• Journal of Korean Society of Steel Construction
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• v.25 no.1
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• pp.15-24
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• 2013

This paper presents the results from a systematic finite element study on the bending moment resisting capacity of double web-angle connection for a CFT(concrete filled tube) composite frame subjected to cyclic loading. The three-dimensional nonlinear finite element models are constructed to investigate the rotational stiffness, bending moment capacity, and failure modes of the partially restrained composite CFT connections. A wide scope of additional structural behaviors explain the different influences of the double web-angle connections parameters, such as the different thickness of connection angles and the gage distances of high strength steel connection bar. The moment-rotation angle relationships obtained statically from the finite element analysis are compared with those from Richard's theoretical equation.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2637-2642
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• 2011

A new ultrasonic-assisted micellar extraction and cloud-point pre-concentration method was developed for the determination of major saikosaponins, namely saikosaponins -A, -C and -D, in Radix Bupleuri by high performance liquid chromatography with evaporative light scattering detection (HPLC-ELSD). The non-ionic surfactant Genapol X-080 (oligoethylene glycol monoalkyl ether) was chosen as the extraction additive and parameters affecting the extraction efficiency were optimized. The highest yield was obtained with 10% (w/v) Genapol X-080, a liquid/solid ratio of 200:1 (mL/g) and ultrasonic-assisted extraction for 40 min. In addition, the optimum cloud-point pre-concentration was reached with 10% sodium sulfate and equilibration at $60^{\circ}C$ for 30 min. Separation was achieved on an Ascentis Express C18 column (100 ${\times}$ 4.6 mm i.d., 2.7 ${\mu}M$) using a binary mobile phase composed of 0.1% acetic acid and acetonitrile. Saikosaponins were detected by ELSD, which was operated at a $50^{\circ}C$ drift tube temperature and 3.0 bar nebulizer gas ($N_2$) pressure. The water-based solvent modified with Genapol X-080 showed better extraction efficiency compared to that of the conventional solvent methanol. Recovery of saikosaponins ranged from 93.1 to 101.9%. An environmentally-friendly extraction method was successfully applied to extract and enrich major saikosaponins in Radix Bupleuri.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.4
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• pp.243-250
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• 2011

In order to investigate the effects of PAG oil concentration on heat transfer performance and pressure drop during gas cooling process of $CO_2$, the experiments on fin-tube heat exchanger of $CO_2$ heat pump were performed. The experimental apparatus consists of a gas cooler, a heater, a chiller, a mass flow meter, a pump and measurement system. Experiments were conducted in various experimental conditions, which were inlet temperature($110^{\circ}C$), mass flow rates (50, 55, 60, 65, 70 g/s) and PAG oil concentration(0 to 2.6 wt%). Heat transfer rate decreased with the increase of the oil concentration and the decrease of inlet pressure. And pressure drop increased with the increase of the oil concentration and mass flow rate of refrigerant. The COP reduction by deterioration of gas cooler performance with oil concentration was analyzed. When inlet pressure of gas cooler is 100 bar, the COP reduction was estimated by 6% under 1 wt% of oil concentration.

• Journal of the Korean GEO-environmental Society
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• v.9 no.2
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• pp.61-65
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• 2008

In this study, a newly modified soil nailing technology named as the PGSN (Pressurized Grouting Soil Nailing) system is proposed. Effects of various factors related to the design of the pressurized grouting soil nailing system, such as the length of re-bars and type of reinforcement materials, were examined throughout a series of the displacement-controlled field pull-out tests. 9 displacement-controlled field pull-out tests were performed and the ratio of injected grout volume to grout hole volume were also evaluated based on the measurements. In addition, short-term characteristics of pull-out deformations of the newly proposed PGSN system were analyzed and compared with those of the ordinary soil nailing system by carrying out field pull-out tests. The test results were shown that the displacements of pressurized grouting soil nailing system were decreased 30~36% in comparison with using gravity grouting soil nailing system by the pressurized effect. The displacements of steel tube were diminished 31~32% comparison with using deformed bar by the reinforcement type change from the field pull-out tests.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.3A
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• pp.383-390
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• 2008

A Precast Prefabricated Bridge Column using steel tube and prestressing bar was proposed for the application of precast method on substructure. A column specimen designed by the proposed bridge column system was made and performed a quasi-static test. The failure mode appeared to be a flexural failure and there is no damage on column segment connection. And it is good use of the self-centering ability by prestressing force. Test results showed that a column specimen satisfy the earthquake specification, and the structural stability was verified. Nonlinear finite element analysis was performed and compared with the test results. Force-displacement relation and location of crack from the analysis results were compared with the test results and it agreed well. The quantitative analysis was also performed by a parametric study using this modeling technique.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.553-558
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• 2012

A simple new method was developed for the determination of betaine in Fructus Lycii using hydrophilic interaction liquid chromatography with evaporative light scattering detection (HILIC-ELSD). Good chromatographic separation and reasonable betaine retention was achieved on a Kinetex HILIC column ($2.1{\times}100mm$, $2.6{\mu}m$) packed with fused-core particle. The mobile phase consisted of (A) acetonitrile and (B) 10 mM ammonium formate (pH 3.0)/acetonitrile (90/10, v/v). It was used with gradient elution at a flow rate of 0.7 mL/min. The column temperature was set at $27.5^{\circ}C$ and the injection volume was $10{\mu}L$. The ELSD drift tube temperature was $50^{\circ}C$ and the nebulizing gas (nitrogen) pressure was 3.0 bar. Stachydrine, a zwitterionic compound, was used as an internal standard. Calibration curve over $10-250{\mu}g/mL$ showed good linearity ($R^2$ > 0.9992) and betaine in the 70% methanol extract of Fructus Lycii was well separated from other peaks. Intraand inter-day precision ranged from 1.1 to 3.0% and from 2.4 to 5.3%, respectively, while intra- and inter-day accuracy ranged from 100.0 to 107.0% and from 94.3 to 103.9%, respectively. The limit of quantification (LOQ) was $10{\mu}g/mL$ and the recoveries were in the range of 98.2-102.7%. The developed HILIC-ELSD method was successfully applied to quantitatively determine the amount of betaine in fourteen Fructus Lycii samples from different locations, demonstrating that this method is simple, rapid, and suitable for the quality control of Fructus Lycii.