• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.5
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• pp.88-93
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• 2012

This paper describes the machinability of the sintered carbide and tool-die steel(STD-11) by electric discharge drilling with various tubular electrodes which have multi-holes. Various types of electrode which have different diameters and materials are used with the application of continuous direct current and axial electrode feed. Inner part of electrodes are inserted with smaller tubes or Y-channel or bar. In ED-Drilling, the dielectric flushed down the interior of the rotating tube electrode, in order to remove machining debris from the hole. As result of experiments, the bigger the diameter of the electrode is, the lower the material removal rate is. Machinability of copper electrode is higher than that of brass. In machining of sintered carbide, to use oil is better than distilled water as dielectric.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2000.11a
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• pp.827-830
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• 2000

This paper describes the machining characteristics of the sintered carbide and die steel by electric discharge drilling with various tubular electrodes. Electrical discharge machining(EDM) removes material from the workpiece by a series of electrical sparks that cause localized temperatures high enough to melt or vaporise the metal in the vicinity of the charge. In the experiment, four types of electrode which have different diameter are used with the application of continuous direct current and axial electrode feed. The controlled factors include the dimension of the electrode. In drilling by EDM, the dielectric flushed down the interior of the rotating tube electrode, in order to facilitate the removal of machining debris from the hole.

• Journal of the Korean institute of surface engineering
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• v.30 no.5
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• pp.333-346
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• 1997

Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.3
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• pp.73-79
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• 2012

This paper describes the machining characteristics of the sintered carbide and die steel(STD-11) by electric discharge drilling with various tubular electrodes. Electrical discharge machining(EDM) removes material from the workpiece by a series of electrical sparks that cause localized temperatures high enough to melt or vapourize the vicinity of the charge. In the experiment. four types of electrode which have different diameter are used with the application of continuous direct current and axial electrode feed. The controlled factors include the dimension of the electrode. In drilling by EDM, the dielectric flushed down the interior of the rotating tube electrode, in order to order to facilitate the removal of machining debris the hole. The expansion increase with increasing the thickness of material and the diameter of electrode and the expansion of sintered carbide is 1.75 times large then that of die steel. The taper of machined hole decrease with increasing the thickness of material. The crater sixe of die steel is larger then thet of sintered carbide and the surface roughness of sintered carbide is 1.58 tims larger then that of die steel.

• Journal of the Korean Chemical Society
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• v.33 no.4
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• pp.388-398
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• 1989

A continuous-automated method for the determination of nitrite ion using gas-sensing membrane electrode was developed. The pH electrode of tubular PVC membrane type was used as a detector of this system. The slope of linear response of the electrode measured at optimum conditions for the continuous-automated determination of nitrite ion was 63.5 mV/decade. The concentration range of linear response and detection limit were 2.5 ${\times}10^{-4}{\sim}\;7.5{\times}10^{-2}$M and $8.0{\times}10^{-5}$M, respectively. This detection system was not only less interfering to acidic gas species than other methods but also less time consumable for determination.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2423-2430
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• 2014

Nitrogen-doped short tubular carbons (N-STCs) with big inner diameter have been successfully synthesized via carbonization of polydopamine (PDA) wrapped halloysite nanotubes (HNTs). The obtained N-STCs have average length of $0.3{\mu}m$ with big inner diameter (50 nm), thin wall (2-3 nm) and large surface area ($776m^2g^{-1}$), and show excellent electrochemical properties. As an example in electrochemical applications, N-STCs were used to electrochemically detect hydrogen peroxide ($H_2O_2$) and glucose. The results showed that the N-STCs modified glassy carbon (N-STCs/GC) electrode had much better analytical performance (lower detection limit and wider linear range) compared to the acid-treated carbon nanotubes (AO-CNTs) based GC electrode. The unique structure endows N-STCs the enhanced electrochemical performance and promising applications in electrochemical sensing.

• Proceedings of the KIEE Conference
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• 1995.07c
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• pp.1093-1094
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• 1995

A porous electrode substrate of Ni-YSZ cermet anode was used as a support for YSZ film fabrication. The purpose of this research is to investigate characteristics for tubular solid oxide fuel cell.

• Journal of the Korean Chemical Society
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• v.35 no.1
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• pp.51-58
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• 1991

A new tubular poly(vinyl chloride) membrane type of nitrate selective electrode was prepared and its characteristics were evaluated. The response slope, detection limit, and response time (t$_{99}$) under the optimum membrane composition (5${\%}$ aliquat-NO$_3$ solution + 32${\%}$ poly(vinyl chloride) + 63${\%}$ dibutyl sebecate) of the electrode were 58.5 ${\pm}$ 0.1 mV/decade, 2.0 ${\times}$ 10$^{-5}$ M, and 25 seconds, respectively. The nitrite ion was determined by the continuous-automated method using the new electrode. 10$^{-2}$ M phosphate buffer solution (pH 7.6) was used as a recipient solution. And also hydrogen peroxide (0.3${\%}$) was added to the recipient as an oxidant. The linear response range and response range and response slope for the standard nitrite solution under the optimum condition of this electrode system were 8.0 ${\times}$ 10$^{-5}$ M ∼ 5.0 ${\times}$ 10$^{-2}$ M and 56.8 ${\pm}$ 0.2 mV/decade, respectively.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2002.11a
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• pp.191-196
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• 2002

In this paper we introduce novel electrode structure for high efficiency discharge. We operate discharge tube under the 0.16 torr pure Xe and apply the sinusoidal wave power to the lamp with 60kHz. We measure the electric power dissipation, plasma parameters, and 828 nm IR intensity. From these data we determine the discharge efficiency, IR intensity/watt, EEDF(Electron energy distribution function). As a result we obtain that the novel electrode structure has better performance in efficiency than that of conventional external electrode system. Also we determine the EEDF for each type of electrode structure by Boltzmann stover, EELNDIF code. The result of Boltzmann equation solving show that the noble electrode system has many high energy electrons compared with the conventional system.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2007.11a
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• pp.193-198
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• 2007

KIER has been developing the anode supported flat tubular SOFC stack for the intermediate temperature $(700{\sim}800^{\circ}C)$ operation. for this purpose, we have first fabricated anode supported flat tubular cells by the optimization between the current collecting method and the induction brazing process. After that we designed the compact fuel & air manifold by adopting the simulation technique to uniformly supply fuel & air gas and the unique seal & insulation method to make the more compact stack. For making stack, the prepared anode-supported flat tubular cells with effective electrode area of $90cm^2$ of connected in series with 12 modules, in which one module consists of two cells connected in parallel. The performance of stack in 3 % humidified $H_2$ and air at $800^{\circ}C$ shows maximum power of 507 W. Through these experiments, we obtained basic & advanced technology of the anode-supported flat tubular cell and established the proprietary concept of the anode-supported flat tubular SOFC stack in KIER.