• 제목/요약/키워드: Tubular Cell

검색결과 288건 처리시간 0.025초

연료극 지지체식 원통형 고체산화물 연료전지의 성능 특성 (Performance Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell)

  • 송락현;송근숙
    • 한국재료학회지
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    • 제14권5호
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    • pp.368-373
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    • 2004
  • To improve the conventional cathode-supported tubular solid oxide fuel cell (SOFC) from the viewpoint of low cell power density, expensive fabrication process and high operation temperature, the anode-supported tubular solid oxide fuel cell was investigated. The anode tube of Ni-8mol% $Y_2$O$_3$-stabilized $ZrO_2$ (8YSZ) was manufactured by extrusion process, and, the electrolyte of 8YSZ and the multi-layered cathode of $LaSrMnO_3$(LSM)ILSM-YSZ composite/$LaSrCoFeO_3$ were coated on the surface of the anode tube by slurry dip coating process, subsequently. Their cell performances were examined under gases of humidified hydrogen with 3% water and air. In the thermal cycle condition of heating and cooling rates with $3.33^{\circ}C$/min, the anode-supported tubular cell showed an excellent resistance as compared with the electrolyte-supported planar cell. The optimum hydrogen flow rate was evaluated and the air preheating increased the cell performance due to the increased gas temperature inside the cell. In long-term stability test, the single cell indicated a stable performance of 300 mA/$\textrm{cm}^2$ at 0.85 V for 255 hr.

원통형 고체산화물 연료전지 스택 제작 및 성능평가 (Fabrication and Performance Evaluation of Tubular Solid Oxide Fuel Cells Stack)

  • 김완제;이승복;송락현;박석주;임탁형;이종원
    • 한국수소및신에너지학회논문집
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    • 제24권6호
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    • pp.467-471
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    • 2013
  • In present work, optimized the manufacturing process of anode-supported tubular SOFCs cell and stack were studied. For this purpose, we first developed a high performance tubular SOFC cell, and then made electrical connection in series to get high voltage. The gas sealing was established by attaching single cells to alumina jig with ceramic bond. Through these process, we can obtain such high OVP as around 15V, which means that the electrical connection and gas sealing were optimized. Finally we developed a new tubular SOFC stack which shows a maximum power of 65W @ $800^{\circ}C$.

세그먼트 SOFC 관형 세라믹 지지체의 제작 및 특성 평가 (Evaluation of Properties and Fabrication of Tubular Supports Segmented-in-Series Solid Oxide Fuel Cell (SOFC))

  • 윤의진;이종원;이승복;임탁형;박석주;송락현;신동렬;한규승
    • 한국수소및신에너지학회논문집
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    • 제21권3호
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    • pp.214-219
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    • 2010
  • In this study, we fabricated tubular ceramic support for segmented-in-series solid oxide fuel cell (SOFC) by using CSZ(CaO-stabilized $ZrO_2$) as main material and activated carbon as pore former. Thermal expansion properties of ceramic support with different amounts of activated carbon were analyzed by using dilatometer to decide a suitable sintering temperature. The tubular ceramic supports with different amounts of activated carbon (5, 10, 15wt.%) were fabricated by the extrusion technique. After sintering at $1100^{\circ}C$ and $1400^{\circ}C$ for 5h., cross section and surface morphology of tubular ceramic support were analyzed by using SEM image. Also, the porosity, mechanical property, gas permeability of tubular ceramic supports was measured. Based on these results, we established the suitable fabrication technique of tubular ceramic support for segmented-in-series SOFC.

원통형 고체산화물 연료전지 기술개발 (Development of Tubular Solid Oxide Fuel Cell)

  • 송락현
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2001년도 유체기계 연구개발 발표회 논문집
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    • pp.373-380
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    • 2001
  • Solid Oxide Fuel Cells (SOFCs) have received considerable attention because of the advantages of high effiiciency, low pollution, cogeneration application and excellent integration with simplified reformer In this paper, we reported development of anode-tubular SOFC by wet process. For making tubular cell, Ni-cermet YSZ anode tube was fabricated using extrusion process, and YSZ electrolyte layer and LSM-YSZ composite, LSM, LSCF cathode layer were coated onto the anode supported tube using slurry dipping process and sintered by co-firing process. By using this tubular cell, we fabricated single cell consisted of the various cathode layers and 4 cell stack with an effective area of $75 cm^2$ per single cell, and evaluated their performance characteristics.

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관형 고체산화물연료전지 테스트 지그 최적화 (Optimal Design for Tubular SOFC Testing Jig)

  • 최훈;안권성;신창우;차석원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.303-306
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    • 2009
  • High temperature solid oxide fuel cells (SOFCs) offer a clean, pollution-free technology to electrochemically generate electricity at high efficiencies. Solid oxide fuel cells in several different designs have been investigated; these include planar and tubular geometries. The tubular type cell is widely researched due to it have advantages about thermal expansion and sealing issues. Unfortunately, lab scale tubular cell for testing has thermal expansion and sealing problems. The previous Jig for lab scale tubular cell testing has many sealing problems. When we feed fuel gas to jig inlet, ceramic glue sealant has amount of gas expansion pressure, because temperature of feeding gas changes ambient temperature to high temperature ($700{\sim}900^{\circ}C$). Furthermore, when we carry out long time test, something like degradation test, crack of ceramic glue sealant due to weakness of mechanical properties can make stop working the test. Additionally, we reduce setting process for assembling, because micanite is not required drying or debinding process.

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500W 급 연료극 지지체 평관형 고체산화물연료전지 스택의 운전 특성 (Operating Characteristics of Advanced 500W class Anode-supported Flat Tubular SOFC stack in KIER)

  • 임탁형;김관영;박재량;송락현;이승복;신동열
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2007년도 추계학술 발표회
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    • pp.193-198
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    • 2007
  • KIER has been developing the anode supported flat tubular SOFC stack for the intermediate temperature $(700{\sim}800^{\circ}C)$ operation. for this purpose, we have first fabricated anode supported flat tubular cells by the optimization between the current collecting method and the induction brazing process. After that we designed the compact fuel & air manifold by adopting the simulation technique to uniformly supply fuel & air gas and the unique seal & insulation method to make the more compact stack. For making stack, the prepared anode-supported flat tubular cells with effective electrode area of $90cm^2$ of connected in series with 12 modules, in which one module consists of two cells connected in parallel. The performance of stack in 3 % humidified $H_2$ and air at $800^{\circ}C$ shows maximum power of 507 W. Through these experiments, we obtained basic & advanced technology of the anode-supported flat tubular cell and established the proprietary concept of the anode-supported flat tubular SOFC stack in KIER.

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고정화된 효모로 충전된 관형발효기에서의 에탄올 연속발효 (Comparative Study on Continuous Ethanol Fermentation by Immobilized Tubular Fermentor)

  • 서근학;최명호;송승구
    • 한국미생물·생명공학회지
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    • 제16권3호
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    • pp.205-212
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    • 1988
  • Saccharomyces formosensis를 wood chip과 alginate gel에 고정화 실험을 한 결과, 모두 효모 고 정화도 매우 높으므로 고정화를 인한 Support로서 적절한 것으로 판단되었다. 관형발효기에 효모를 고 정화한 wood chip 및 alginate gel를 충전하여 연속발효 실험을 수행한 경우 0.446-0.485g EtOH/ g glucose로서 비슷하였으나, cell 수율은 alginate gel의 경우가 wood chip의 경우보다 낮아서 down stream의 처리시 유리하였다. 관형발효기의 에탄을 생산성은 wood chip을 이용할 경우 정상상태에서 에탄을 농도 68.3-54.9g/$\ell$ 범위에서 17.1-32.6g EtOH/$\ell$.hr를 나타내었고, alginate gel을 이용할 경우 정상상태에서 에탄올 농도 80.0-56.8g/$\ell$범위에서 에탄올 생산성은 20.0-32.0g EtOH/ hr를 얻었다. 본 실험의 에탄올 생산성은 다른 고정화법에 비하여 높았으며, 고정화 방법 중 alginate gel을 이용한 고정화법은 에탄을 생산을 위하여 효과적인 에탄을 생산 방법으로 사료되었다.

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비예혼합 튜브형상내 화염셀의 거동에 대한 수치 해석적 연구 (A Numerical Study of the Flame Cell Dynamics in Opposed Nonpremixed Tubular Configuration)

  • 박현수;유춘상
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.175-178
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    • 2014
  • The flame cell dynamics in 2-D opposed nonpremixed tubular configuration was investigated using high-fidelity numerical simulations. The diffusive-thermal instability occurs as the $Damk{\ddot{o}}hler$ number, Da, approaches the 1-D extinction limit of the tubular flames and several flame cells are generated depending on Da, and flame radius. In general, the number of flame cells are found close to the largest wave number from the linear stability analysis. It was also found from the displacement speed analysis that during the local flame extinction and cell formation, negative edge flame speed is observed due to small gain from reaction compared to large loss from diffusion.

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Fabrication of YSZ-based Micro Tubular SOFC Single Cell using Electrophoretic Deposition Process

  • Yu, Seung-Min;Lee, Ki-Tae
    • 한국세라믹학회지
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    • 제52권5호
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    • pp.315-319
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    • 2015
  • Yttria-stabilized zirconia (YSZ)-based micro tubular SOFC single cells were fabricated by electrophoretic deposition (EPD) process. Stable slurries for the EPD process were prepared by adding phosphate ester (PE) as a dispersant in order to control the pH, conductivity, and zeta-potential. NiO-YSZ anode support, NiO-YSZ anode functional layer (AFL), and YSZ electrolyte were consecutively deposited on a graphite rod using the EPD process; materials were then co-sintered at $1400^{\circ}C$ for 4 h. The thickness of the deposited layer increased with increasing of the applied voltage and the deposition time. A YSZ-based micro tubular single cell fabricated by the EPD process exhibited a maximum power density of $0.3W/cm^2$ at $750^{\circ}C$.

Decursin derivative-004 protect renal cell damage via p38 MAPK inhibition

  • Shin, Seon-Mi;Kim, Hyeon-Ho;Kim, Ik-Hwan
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.337.1-337.1
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    • 2002
  • Hypertrophy and the alteration of renal cell growth have been reported as early abnormality in diabetic nephropathy. However, the effects ot high PKCglucose and its action mechanism in renal proximal tubular cell (PTC) have not been elucidated. High glucose condition increases diacyl glycerol (DAG) and activates protein kinase C (PKC) in renal tubular cells. The PKC activates mitogen-activated protein kinases (MAPK), such as extracellular regulated kinase (ERK) and p38 MAPK. (omitted)

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