• Journal of the Korean Solar Energy Society
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• v.21 no.2
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• pp.45-54
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• 2001

In this study, the characteristics of optical fibers for the application in photocatalytic system was investigated using the intentionally designed accessories for spectrometer and radiometer to resolve the problems associated with the conventional system such as cost and structural restrictions from artificial lamp usage, to broaden the application fields into underground, and to utilize solar light in the future. To do this two kinds of optical fibers, plastic optical fiber (POF) and quartz optical fiber (QOF) were compared in terms of characteristics related with light transmittance and absorption and reactivity in TCE degradation.

• Proceedings of the Korean Environmental Health Society Conference
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• 2003.06a
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• pp.123-127
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• 2003

This experiment was performed to investigate the characteristics of sonolytic reaction as the basic data for development of the ultrasonic AOP(Advanced Oxidation Process) process from which the refractory organic compounds in aqueous solution which are not readily removed by the existing conventional wastewater treatment processes can be destructed and removed. Trichloroethylene (TCE), benzene, and 2,4-dichlorophenol(DCP) were used as the samples, and their destruction efficiency were measured in terms of experimental parameters of the initial solution concentration, initial solution pH, reaction temperature, acoustic frequencies and intensities. Results showed that the destruction efficiencies of all of the sample materials were above 80% within 120 minutes of sonolytic reaction in all reaction condition. The reaction order of these three compounds was verified as Pseudo first order. From the fore-mentioned results, it can be concluded that the refractory organic compounds could be removed by the ultrasonic irradiation with radicals, such as H$.$and OH$.$causing the high increase of pressure and temperature. Finally, it appears that the new AOP technology using ultrasonic irradiation can be applied to the treatment of refractory substances which are difficult to be decomposed by the conventional methods.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.8 no.1
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• pp.88-94
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• 1998

Korea has been rapidly industrialized during the past 35 years. During this period, Korea has emphasized only production and workers health has been ignored. Workers are most frequently exposed to organic vapors, such as thinners. This study was performed to evaluate worker exposures to organic solvents by size and type of industry. Results are summarized below. Workers were exposed to mixtures of toluene, xylenes, trichloroethylene, n-hexane, acetone, methanol, n-butanol, n-butyl acetate, and MIBK. Considering additive effects of the compounds, exposure indices (EIs) were calculated. It was found that worker exposures to organic solvents were highest in small industries and lowest in large industries. During a day shift, the highest exposure was indicated 3 - 5 p.m. in the afternoon. Workers in small industries had potential exposures exceeding permissible exposure limits for organic solvents. Local exhuast systems were inappropriate and respiratory protective devices were not supplied to the workers in small industries. Neither program for safe use and storage of toxic materials nor program for respirators was found in any of the plants investigated. Based on the results of the study, workers of small scale industries should be considered first in industrial health.

• Journal of Microbiology and Biotechnology
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• v.11 no.5
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• pp.804-811
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• 2001

In many Gram-negative bacteria, autoinducers, such as N-acyl-L-homoserine lactone(acyl-HSL) and its derivative molecules, mediate the cell-density-dependnet expression of certain operons. The current study identified the autoinducers produced by Burkholderia cepacia G4, a trichloroethylene-degrading lagoon isolate, using TLC bioassays with Agrobacterium tumefaciens NT1(pDCI141E33) and Chromobacterium violaceum CVO26, and a GC-MS analysis. The ${R_f}\;and\;{R_t}$ values and mass spectra were compared with those of synthetic compounds. Based on the analyses, it was confirmed that G4 produces N-hexanoyl (C6)-, N-octanoyl (C8)-, N-decanoyl (C10)-, N-dodecanoyl (C12)-HSL, and an unknown active species. The integration of the GC peak areas exhibited a ratio of C8-HSL:C10-HSL:C12-HSL at 3:17:1 with C6-HSL and C10-HSL production at trace and micromolar levels, respectively, in the culture supernatants. Nutants partially defective in producing acyl-HSLs were also partially defective in the biosynthesis of an antibiotic substance. These results indicate that the autoinducer-dependent gene regulation in G4 is dissimilar to the clinical B. cepacia strains isolated from patients with cystic fibrosis.

• Proceedings of the Microbiological Society of Korea Conference
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• 2002.10a
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• pp.27-30
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• 2002

Ralstonia eutrupha JMP134 is a well-known soil bacterium which can metabolite diverse aromatic compounds and xenobiotics, such as phenol, 2,4-dichlorophenoxy acetic acid (2, 4-D), and trichloroethylene (TCE), etc. Phenol is degraded through chromosomally encoded phenol degradation pathway. Phenol is first metabolized into catechol by a multicomponent phenol hydroxylase, which is further metabolized to TCA cycle intermediates via a meta-cleavage pathway. The nucleotide sequences of the genes for the phenol hydroxylase have previously been determined, and found to composed of eight genes phlKLMNOPRX in an operon structure. The phlR, whose gene product is a NtrC-like transcriptional activator, was found to be located at the internal region of the structural genes, which is not the case in most bacteria where the regulatory genes lie near the structural genes. In addition to this regulatory gene, we found other regulatory genes, the phlA and phlR2, downstream of the phlX. These genes were found to be overlapped and hence likely to be co-transcribed. The protein similarity analysis has revealed that the PhlA belongs to the GntR family, which are known to be negative regulators, whereas the PhlR2 shares high homology with the NtrC-type family of transcriptional activators like the PhlR. Disruption of the phlA by insertional mutation has led to the constitutive expression of the activity of phenol hydroxylase in JMP134, indicating that PhlA is a negative regulator. Possible regulatory mechanisms of phenol metabolism in R. eutropha JMP134 has been discussed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.10a
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• pp.89-110
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• 2003

The limitations of conventional soil and groundwater contamination remediation technologies have motivated a search for innovative technologies; particularly in situ technologies that do not require extraction of contaminants from the subsurface. All engineered in situ remediation systems require that the contaminant be mixed with a remedial compound. Horizontal flow treatment wells (HFTWs), an innovative technology that consists of a pair of dual-screened treatment wells, were used at a trichloroethylene (TCE) contaminated site to efficiently achieve this mixing of contaminant and remedial compound in order to effect in situ bioremediation (McCarty et al., 1998). In this paper, the potential of HFTWs to treat chlorinated aliphatic hydrocarbons (CAHs) as well as other soil and groundwater contaminants of concern, such as nitroaromatic compounds (NACs), perchlorate, and methyl-tert-butyl ether (MTBE), is examined. Through a combination of laboratory studies, model analyses, and field evaluations, the effectiveness of this innovative technology to manage these contaminants is investigated.

• Journal of Korean Society of Water and Wastewater
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• v.7 no.2
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• pp.9-23
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• 1993

Emission of hazardous and volatile organic chemicals from solid waste landfill site was become to important issue because of environmental pollution and health risk by such chemicals. Laboratory batch and continuous experiments were conducted respectively to elucidate isothermal sorption behaviors and transport phenomena(by gas through unsaturated solid waste layer) in wet solid waste-gas system. Source separated and size reduced refuse(bulky waste) and incinerated ash were used after controlling water content, and trichloroethylene(TCE) was chosen among many such chemicals because of it's generality among those man-created pollutants. Isothermal TCE sorption equilibria wet solid waste-gas system can be described in linear equation and partition coefficient in this system can be estimated approximately by the simple equation derived from schematic structure of the system. Transport equation modified by instantaneous equilibrium sorption fraction and kinetic sorption rate(overall mass transfer capacity coefficient) simulated well the column experiment results.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.114-116
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• 2005

Natural attenuation has been actively studied and often selected as final clean-up process in remediation of contaminated ground-water and soil for the last decade. Accordingly, understanding of natural processes affecting the fate and transport of contaminants in the subsurface becomes important for a success of implementation of the natural remediation strategy, Contaminant advection and diffusion processes in the unsaturated zone are naturally related to environmental changes in the atmosphere. The atmospheric pressure changes affecting the transport of contaminants in the subsurface are investigated in this study. Moisture content, trichloroethylene (TCE) concentration, temperature, and pressure variations in the subsurface were measured for the July, August, November, and December 2001 at Picatinny Arsenal, New Jersey. These data were used for a one-phase flow and one-component transport model in simulating the soil-gas flow and accordingly the TCE transport in the subsurface in accordance with the atmosphere pressure variations at the surface. The soil-gas velocities during the sampling periods varied with a magnitude of $10^{-6}\;to\;10^{-7}\;m\;s^{-1}$ at land surface. The TCE advection fluxes at land surface were several orders of magnitude smaller than the TCE diffusion fluxes. A sensitivy analysis indicated that advection fluxes were more sensitive to changes in geo-environmental conditions compared to diffusion fluxes. Of all the parameters investigated in this study, moisture content has the most significant effect on TCE advection and diffusion fluxes.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.53-56
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• 2005

A Laboratory study was conducted to evaluate the kinetics of oxidation of trichloroethylene (TCE) in groundwater by potassium permanganate $(KMnO_4)$, Consumption of permanganate by TCE and aquifer materials was also evaluated to obtain an appropriate injection rate of $KMnO_4$. TCE degradation by $KMnO_4$ in the absence of aquifer material showed effective with pseudo-first order rate constant, $k_{obs}=1.8110^{-3}\;s^{-1}\;at\;KMnO_4=500mg/L$. TCE oxidation by $KMnO_4$ was found to be second order reaction and the rate constant, $k=0.65{\pm}0.08\;M^{-1}s^{-1}$, was independent of pH changes. $KMnO_4$ consumption rate by groundwater sampled from field site was not significant, indicating that groundwater containing negligible amount of dissolved organic matter does not have any influence on the $KMnO_4$ degradation. Meanwhile, aquifer materials from field site were actively reacted with permanganate, resulting in the significant consumption of $KMnO_4$. It might be attributed to the existence of metal oxides in aquifer materials, Based on the rate constants obtained from this study, appropriate injection rate of permanganate and TCE removal rate in groundwater could be estimated.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.103-111
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• 1999

This study is on the mathematical modeling and its verification of the retardation phenomenon of gas migration in an unsaturated zone of very little moisture content The adsorption of VOCs onto the surface of the dry medium was taken into account, which has not been usually considered in the conventional models. The trichloroethylene(TCE) gas migration predicted from the mathematical model developed in this study fits the experimental results obtained from a dry glass-bead column and a dry silica sand column very well The model developed in this study gave much better prediction than did a coventional model.