• Journal of the Microelectronics and Packaging Society
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• v.13 no.1 s.38
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• pp.51-55
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• 2006

The green emitting high performance OLEDs using the $Alq_3$-C545T fluorescent system have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, green color emission layer was deposited using $Alq_3$ as a host material and C-545T[10-(2-benzothiazolyl)-1,1,7,7- tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one] as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/$Alq_3$:C545T/$Alq_3$/LiF/Al were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Green OLEDs fabricated in our experiments showed the color coordinate of CIE(0.29, 0.65) and the maximum power efficiency of 7.3 lm/W at 12 V with the peak emission wavelength of 521 nm.

• Journal of the Korean Electrochemical Society
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• v.11 no.1
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• pp.42-46
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• 2008

Even though fuel cell have high efficiency when pure hydrogen from gas tank is used as a fuel source, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, $CH_4$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of the electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. This study is aimed at investigating the effect of carbon dioxide on fuel cell performance. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run(10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography(GC).

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.9 no.2
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• pp.86-96
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• 1997

In order to investigate the formation of a shallow water front and its relation to water quality distributions, oceanographic measurements were made, and the numerical computations of the Simpson-Hunter stratification parameter log(H/U$^3$) were performed. It is shown from satellite image and hydrographic data that the shallow water front is formed near the northern Kaduk channel, and the stratification parameter log(H/U$^3$) near the front is in a range of 2.0-2.5. Measured COD (Chemical Oxygen Demand) concentrations in offshore region of the front and in the western part of the bay are below 2.0 mg/1. whereas the concentrations in Masan Bay located in the northern inside of the frontal zone are high as 3.0-5.5 mg/1. COD concentrations decrease gradually from Masan Bay toward the offshore due to the dilution by strong water mixing. Anoxic and hypoxic water masses at the bottom layer in summcr occur in the western part of Chinhae Bay and in Masan Bay, and DO (Dissolved Oxygen) concentrations become low with increasing the stratification parameter. DO concentrations outside the front are more than about 4.0 mg/1, whereas the concentrations inside the front are low. The shallow water front plays a significant role for material transport from coastal area to oceanic area, and the frontal region seems to be important physical and chemical boundaries.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.17-17
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• 2011

As a method of countermeasure to bed degradation and armoring phenomena of bed material in the downstream area of dam reservoirs, sediment augmentation (replenished sediment) has been carried out in many Japanese rivers. In general, bed of the replenished sediment site is composed of rocks, because the site is located in the downstream area of the dams and sediment supply is very small. Bed deformation process has been researched by many researchers. As a method of countermeasure to bed degradation and armoring phenomena of bed material in the downstream area of dam reservoirs, sediment augmentation (replenished sediment) has been carried out in many Japanese rivers. In general, bed of the replenished sediment site is composed of rocks, because the site is located in the downstream area of the dams and sediment supply is very small. Bed deformation process has been researched by many researchers. However, most of them can treat movable bed only and cannot be applied to the bed deformation process of sediment on rocks. If the friction angle between the sediment and the bed surface is assumed to be the same as the friction angle between the sediment and the sediment, sediment transport rate must be smaller without sediment deposition layer on the rocks. As a result, the reproduced bed geometry is affected very well. In this study, non-equilibrium transport process of non-cohesive sediment on rigid bed is introduced into the horizontal two dimensional bed deformation model and the model is applied to the erosion process of replenished sediment on rock in the Nakagawa, Japan. Here, the Japanese largest scale sediment augmentation has been performed in the Nakagawa. The results show that the amounts of the eroded sediment and the remained sediment reproduced by the developed numerical model are $56300m^3$ and $26800m^3$, respectively. On the other hand, the amounts of the eroded sediment and the remained sediment measured in the field after the floods are $56600m^3$ and $26500m^3$, respectively. The difference between the model and field data is very small. Furthermore, the bed geometry of the replenished sediment after the floods reproduced by the developed model has a good agreement with the measured bed geometry after the floods. These results indicate that the developed model is able to simulate the erosion process of replenished sediment on rocks very well. Furthermore, the erosion speed of the replenished sediment during the decreasing process of the water discharge is faster than that during the increasing process of the water discharge. The replenished sediment is eroded well, when the top of the replenished sediment is covered by the water. In general, water surface level is kept to be high during the decreasing process of the discharge during floods, because water surface level at the downstream end is high. Hence, it is considered that the high water surface level during the decreasing process of the water discharge affects on the fast erosion of the replenished sediment.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.864-870
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• 2018

The effect of lower bed height on the collapse velocity was investigated for a two-stage bubbling fluidizedbed (0.1 m in diameter, 1.2 m high) connected with a standpipe (0.025 m in diameter) for solid transport. Air was used as fluidizing gas and mixture of coarse (< $1000{\mu}m$ in diameter and $3625kg/m^3$ in apparent density) and fine (< $147{\mu}m$ in diameter and $4079kg/m^3$ in apparent density) particles as solid particles. Mixing ratio of fine particles, height of the lower bed and the distributor of the upper bed were considered as experimental variables. The collapse velocity increased with static height of the lower bed. However, the effect decreased as the mixing ratio of fine particles increased. The effect seemed to be attributed to the increase in height of the dense layer of coarse particles that prevented the gas from flowing into the standpipe, not in pressure drop for the standpipe, as the bed height increased. The collapse velocity decreased a little as the pressure drop of the distributor of the upper bed increased. An improved correlation was proposed for predicting the collapse velocity.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.80-81
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• 2012

Recently, one of the critical issues in the etching processes of the nanoscale devices is to achieve ultra-high aspect ratio contact (UHARC) profile without anomalous behaviors such as sidewall bowing, and twisting profile. To achieve this goal, the fluorocarbon plasmas with major advantage of the sidewall passivation have been used commonly with numerous additives to obtain the ideal etch profiles. However, they still suffer from formidable challenges such as tight limits of sidewall bowing and controlling the randomly distorted features in nanoscale etching profile. Furthermore, the absence of the available plasma simulation tools has made it difficult to develop revolutionary technologies to overcome these process limitations, including novel plasma chemistries, and plasma sources. As an effort to address these issues, we performed a fluorocarbon surface kinetic modeling based on the experimental plasma diagnostic data for silicon dioxide etching process under inductively coupled C4F6/Ar/O2 plasmas. For this work, the SiO2 etch rates were investigated with bulk plasma diagnostics tools such as Langmuir probe, cutoff probe and Quadruple Mass Spectrometer (QMS). The surface chemistries of the etched samples were measured by X-ray Photoelectron Spectrometer. To measure plasma parameters, the self-cleaned RF Langmuir probe was used for polymer deposition environment on the probe tip and double-checked by the cutoff probe which was known to be a precise plasma diagnostic tool for the electron density measurement. In addition, neutral and ion fluxes from bulk plasma were monitored with appearance methods using QMS signal. Based on these experimental data, we proposed a phenomenological, and realistic two-layer surface reaction model of SiO2 etch process under the overlying polymer passivation layer, considering material balance of deposition and etching through steady-state fluorocarbon layer. The predicted surface reaction modeling results showed good agreement with the experimental data. With the above studies of plasma surface reaction, we have developed a 3D topography simulator using the multi-layer level set algorithm and new memory saving technique, which is suitable in 3D UHARC etch simulation. Ballistic transports of neutral and ion species inside feature profile was considered by deterministic and Monte Carlo methods, respectively. In case of ultra-high aspect ratio contact hole etching, it is already well-known that the huge computational burden is required for realistic consideration of these ballistic transports. To address this issue, the related computational codes were efficiently parallelized for GPU (Graphic Processing Unit) computing, so that the total computation time could be improved more than few hundred times compared to the serial version. Finally, the 3D topography simulator was integrated with ballistic transport module and etch reaction model. Realistic etch-profile simulations with consideration of the sidewall polymer passivation layer were demonstrated.

• Horticultural Science & Technology
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• v.32 no.1
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• pp.33-40
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• 2014

This study was carried out to understand the physiological characteristics of early-matured 'Hanareum' (Pyrus pyrifolia Nakai) pears through anatomical structure and fruit characteristics and also the changes according to gibberellin (GA) treatment. The pericarp at full bloom consists of outer epidermis, hypodermis, parenchyma cell, and inner epidermis from the exterior and five types of vascular bundle tissues. Cork cell layer was formed at 70 days after full bloom (DAFB) in non-treated fruits and formed at 60 DAFB in GA treated fruits. Cell division period was from full bloom (FB) to 40 DAFB and then fruit enlargement was accomplished by the cell growth. Comparison of the fruit enlargement and fruit structure development by GA treatment or non-treatment showed that cell division of 'Hanaerum' fruits did not affect the GA treatment but fruit enlargement was affected cell growth. Fruit stalk of GA treatment fruits was larger than non-treated fruits from 40 DAFB which correspond to the period of the stop of cell division and 'Hanareum' was regarded GA treatment expedite of vascular bundle tissue growth and relatively increased nutrient transport to fruit. In addition to, average fruit quality between the non-treatment and GA treatment showed that fruit weight was higher in fruits treated by GA but firmness was lower and probably was effected fruit storing in 'Hanareum' pear.

• The Journal of the Acoustical Society of Korea
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• v.32 no.1
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• pp.14-21
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• 2013

The erosion, suspension, and transport of sediment frequently occur in the coastal waters and estuarine. These processes often generate the so-called fluid mud layer, which is defined as a high-concentration aqueous suspension of fine grained sediment (> 10 g/l), consisting mainly of silt and clay-size particles. Therefore the high-resolution ultrasound is mostly used to detect or monitor the fluid mud layer. Because the sound attenuation tends to increase rapidly with the suspended sediment concentration, it is necessary to consider the accurate attenuation correction to estimate the backscattering strengths from the suspended sediment layers. In this paper, the volume backscattering strengths with various suspended sediment concentrations were measured using 5-MHz ultrasound signal in a small-scale water tank. The sound attenuation due to the viscosity and scattering from suspended sediment particles was predicted by the Richard's model and applied to the sonar equation to estimate the volume backscattering strengths from the suspended sediment concentrations. For the case that the additional attenuation was not considered, the volume backscattering strengths increased to the concentration of 20 g/l, and over this point, the backscattering strengths were roughly constant. However, for the case that the attenuation due to the suspended sediment concentration was considered, the backscattering strengths increased with the concentration.

• Fire Science and Engineering
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• v.32 no.2
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• pp.7-16
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• 2018

In this study, the previous design fire curve for fire simulation was modified and re-suggested. Numerical simulations with the FDS and CFAST were performed for the n-heptane and n-octane pool fires in the ISO 9705 compartment to evaluate the prediction performances of the previous 1-stage and modified 2-stage design fire curves. The numerical results were compared with the experimental temperature and concentrations of $O_2$ and $CO_2$. The FDS and CFAST simulations with the 2-stage design fire curve showed better prediction performance for the variation of temperature and major species concentration than the simulations with 1-stage design fire curve. Especially, the simulations with the 2-stage design fire curve agreed with the experimental temperature more reasonably than the results with the 1-stage design fire curve. The FDS and CFAST simulations showed good prediction performance for the temperature in the upper layer of compartment and the results with the FDS and CFAST were similar to each other. However, the FDS and CFAST showed poor and different prediction performance for the temperature in the lower layer of compartment.

• Journal of Korea Water Resources Association
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• v.43 no.10
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• pp.883-891
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• 2010

More recently, there have been significant changes in the forms of channels due to runoff characteristics driven by climate changes and other alterations in basin/channel environments. Particularly, increasing local deposition in major channels is being observed nationwide. Of such phenomena, it is noteworthy that flood-plains show unidirectional growth and lowering of channels within compound channels in the form of a high-flow plain. These changes are supposed to affect management of the river ecology as well as flood control. In this study, the research on channels in Korea confirmed that the phenomenon of local deposition in those channels is actually taking place, rendering a problem to be urgently addressed. Previous studies on bed changes have been focused on low channels based on bed materials distributed over the channels. However, this research has proved that surface-layer deposition of a high-flow plain is closely related with changes in the conditions of ground surfaces and, ultimately, affects the bed of the entire channel as well. According to the intensive research on the condition of the high-flow plain of the mouth of the Han River, the silt deposited in the high-flow plain was the main cause of settlement/growth of vegetation. And this leads to landforming along with woods-forming, disturbing flood control as well as the normal river ecology.