• 제목/요약/키워드: Triplets

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Weak Interactions Between Organic Molecules and Alkali Metal Ions Present in Zeolites Help Manipulate the Excited State Behavior of Organic Molecules

  • Ramamurthy, V.
    • Journal of Photoscience
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    • 제10권1호
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    • pp.127-148
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    • 2003
  • Zeolite is a porous highly interactive matrix. Zeolitic cations help to generate triplets from molecules that possess poor intersystem crossing efficiency. Certain zeolites act as electron acceptors and thus can spontaneously generate radical cations. Zeolites also act as proton donors and thus yield carbocations without any additional reagents. These reactive species, radical cations and carbocations, have long lifetime within a zeolite and thus lend themselves to be handled as ‘regular’ chemicals. Internal structure of zeolites is studded with cations, the counter-ions of the anionic framework. The internal constrained structure and the cations serve as handles for chemists to control the behavior of guest molecules included within zeolites.

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Soluble expression and purification of synthetic human bone morphogenetic protein-2 in Escherichia coli

  • Ihm, Hyo-Jin;Yang, Seung-Ju;Huh, Jae-Wan;Choi, Soo-Young;Cho, Sung-Woo
    • BMB Reports
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    • 제41권5호
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    • pp.404-407
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    • 2008
  • A 345-bp gene that encodes human bone morphogenetic protein-2 (hBMP-2) has been synthesized. The codon usage of the resulting gene was modified to include those triplets that are utilized in highly expressed Escherichia coli genes. The hBMP-2 gene was efficiently expressed in E. coli as a soluble and active protein. Since the recombinant hBMP-2 was readily solublized, no further solublization steps were required throughout purification. No additional tagging residues were introduced into the synthetic hBMP-2 gene product. The developed synthetic gene is a promising approach for scaling-up the soluble expression of hBMP-2.

경직형과 불수의운동형 뇌성마비 성인의 파열음 산출의 음향음성학적 특성 (Acoustic Properties Associated with the Plosive Production of Adults with Cerebral Palsy)

  • 김정연;황민아;박창일;지민제
    • 음성과학
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    • 제8권3호
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    • pp.209-224
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    • 2001
  • The purpose of this study was to identify the acoustic properties of 9 word initial Korean plosives in the speech of adults with cerebral palsy. Normal adults and two groups of adults with cerebral palsy (athetoid group and spastic group) participated in this study. Speech material included monosyllabic CVC real word pairs. Among the various acoustic properties of plosives, the aspiration duration was measured. Adults with cerebral palsy exhibited different patterns of aspiration duration for triplets of Korean plosives compared to normal adults. In addition, the plosive production of spastic group was distinguished from that of athetoid group. Such acoustic characteristics of plosives of adults with cerebral palsy may negatively affect the intelligibility of their speech.

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Monochorionic Triamniotic Triplet Pregnancy Following Assisted Reproductive Technology and Radiofrequency Ablation for Selective Reduction

  • Lee, Jeong-Heon;Oh, Su-Hyun;Hong, Ah-Reum;Jeong, Young-Ju;Cho, Sung-Nam;Cho, Dong-Hyu
    • Perinatology
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    • 제29권4호
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    • pp.180-184
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    • 2018
  • In assisted reproductive techniques, monozygotic twinning is not influenced by the trial of reducing the number of embryos transferred. We present extremely rare case of monochorionic triamniotic triplet pregnancy following in vitro fertilization and two-embryo transfer. During the first trimester, the crucial ultrasound findings of monochorionic triamniotic triplet pregnancy are three distinct amniotic sacs forming a triangle or ipsilon zone within a single chorionic cavity. After prudential counseling about the potential risk of a monochorionic triamniotic triplet pregnancy with the patient, selective reduction of two fetuses via radiofrequency ablation was performed. We report a case of selective reduction for monochorionic triamniotic triplet pregnancy using radiofrequency ablation at 12 weeks' gestation and obstetric progression after radiofrequency ablation was uneventful until 20 weeks' gestation.

Graph Database Solution for Higher Order Spatial Statistics in the Era of Big Data

  • Sabiu, Cristiano G.;Kim, Juhan
    • 천문학회보
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    • 제44권1호
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    • pp.79.1-79.1
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    • 2019
  • We present an algorithm for the fast computation of the general N-point spatial correlation functions of any discrete point set embedded within an Euclidean space of ${\mathbb{R}}n$. Utilizing the concepts of kd-trees and graph databases, we describe how to count all possible N-tuples in binned configurations within a given length scale, e.g. all pairs of points or all triplets of points with side lengths < rmax. Through benchmarking we show the computational advantage of our new graph-based algorithm over more traditional methods. We show that all 3-point configurations up to and beyond the Baryon Acoustic Oscillation scale (~200 Mpc in physical units) can be performed on current Sloan Digital Sky Survey (SDSS) data in reasonable time. Finally we present the first measurements of the 4-point correlation function of ~0.5 million SDSS galaxies over the redshift range 0.43< z <0.7. We present the publicly available code GRAMSCI (GRAph Made Statistics for Cosmological Information; bitbucket.org/csabiu/gramsci), under a GNU General Public License.

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Impact of Environmental Factors on Birth Weight in Teddy Goat

  • Raza, S.H.;Tahir, M.;Zia, S.;Iqbal, Arshad;Ahmad, Shafiq
    • Asian-Australasian Journal of Animal Sciences
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    • 제11권2호
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    • pp.152-154
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    • 1998
  • The data 1241 birth, weights of Teddy goats maintained at Livestock Production Research Institute, Bahadurnagar, Okara, Pakistan, during 1975-1990 were used for this study. The mean birth weight during study period ranged from $1.55{\pm}0.06$ to $1.78{\pm}0.09kg$ with and over all mean of $1.66{\pm}0.031kg$. It was found that year of birth, type of birth, sex of kid and age of dam had significant (p < 0.01) effects on birth weight while the effect of season was found to be non-significant. It was inferred that single born kids were significantly heavier than twins and twins were heavier than triplets. The mean values of birth weight for male and female kids were $1.70{\pm}0.032$ and $1.61{\pm}0.03kg$ respectively. The birth weight was found to be the highest in 8 year age group that was $1.82{\pm}0.016kg$ and the lowest in one year group $(1.55{\pm}0.02kg)$.

음소대조 검사방법을 이용한 마비말장애인의 말소리 명료도 특성 (The Speech Characteristics of Korean Dysarthria: An Experimental Study with the Use of a Phonetic Contrast Intelligibility Test)

  • Kim Soo Jin;Kim Young Tae;Kim Gi Na
    • The Journal of the Acoustical Society of Korea
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    • 제24권1E호
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    • pp.28-33
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    • 2005
  • This study was designed to suggest an assessment tool for analyzing the characteristics of Korean phonetic contrast intelligibility among dysarthric individuals. The intelligibility deficit factors of phonetic contrast in Korean dysarthric patients were analyzed through stepwise regression analysis. The 19 acoustic-phonetic contrasts proposed by Kent et al. (1999) have been claimed to be useful for clinical assessment and research on dysarthria. However, the test cannot be directly applied to Korean patients due to linguistic differences between English and Korean. Thus, it is necessary to devise a Korean word intelligibility test that reflects the distinct characteristics of the Korean language. To identify the speech error characteristics of a Korean dysarthric group, a Korean word list was audio-recorded by 3 spastic, 4 flaccid, and 5 mixed type of dysarthric patients. The word list consisted of monosyllabic consonant-vowel-consonant (CVC) real word pairs. Stimulus words included 41 phonemic contrast pairs and six triplets. The results showed that the percentage of errors in final position contrast was higher than in any other position. Unlike the results of previous studies, the initial-position contrasts were crucial in predicting the overall intelligibility among Korean patients.

Superconducting magnet system of in-flight separator for a heavy ion accelerator planned in Korea

  • Kim, J.W.;Kim, D.G.;Jo, H.C.;Choi, Y.S.;Kim, S.H.;Sim, K.D.;Sohn, M.H.
    • 한국초전도ㆍ저온공학회논문지
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    • 제17권1호
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    • pp.28-31
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    • 2015
  • An in-flight fragment separator, which aims to produce and study rare isotopes, consists of superferric quadrupole triplets and $30^{\circ}$ dipole magnets to focus and bend the beams for achromatic focusing and momentum dispersion, respectively. The separator is divided into pre and main stages, and we plan to use superconducting magnets employing high-Tc superconductor (HTS) coils in the pre-separator area, where radiation heating is high. The HTS coils will be cooled by cold He gas in 20-50 K, and in the other area, superferric magnets using low-temperature superconductor (LTS) will be used at 4 K. A few LTS coils were wound and successfully tested in a LHe dewar, and the design of cryostat has been optimized. Development of the HTS coils is ongoing in collaboration with a group at KERI. An HTS coil of racetrack shape was wound and tested in a $LN_2$ bath and in a dewar with cryocooler. No degradation on critical current due to coil winding was found.

Insights into the Usage of Nucleobase Triplets and Codon Context Pattern in Five Influenza A Virus Subtypes

  • Deka, Himangshu;Chakraborty, Supriyo
    • Journal of Microbiology and Biotechnology
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    • 제26권11호
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    • pp.1972-1982
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    • 2016
  • Influenza A virus is a single-stranded RNA virus with a genome of negative polarity. Owing to the antigenic diversity and cross concrete shift, an immense number of novel strains have developed astronomically over the years. The present work deals with the codon utilization partialness among five different influenza A viruses isolated from human hosts. All the subtypes showed the homogeneous pattern of nucleotide utilization with a little variation in their utilization frequencies. A lower bias in codon utilization was observed in all the subtypes as reflected by higher magnitudes of an efficacious number of codons. Dinucleotide analysis showed very low CpG utilization and a high predilection of A/T-ending codons. The H5N1 subtype showed noticeable deviation from the rest. Codon pair context analysis showed remarkable depletion of NNC-GNN and NNT-ANN contexts. The findings alluded towards GC-compositional partialness playing a vital role, which is reflected in the consequential positive correlation between the GC contents at different codon positions. Untangling the codon utilization profile would significantly contribute to identifying novel drug targets that will pacify the search for antivirals against this virus.

Photochemical Reactions of Saccharin-$\alpha$-Silylamine Systems. Desilylmethylation of $\alpha$-Silylamine via Single Electron Transfer Pathway

  • Ung Chan Yoon;Young Sim Koh;Hyun Jin Kim;Dong Yoon Jung;Dong Uk Kim;Sung Ju Cho;Sang Jin Lee
    • Bulletin of the Korean Chemical Society
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    • 제15권9호
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    • pp.743-748
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    • 1994
  • Photochemical reactions of saccharin with tertiary amines were explored. Saccharin was found to undergo an acid-base reaction with N-trimethylsilylmethyl-N,N-diethyl amine to form N-trimethylsilylmethyl-N,N-diethyl ammonium saccharin salt which is in equilibrium with free saccharin and N-trimethylsilylmethyl-N,N-diethyl amine insolution. Photoreaction of N-trimethylsilylmethyl-N,N-diethyl ammonium saccharin in $CH_3OH\;or\;CH_3CN$ results in the generation of desilylmethylated product, N,N-diethyl ammonium saccharin mainly along with benzamide. Photoreaction of N-methylsaccharin with N-trimethylsilylmethyl-N,N-diethyl amine in $CH_3OH$ leads to the production of o-(N-methylcarbamoyl)-N-ethylbenzenesulfonamid e as the major product along with N-methylbenzamide as the minor product. On the other hand, photoreaction of N,N,N-triethyl ammonium saccharin, generated from saccharin and triethylamine, produces N-methylbenzamide as the exclusive product. These photoreactions are quenched by oxygen indicating that triplets of saccharin and N-methylsaccharin are the reactive excited states. Based on the consideration of the redox potentials of saccharin and N-trimethylsilylmethyl-N,N-diethyl amine, and the nature of photoproducts, pathways involving initial triplet state single electron transfer are proposed for photoreactions of the saccharins with the ${\alpha}$-silylamine.