• Title/Summary/Keyword: Tube-sheet

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Electrochemical Properties of Carbon Nano-Tube Electrode (탄소나노튜브 전극의 전기화학적 특성)

  • Lee Dong-Yoon;Koo Bo-Kun;Lee Won-Jae;Song Jae-Sung;Kim Hyun-Ju
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.139-143
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    • 2005
  • For application of carbon nano-tube (CNT) as a counter electrode materials of dye-sensitized solar cell (DSSC), the electrochemical behavior of CNT electrode was studied, employing cyclic-voltammetry (C-V) and impedance spectroscopy. Fabrication of CNT-paste and formation of CNT-counter electrode for characteristic measurement have been carried out using ball-milling and doctor blade process, respectively. Unit cell for measurements was assembled using Pt electrode, CNT electrode, and iodine-embedded electrolyte. Field emission-scanning electron microscopy (FE-SEM) was used for structural investigation of CNT powder and electrode. Sheet resistance of electrode was measured with 4-point probe method. Electrochemical properties of electrode, C-V and impedance spectrum, were studied, employing potentiogalvanostat (EG&G 273A) and lock in amplifier (EG&G 5210). As a results, the sheet resistance of CNT electrode is almost similar to that of F-doped SnO2 (FTO) coated glass substrate as approximately 10 ohm/sq. From C-V and impedance spectroscopy measurements, it was found that CNT electrode has high reaction rate and low interface reaction resistance between CNT surface and electrolyte. These results provides that CNT electrode were superior to that of conventional Pt electrode. Particularly, the reaction rate in the CNT electrode is about thrice high than Pt electrode. Therefore. CNT electrode is to be good candidate material for counter electrode in DSSC.

A Facile Strategy to Fabricate TiO2 Nanostructures with Controllable Crystalline Polymorphs and Morphologies and Their Photoelectrochemical Applications

  • Choe, Min-Gi;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.466.1-466.1
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    • 2014
  • $TiO_2$는 저렴한 가격, 적절한 bandgap, 열적, 화학적, 생물학적 안정성 등으로 촉망받는 광촉매 물질이다. $TiO_2$는 rutile (tetragonal, space group: P42/mnm), anatse (tetragonal, space group: I41/amd), and brookite (orthorhombic, space group: Pbca )의 3가지 대표적인 결정구조를 가지고 있다. Rutile과 anatase는 1972년 Fujishima와 Honda가 $TiO_2$의 광촉매 특성을 발견 한 후로 아주 많은 연구가 되어왔다. 반면 brookite의 경우는 자연에 거의 존재하지 않으며, 합성방법도 어려워서 rutile과 anatase에 비해 많은 연구가 되지 않았다. 본 연구에서는 brookite를 포함한 다양한 $TiO_2$ 나노구조를 간단한 수열합성법으로 티타늄 호일 위에 합성하였다. 합성된 $TiO_2$는 반응 온도와 시간, additive의 농도에 따라서 sheet, tube, wire, pyramidal 의 4가지 morphologies를 가졌다. 이 다양한 morphologies은 SEM과 TEM으로 분석되었으며, 각 물질의 결정 구조는 XRD분석과 TEM의 SAED pattern 분석으로 sheet, tube, wire은 anatase, pyramidal 구조는 brookite라는 것이 확인 되었다. 위의 방법으로 합성된 각각의 $TiO_2$ 물질들을 working 전극으로, Pt와 Ag/AgCl을 reference와 counter 전극으로 만들어서 photoelectrochemical 특성을 측정해서 비교를 해보았을 때, brookite 물질이 anatase보다 더 좋은 photoelectrochemical 특성을 나타내는 것을 확인하였다.

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The Experimental Study on Axial Loaded Concrete Filled Steel Tube Confined by Carbon Fiber Sheet (탄소섬유쉬트로 구속된 콘크리트충전 각형강관기둥의 단조압축실험)

  • Park, Jai Woo;Hong, Young Kyun;Hong, Gi Soup;Lee, Seoung Hee;Choi, Sung Mo
    • Journal of Korean Society of Steel Construction
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    • v.21 no.3
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    • pp.311-320
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    • 2009
  • This paper presents the experimental results of an experiment on the current rectangular CFT columns and rectangular CFT columns additionally confined by carbon fiber sheets(CFS) under axial loading. The main experimental parameters were the layer numbers of the CFS and the depth-to-thickness ratio. Nine specimens were prepared according to the experimental parameter plans, and axial compression tests were conducted. From the tests, the failure procedure, the load-axial deformation curve, the maximum axial strength, and the deformation capacity of the CFT columns and the confined CFT columns were compared. Finally, it was seen that the maximum axial strengths of the CFT increased more significantly than that of the current CFT columns because of delayed local buckling.

Evaluation of Tungsten Blended Filament Shields Made by 3D Printer in Radiography (일반촬영분야에서의 3D 프린터로 제작한 텅스텐 혼합 필라멘트 차폐체의 성능평가)

  • Yoon, Joon;Yoon, Myenog-Seong
    • Journal of radiological science and technology
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    • v.44 no.6
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    • pp.615-621
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    • 2021
  • In the medical field, radiation provides information for the diagnosis and treatment of diseases. As the use of radiation increases and the risk of exposure increases, interest in radiation protection is also rapidly increasing. Lead shielding material is mainly used, which has a risk of lead poisoning and absorption into the body. Tungsten mixed filament shielding sheets were fabricated with a size of 70 × 70 mm and a thickness of 1, 2, and 4 mm by using a 3D printer. In the general shooting experiment, the thickness of the shielding sheet is 1 ~ 5mm, the tube voltage is 60, 80, 100, 120 kVp and the tube current is 20, 40 mAs. In general photography, Tungsten showed better shielding rate compared to Brass, Copper, and Lead protective tools under all irradiation conditions, and in particular, Tungsten 5 mm showed 100% shielding rate. The 3D-printed tungsten mixed filament shielding is expected to be used as a new shield that can replace the existing lead protection tools as it shows a better shielding rate than the existing lead protection tools in Radiography.

Behavior of Geotextile Tube by Plane Strain Analysis and 3-Dimensional Finite Element Method (평면변형해석과 3-D FEM 기법을 통한 지오텍스타일 튜브의 거동해석)

  • 신은철;오영인
    • Journal of the Korean Geotechnical Society
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    • v.19 no.5
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    • pp.233-241
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    • 2003
  • Geotextile tube is hydraulically filled with dredged materials and has been applied to coastal protection and scour protection, dewatering method of slurry, and isolation of contaminated material. Recently, geotextile tube technology is no longer alternative construction technique but suitable desired solution. In this paper, the numerical analysis was performed to investigate the behavior of geotextile tube with various properties of geotextile sheet and hydraulic pumping conditions. Numerical analysis was executed to compare with the results from the large-scale field model tests, and also with those of plane strain analysis and 3-D FEM analysis. A geotextile tube was modeled using the commercial finite element analysis program ABAQUS and the one-quarter of tube was modeled. Behavior of geotextile tube during the hydraulic pumping procedure was analyzed by comparing the large-scale field model test and numerical analysis. The shape variation and maximum tube height between the numerical analysis results and large-scale filed test results are turned out to be in a good agreement.

A Study on Feasibility of the Phosphoric Acid Doping for Solar Cell Using Newly Atmospheric Pressure Plasma Source (새로운 대기압 플라즈마 소스를 이용한 결정질 실리콘 태양전지 인산 도핑 가능성에 관한 연구)

  • Cho, I-Hyun;Yun, Myoung-Soo;Jo, Tae-Hoon;Kwon, Gi-Chung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.6
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    • pp.95-99
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    • 2013
  • Furnace is currently the most important doping process using POCl3 in solar cell. However furnace need an expensive equipment cost and it has to purge a poisonous gas. Moreover, furnace typically difficult appling for selective emitters. In this study, we developed a new atmospheric pressure plasma source, in this procedure, we research the atmospheric pressure plasma doping that dopant is phosphoric acid($H_3PO_4$). Metal tube injected Ar gas was inputted 5 kV of a low frequency(scores of kHz) induced inverter, so plasma discharged at metal tube. We used the P type silicon wafer of solar cell. We regulated phosphoric acid($H_3PO_4$) concentration on 10% and plasma treatment time is 90 s, 150 s, we experiment that plasma current is 70 mA. We check the doping depth that 287 nm at 90 s and 621 nm at 150 s. We analysis and measurement the doping profile by using SIMS(Secondary Ion Mass Spectroscopy). We calculate and grasp the sheet resistance using conventional sheet resistance formula, so there are 240 Ohm/sq at 90 s and 212 Ohm/sq at 150 s. We analysis oxygen and nitrogen profile of concentration compared with furnace to check the doped defect of atmosphere.

Development of Ultrasonic Testing Method for Evaluation of Adhesive Layer of Blaster Tube (토출관 접합계면 평가를 위한 초음파 시험법 개발)

  • Kim, Y.H.;Song, S.J.;Park, J.S.;Cho, H.;Lim, S.Y.;Yun, N.G.;Park, Y.J.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.2
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    • pp.46-53
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    • 2004
  • Ultrasonic testing method has been developed to evaluate flaw of adhesive layers in blast tube for the reliability of the rocket nozzle. The ultrasonic reflection from the interface between the steel sheet and the epoxy adhesive is measured with a high-frequency Pulse-echo setup in order to identify contact debonding and missing adhesive in epoxy layer between steel and FRP layers. The steel sheet is resonated by low-frequency ultrasound, and the gap size underneath the measuring location is estimated from the resonance responses. For practical application in industry an automated testing system has been developed where the proposed approach is implemented. The performance of the proposed approach has been verified by actual measurement of gap sizes from the cross-sections of cut specimens using an optical microscope.

Development of ultrasonic testing method for the evaluation of adhesive layer of blast tube (토출관 접합계면 평가를 위한 초음파 시험법 개발)

  • Kim, Y.H.;Song, S.J.;Park, J.S.;Cho, H.;Lim, S.Y.;Yun, N.G.;Park, Y.J.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.230-237
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    • 2003
  • Ultrasonic testing method has been developed to evaluate adhesive layers in blast tube for the reliability of the rocket. The main objective of the present work was to find debonding and missing adhesive in epoxy layer between steel and FRP layers. In this approach, the ultrasonic reflection from the interface between the steel sheet and the epoxy adhesive is measured with a high-frequency pulse-echo setup in order to identify contact debonding and missing adhesive. Then, the steel sheet is excited to resonance by low-frequency ultrasound, and the gap size underneath the measuring location is estimated from the resonance responses. For practical application in industry an automated testing system has been developed where the proposed approach is implemented. The performance of the proposed approach has been verified by actual measurement of gap sizes from the cross-sections of cut specimens using an optical microscope.

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Solid State Joining Processes for Dissimilar Joints of Mg/Al Alloys (고상접합을 이용한 Al/Mg 합금의 이종 용접)

  • Kim, Heung-Ju;Kim, Wook-Seong;Chun, Chang-Keun;Chang, Woong-Seong
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.41-41
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    • 2009
  • To evaluate the applicability of dissimilar joining between Mg and Al alloys in automobile manufacturing process, solid state joining processes such as magnetic pulse welding(MPW), friction stir welding(FSW) and friction spot joining(FSJ) were attempted successfully. MPW process has been concentrated mainly on round section tube to tube and tube to bar welds. AZ31 Mg alloy has been successfully welded to pure Al A1070 as well as to Al alloy A3003. While, for friction stir welding of dissimilar sheet joints, AZ31B/A6061 with the thickness of 2mm were used and a square butt joint with a good quality was obtained at the conditions of 0.8mm/sec of travel speed and tool rotation speed of 850rpm. The maximum tensile strength of 179 MPa, which was about 80 % of the Mg base metal tensile strength, has been obtained. Finally, friction spot joining was attempted to make a dissimilar lap joint between AZ31(0.8mm) and A6061(1mm), while the joint exhibited the same level of tensile shear strength as that of similar Mg joint.

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Effect of a Coil Shape on an Impulse Velocity of the Electromagnetic Welding (전자기 용접의 충돌 속도에 대한 코일 형상의 영향)

  • Park, H.;Lee, K.;Lee, J.;Lee, Y.;Kim, D.
    • Transactions of Materials Processing
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    • v.28 no.3
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    • pp.135-144
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    • 2019
  • Electromagnetic impulse welding (EMIW) is a type of solid state welding using the Lorentz force generated by interaction between the magnetic field of the coil and the current induced in the workpiece. Although many experimental studies have been investigated on the expansion and compression welding of tube using the EMIW process, studies on the EMIW process of lap joint between flat sheets are uncommon. Since the magnetic field enveloped inside the tube can be controlled with ease, the electromagnetic technique has been widely used for tube welding. Conversely, it is difficult to control the magnetic field in the flat sheet welding so as to obtain the required welding velocity. The current study analyzed the effects of coil shape on the impulse velocity for suitable flat one-turn coil for the EMIW of the flat sheets. The finite element (FE) multi-physics simulation involving magnetic and structural field of EMIW were conducted with the commercial software LS-DYNA to evaluate the several shape variables, viz., influence of various widths, thicknesses, gaps and standoff distances of the flat one-turn coil on the impulse velocity. To obtain maximum impulse velocity, the flat one-turn coil was designed based on the FE simulation results. The experiments were performed using an aluminum alloy 1050 sheets of 1.0mm thickness using the designed flat one-turn coil. Through the microscopic interfacial analysis of the welded specimens, the interfacial connectivity was observed to have no defects. In addition, the single lap joint tests were performed to evaluate the welding strength, and a fracture occurred in the base material. As a result, a flat one-turn coil was successfully designed to guarantee welding with bond strength equal to or greater than the base material strength.