독도 초종용에서 형태 변이와 지리적 분포 양상)

  • Lee, Woong;Jeong, Keum Seon;Choi, Kyung;Kim, Jin Seok;Cho, Seong Ho;Pak, Jae-Hong
    • Korean Journal of Plant Taxonomy
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    • v.46 no.4
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    • pp.405-412
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    • 2016
  • We investigate the intraspecific morphological variations and geographical distributions from twelve populations (28 samples) of Orobanche coerulescens in Korea. Two main morphological types were detected, i.e., glabrous (G-type) and pilose (P-type), in the external morphology (stem, leaf, bract, calyx, and corolla). The G-type was found on Ulleung-do and Dok-do, and the P-type was observed on the coasts of South Korea, Jeju-do and Ulleung-do. The distinct difference in the morphological types and geographical distribution suggested the existence of two putative lineages with different distribution processes. O. coerulescens, distributed in very limited areas, was only identified as the G-type on Dok-do. Hence, conservation efforts should focus on protecting native habitats to conserve native species and the unique biogeographic significance of this species.

Comparison of Structural Types of Proline Pentamer by Quantum Chemical Calculation (QCC)

  • Jae-Ho Sim
    • International Journal of Advanced Culture Technology
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    • v.11 no.2
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    • pp.323-329
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    • 2023
  • In this study, Proline pentamer model was used to investigate change in the dihedral angle, intramolecular hydrogen bonding and formation energies during structural optimization. L-Proline (LP, as an imino acid residue) pentamers having four conformation types [β: φ/ψ=t−/t+, α: φ/ψ=g−/g−, PPII: φ/ψ=g−/t+ and Plike: φ/ψ= g−/g+] were carried out by QCC [B3LYP/6-31G(d,p)]. The optimized structure and formation energy were examined for designated structure. In LP, P-like and PPII types did not change by optimization, and β types were transformed into PPII having no H-bond independently of the designated ψ values. PPII was more stable than P-like by about 2.2 kcal/mol/mu. The hydrogen bond distances of d2(4-6) type H-bonds were 1.94 - 2.00Å. In order to understand the processes of the transformations, the changes of φ/ψ, distances of NH-OC (dNH/CO) and formation energies (ΔE, kcal/mol/mu) were examined.

A Proposal of Sequencing the Combined Processes for Resources Recovery and Nitrogen Removal from Piggery Waste (슬러리형 돈사폐수에서 자원회수와 질소제거를 위한 순차적 결합공정 제안)

  • Hwang, In-Su;Min, Kyung-Sok;Bae, Jin-Yeon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.1
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    • pp.61-66
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    • 2006
  • The combined ADEPT(Anaerobic Digestion Elutriated Phased Treatment)-SHARON(Single reactor system for High Ammonium Removal Over nitrite)-ANAMMOX(Anaerobic ammonium oxidation) processes were operated for resources recovery and nitrogen removal from slurry-type piggery waste. The ADEPT process operated at an acidogenic loading rates of 3.95 gSCOD/L-day, the SCOD elutriation rate and acid production rate were 5.3 gSCOD/L-day and 3.3 gVFAs(as COD)/L-day, respectively. VS reduction and SCOD reduction by the hydrolysis were 13% and 0.19 $gSCOD_{prod.}/gVS_{feeding}$, respcetively. Also, the acid production rate was 0.80 $gVFAs/gSCOD_{prod}$. In methanogenic reactor, the gas production rate and methane content were 2.8 L/day($0.3m^3CH_4/kgCOD_{removal}@STP$) and 77%, respectively. With these operating condition, the removals of nitrogen and phosphorus were 94.1% as $NH_4-N$(86.5% as TKN) and 87.3% as T-P respectively.

Design of Flower Pattern in Roll Forming Process for Ultra High Strength Bumper Beam (초고강도 범퍼 빔의 롤 포밍 공정을 위한 플라워 패턴 설계)

  • Cha, T.W.;Kim, J.H.;Kim, G.H.;Kim, B.M.
    • Transactions of Materials Processing
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    • v.25 no.5
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    • pp.319-324
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    • 2016
  • Recently, the roll forming process is one of the most widely used processes for manufacturing automotive part. In this study, flower patterns of roll forming process were designed to manufacture an ultra high strength bumper beam using the finite element analysis. Three types of flower patterns such as the basic type, the rotation type and the split type were designed based on the constant arc length forming method using the design software, UBECO Profil. Finite element analysis was performed to evaluate the suitability of designed flower patterns in terms of the longitudinal strain and the bow defect. The analytical results show that the split type represents more uniform longitudinal strain distributions and a good dimensional accuracy than other types of flower patterns.

Inhibition by Hyaluronan of Collagen-Induced Activation of Hepatic Stellate Cells

  • Lee, Gum-Hwa;Cho, Min-Kyung;Kim, Sang-Geon
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.10b
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    • pp.120-120
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    • 2003
  • Synthesis and distribution of extracellular matrix (ECM) components are dynamically altered in response to the pathophysiological processes including infection, inflammation and apoptosis. In particular, the levels of hyaluronan (HA) change with concomitant increases in the levels of collagen (e.g. type I collagen) and fibronectin in chronic liver diseases.(omitted)

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Characterization of Activated Sludge Settlings in Korea (국내 하수처리장 활성 슬러지의 침전특성에 관한 연구)

  • Lee, Hwangu;Kim, Youngchul;Choi, Euiso
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.964-971
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    • 2009
  • In this paper, activated sludge settling was characterized based on field trip and zone settling tests. Plants used for this study include 5 conventional activated sludge processes and 3 A2O type treatment processes. The treatment capacities are in the range from 12,000 to $250,000m^3$/day. Total number of zone settling tests were 188 set and SVI values representing settling characteristics were from 100 to 300 mL/g. It was found out that zone settling velocity of these examined plant sludges can be approximated by mean values calculated by Keinath and Daigger/Roper models. Based on these three models, solid flux analysis were carried out in order to compare design criteria ($3.96{\sim}6.04kg/m^2-hr$) recommended by Korea Sewage Facility Design Guideline with two models used in USA. The results show that design criteria are only applicable for normal condition in settling characteristics (below SVI 100 mL/g). Solid flux analysis of surveyed plants indicates that most of the plants are operated underload conditions except several plants experiencing poor sludge settling problem. Most of the plants are operated under high sludge blanket depths (SBD).

Research on Risk Assessment of Lithium-ion Battery Manufacturing Process Considering Cell Materials (셀소재를 고려한 리튬2차전지 제조공정 위험성 평가 방법 연구)

  • Kim, Taehoon
    • Journal of the Korean Society of Safety
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    • v.37 no.2
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    • pp.76-87
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    • 2022
  • Lithium-ion batteries (LIBs) have attracted much interest for their high energy density (>150 mAh/g), high capacity, low self-discharge rate, and high coulombic efficiency. However, with the successful commercialization of LIBs, fire and explosion incidents are likely to increase. The thermal runaway is known as the major factor in battery-related accidents that can lead to a series of critical conditions. Considering this, recent studies have shown an increased interest in countering the safety issues associated with LIBs. Although safety standards for LIB use have recently been formulated, little attention has been paid to the safety around the manufacturing process for battery products. The present study introduces a risk assessment method suitable for assessing the safety of the LIB-manufacturing process. In the assessment method, a compensation parameter (Z-factor) is employed to correctly evaluate the process's safety on the basis of the type of material (e.g., metal anode, liquid electrolyte, solid-state electrolytes) utilized in a cell. The proposed method has been applied to an 18650 cell-manufacturing process, and three sub-processes have been identified as possibly vulnerable parts (risk index: >4). This study offers some crucial insights into the establishment of safety standards for battery-manufacturing processes.

Development of a Fine Digital Sun Sensor for STSAT-2

  • Rhee, Sung-Ho;Lyou, Joon
    • International Journal of Aeronautical and Space Sciences
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    • v.13 no.2
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    • pp.260-265
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    • 2012
  • Satellite devices for fine attitude control of the Science & Technology Satellite-2 (STSAT-2). Based on the mission requirements of STSAT-2, the conventional analog-type sun sensors were found to be inadequate, motivating the development of a compact, fast and fine digital sun sensor (FDSS). The FDSS uses a CMOS image sensor and has an accuracy of less than 0.03degrees, an update rate of 5Hz and a weight of less than 800g. A pinhole-type aperture is substituted for the optical lens to minimize its weight. The target process speed is obtained by utilizing the Field Programmable Gate Array (FPGA), which acquires images from the CMOS sensor, and stores and processes the image data. The sensor accuracy is maintained by a rigorous centroid algorithm. This paper describes the FDSS designs, realizations, tests and calibration results.

Development of Anti-Fingers Printed EGI Steel Sheet With High Corrosion Resistance (고내식성 내지문 EGI 강판 개발)

  • 김형준
    • Journal of the Korean institute of surface engineering
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    • v.26 no.6
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    • pp.307-315
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    • 1993
  • A study on a new anti-finger printed EGI steel sheet with high corrosion resistance has been carried out to meet the recent requirement of high quality and performance of the pure zinc electrogalvanized steel sheet. The substrate was the pure zinc electrogalvanized sheet with the metallic coating of 20g/$\m^2$. The two differ-ent processes for inorganic(chromating) and organic(resin) coating were applied. One was a two coat/two bake type to separately treat chromating and resin coating which is now widely used. The other was a one coat/one bake type to simultaneously treat them which is newly developed in this study. The solution for the one coat/one bake type was an aqua-base coating agents which was composed of inorganic and organic components. The new anti-finger printed EGI steel sheet with the Cr and resin coating weight of 13mg/$\m^2$ and 800mg/$\m^2$, respectively shows the superior corrosion resistance besides the good paintability, formability fingerprint resistance and earth characteristics properties.

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