• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.404-409
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• 2000

Characteristics of secondary vortices is topologically investigated in the near-wake region of a circular cylinder where the Taylor hypothesis does not hold. The three-dimensional flow fields in the wake-transition regime were measured by a time-resolved PIV. For the analysis in a moving frame of reference, the convection velocity of the Karman vortices is evaluated from the trajectory of vortex center which is defined as the centroid of the vorticity field. Then, a saddle point is obtained by applying the critical point theory. Science the distributions of fluctuating Reynolds stresses defined by triple-decomposition are closely related with the existence of secondary vortices. the physical meaning of them is explained in conjunction with vortex center and saddle point trajectories. Finally, the temporal evolution of streamwise vortex is also discussed.

• 호남수학학술지
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• 제32권4호
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• pp.581-592
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• 2010

With the help of some techniques based upon certain inverse pairs of symbolic operators initiated by Burchnall-Chaundy, the authors investigate decomposition formulas associated with Saran's function $F_E$ in three variables. Many operator identities involving these pairs of symbolic operators are first constructed for this purpose. By employing their decomposition formulas, we also present a new group of integral representations for the Saran function $F_E$.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2019년도 학술발표회
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• pp.136-136
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• 2019

원형 실린더를 주변 흐름에 관한 연구는 오랜 기간 유체역학 전 영역에서 모형실험이나 수치모형으로 광범위하게 연구되었다. 이 흐름은 하천의 교각이나, 바다의 시추선과 같은 수공구조물 주변에서 관측된다. 난류와 와류가 공존하는 복잡한 특성 때문에, 이 흐름은 수공학에서 유사이송, 세굴, 오염물 확산 등에 영향을 준다. 본 연구는 실험실 수로에 설치된 원형 실린더(D=9cm) 후방의 근접 와류 구간에서(x/D<5) 유속을 ADV로 측정한 후, 난류 특성을 Power Spectral Estimation(PSE)와 Singular Spectral Analysis(SSA) 방법으로 연구하였다. PSE는 샘플 스펙트럼의 한계를 보완하고자 자료를 분할하고, window 함수를 적용하여 ensemble 평균을 구하는 경험적 방법이다. PSE를 이용하여 스펙트럼을 계산한 결과, 주 흐름 및 횡방향 흐름은 Inertial subrange에서 Kolmogorov의 가정과 일치하는 추세를 보였다. 그러나 수심방향 흐름의 스펙트럼은 -5/3보다 빠르게 감소하는 추세를 보였다. Inertial subrange 스펙트럼에서 난류 에너지 소산율은 원형 실린더에서 멀어짐에 따라 감소하는 추세를 보였고, 주 흐름방향과 횡방향 흐름은 비슷한 크기를 보였다. 난류 에너지 소산율과 동점성계수를 이용하여 Kolmogorov 길이, 유속, 시간 스케일을 계산했다. 난류의 운동에너지를 계산하기 위해 Triple decomposition 방법 중 하나인 SSA를 적용하였다. SSA는 유속행렬을 이용하여 고윳값과 고유벡터를 계산하고, 유속에서 기여도가 큰 부분을 추출하는 방법이다. SSA를 통해 실린더 후방 흐름에서 와류 성분과 난류 성분을 나누었다. 횡방향 흐름은 강한 와류로 큰 기여도를 갖는 고유벡터가 나타났지만, 주 흐름과 수심방향 흐름은 상대적으로 낮은 기여도를 갖는 고유벡터가 나타났다. 와류를 제외한 흐름에서 난류 운동에너지는 실린더와 멀어짐에 따라 감소하고, 흐름 중앙에서(y/D=0) 가장 큰 값을 보였다.

• 한국세라믹학회지
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• 제28권2호
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• pp.160-166
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• 1991

Microstructure and phase changes during the sintering of ZnO varistors were studied in ZnO-Bi2O3-CoO-Sb2O3 and ZnO-Bi2O3-CoO-Sb2O3-Cr2O3 systems using acanning electron microscopy (SEM) with an energy dispersive X-ray analysis (EDAX), X-ray diffraction (XRD) and differential thermal analysis (DTA). The spinel phase and the Bi2O3 phase were formed by the decomposition of the pyrochlore phase during heating. The spinel particles (2-4$\mu\textrm{m}$), which were formed both along ther grain boundaries and within the ZnO grain, were always found near the pyrochlore phase. Intergranular phases (Bi2O3 and pyrochlore) were precipitated from the liquid phase during cooling. The Bi2O3 phases were located at the triple (or multiple) point of the ZnO grains. Cr2O3 played a role in decreasing the formation temperature of the spinel phase and Bi2O3 phase during sintering, and inhibited the grain growth.

• 한국식품과학회지
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• 제37권3호
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• pp.334-338
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• 2005

본 연구는 식품병마개 PVC 가스켓과 식품에 함유된 SEM을 효과적으로 분석하기 위해 연구했다. SEM은 발포제로 사용되는 ADC의 열분해산물로 알려졌다. 그러나 SEM은 분자량이 낮으며 ultraviolet light나 fluorescence에 활성을 갖지 않는다. 따라서 2-NBA-SEM으로 유도체화하여 HPLC triple column system으로 분석했을 때 상관관계는 0.9997이상이며 검출한계는 0.48ng/g으로 나타났다. 식품병마개 PVC 가스켓에서 SEM의 검출율은 77.08%로 나타났으며, 유통중인 병마개 PVC 가스켓에서 SEM은 812.20-5771.30ng/g 수준이였다. 그리고 회수율은 PVC 가스켓과 식품에서 각각 92.12-98.71%와 83.45-97.33%로 측정되었다.

• 대한약리학회지
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• 제16권2호
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• pp.31-38
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• 1980

Calvert et al. formulated the hypothesis that carbon tetrachloride ($CCl_4$) acted on the central nervous system to produce and intensify sympathetic discharge which resulted in anoxic necrosis of the liver. Recknagel suggested that the essential feature of $CCl_4$ hepatotoxicity depended on the cleavage of it to $CCl_3$(free radical) and the peroxidative decomposition of cytoplasmic membrane structural lipids. And there are many reports which show the increase of adrenergic activity in hyperthyroidism. In this paper, the influence of thyroxine on the hepatotexicity of carbon tetrachloride was investigated in mice. The results obtained were summarized as follows; 1) Hepatic total lipid and lipid peroxide contents were slightly decreased by L-sodium thyroxine injection(4mg/kg/day for 4days or 6days), but hepatic glycogen content was significantly decreased. 2) Hepatic total lipid and lipid peroxide contents and serum lactic dehydrogenase activity were significantly increased by $CCl_4$ (4 ml/kg single dose or triple dose: 4ml/kg/day for 3days), but hepatic glycogen content was significantly decreased. 3) The increase of hepatic total lipid and lipid peroxide contents and serum lactic dehydrogenase activity induced by $CCl_4$ were significantly inhitited by the pretreatment of thyroxine. 4) The decrease of hepatic glycogen induced by $CCl_4$ was not affected by the pretreatment of thyroxine.

• 대한기계학회논문집B
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• 제25권10호
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• pp.1355-1364
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• 2001

Characteristics of secondary vortices is topologically investigated in the near-wake region of a circular cylinder, where the Taylor's hypothesis does nut hold. The three-dimensional flow fields in the wake-transition regime were measured by a time-resolved PIV for various planes of view. The convection velocities of the Karman and secondary vortices are evaluated from the trajectory of the vortex center. Then, saddle points are determined by applying the critical point theory. It is shown that the inclination angle of the secondary vortices agrees well with the previous experimental data. The flow fields in a moving frame of reference have several critical points and the mushroom-like structure appears in the streamline patterns of the secondary vortices. Since the distributions of fluctuating Reynolds stresses defined by triple decomposition are closely related with the existence of secondary vortices, the physical meaning of them is explained in conjunction with the vortex center and saddle point trajectories.

• Bulletin of the Korean Chemical Society
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• 제30권1호
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• pp.149-152
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• 2009

Hydrotalcites are anionic clays that are quite prevalent in nature and their importance is growing more and more because of their very wide range of potential applications and uses. Understanding the structural and compositional changes that occur on the molecular scale during the thermal decomposition of hydrotalcite compounds is essential for the basic prediction and comprehensive understanding of the behavior and technical application of these materials. In this study, several hydrotalcite compounds calcined at different temperatures for applications in a chlorine resistant textile were prepared and 27-Aluminm solid-state nuclear magnetic resonance (NMR) spectroscopy was used as a tool to study their local structure and behavior. The changes in the Al coordination of the hydrotalcite compounds were investigated with one dimensional (1D) solid-state magic angle spinning (MAS) NMR spectroscopy. The two broad resonances arising from the structurally different Al coordinations of these compounds were clearly resolved by two dimensional (2D) triple quantum magic angle spinning (3QMAS) NMR spectroscopy.

• 대한기계학회논문집B
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• 제39권6호
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• pp.527-534
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• 2015

본 연구에서는 직접 탄소 연료전지(DCFC)에서 세 종류의 탄화수소(메탄, 에탄, 프로판) 열분해를 이용하여 다공성 니켈 연료극에 탄소를 직접 생성시켜 연료극과 연료간의 물리적 접촉을 향상시켰다. 전자현미경으로 각각의 탄화수소로부터 생성된 탄소 입자들이 탄소 수가 증가함에 따라 각각 탄소구형체(CS), 탄소나노튜브(CNT), 탄소나노섬유(CNF)임을 확인하였다. 그리고 탄소 샘플들의 결정성을 알아보기 위해 라만 산란 분석을 수행하였고, 탄화수소의 탄소 수가 증가할수록 생성된 탄소의 결정성이 떨어지고 더 유연하였다. 동일한 질량의 탄소로 채워진 연료극의 DCFC 성능을 $700^{\circ}C$ 에서 측정하였고, CNT 와 CNF 가 CS 보다 반응성이 좋아 각각 148%, 210% 높은 전력밀도를 보였다. 이는 결정성이 떨어지는 CNT 와 CNF 의 낮은 전하전달저항에 의한 것으로 사료된다.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.723-732
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• 2022

Cracking ammonia inside solid oxide fuel cell (SOFC) stack is a compact and simple way. To prevent sharp temperature fluctuation and increase cell efficiency, the decomposition reaction should be spread on whole cell area. This leading to a question that, how does anode thickness affect the conversion rate of ammonia and the cell voltage? Since the 0D model of SOFC is useful for system level simulation, how accurate is it to use equilibrium solver for internal ammonia cracking reaction? The 1D model of ammonia fed SOFC was used to simulate the diffusion and reaction of ammonia inside the anode electrode, then the partial pressure of hydrogen and steam at triple phase boundary was used for cell voltage calculation. The result shows that, the ammonia conversion rate increases and reaches saturated value as anode thickness increase, and the saturated thickness is bigger for lower operating temperature. The similar cell voltage between 1D and 0D models can be reached with NH₃ conversion rate above 90%. The 0D model and 1D model of SOFC showed similar conversion rate at temperature over 750℃.