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http://dx.doi.org/10.5012/jkcs.2011.55.6.1000

A Systematic Study on Knoevenagel Reaction and Nazarov Cyclization of Less Reactive Carbonyl Compounds Using Rare Earth Triflates and Its Applications  

Ilangovan, A. (School of Chemistry, Bharathidasan University)
Muralidharan, S. (School of Chemistry, Bharathidasan University)
Maruthamuthu, S. (Corrosion Protection Division, Central Electro Chemical Research Institute)
Publication Information
Journal of the Korean Chemical Society / v.55, no.6, 2011 , pp. 1000-1006 More about this Journal
Abstract
A systematic study of Knoevenagel reaction and Nazarov cyclization was made on variety of less reactive carbonyl compounds such as ${\beta}$-ketoesters, 1,3-diketones and cyclic active methylene compounds using $Yb(OTf)_3$ as the catalyst. Recycling study confirms reusability of the catalyst without much loss of activity.
Keywords
Knoevenagel Reaction; Nazarov cyclization; Yetterbium triflate; 1,3-diketones; Ethyl acetoacetate;
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