• Title/Summary/Keyword: Triflates

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Rhodium-Catalyzed Highly Regioselective C-H Arylation of Imidazo[1,2-a]pyridines with Aryl Halides and Triflates

  • Liu, Yi;He, Lin;Yin, Guoqiang;Wu, Guojie;Cui, Yingde
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2340-2342
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    • 2013
  • A convenient Rh-catalyzed C-H arylation of imidazo[1,2-a]pyridines with a variety of aryl halides or triflates has been reported. This process afforded a range of biaryl compounds in excellent yields and showed high activity and broad scope.

A Systematic Study on Knoevenagel Reaction and Nazarov Cyclization of Less Reactive Carbonyl Compounds Using Rare Earth Triflates and Its Applications

  • Ilangovan, A.;Muralidharan, S.;Maruthamuthu, S.
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.1000-1006
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    • 2011
  • A systematic study of Knoevenagel reaction and Nazarov cyclization was made on variety of less reactive carbonyl compounds such as ${\beta}$-ketoesters, 1,3-diketones and cyclic active methylene compounds using $Yb(OTf)_3$ as the catalyst. Recycling study confirms reusability of the catalyst without much loss of activity.