• Title/Summary/Keyword: Trihydroxybenzenes

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An Efficient and Concise Synthesis of Biologically Interesting Pyranochromenes by Ethylenediamine Diacetate-Catalyzed Double Condensation of Substituted Trihydroxybenzenes to α,β-Unsaturated Aldehydes and Application to Natural Product Analoges

  • Lee, Yong-Rok;Li, Xin
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1739-1745
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    • 2007

  • A new methodology for the preparation of pyranochromenes was developed starting from substituted trihydroxybenzenes. This methodology was applied successfully to the total synthesis of biologically interesting compounds, clusiaphenone A, octandrenolone, O-methyloctandrenolone, trans-3''',4'''-dihydro- 3''',4'''-dihydroxy-O-methyloctandrenolone, trans-3'',4''-dihydro-3'',4''-dihydroxy-O-methyloctandrenolone, flemiculosin, laxichalcone, and racemic 3-deoxy-Ms-II.

  • https://doi.org/10.5012/bkcs.2007.28.10.1739 인용 PDF KSCI