• 제목/요약/키워드: Transport Phenomena

검색결과 406건 처리시간 0.031초

연료전지 촉매층 내 촉매활성도에 대한 탄소지지 백금 촉매의 기하학적 비등방성 효과에 관한 연구 (Geometrically Inhomogeneous Random Configuration Effects of Pt/C Catalysts on Catalyst Utilization in PEM Fuel Cells)

  • 신승호;김아름;정혜미;엄석기
    • 한국정밀공학회지
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    • 제31권10호
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    • pp.955-965
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    • 2014
  • Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

Poly(2-Hydroxyethyl Methacrylate) 수화겔 막에 대한 알카리 금속 염화물의 수송현상 (\Transport Phenomena of Alkali Metal Chlorides theough Poly(2-Hydroxyethyl Methacrylate) Hydrogel Membrane)

  • 성용길;이춘기;전무식
    • 대한의용생체공학회:의공학회지
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    • 제8권2호
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    • pp.123-134
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    • 1987
  • The transport phenomena of alkali metal chlorides through poly(2 hydroxyethyl methacrylate) hydrogel membrane have been studied using electrodialysis. The hydrogel membranes were prepared by the polymerization of 2-hydroxvethyl methacrylate in the presence of 45%(V/V) H2O and ethyleneglycodimethacrylate. The initiator used in the polymerization was azobismethylisobutyrate (AMIB) prepared from azobisiobtyronitrile (AIBN) using Mortimer method. The permeability of alkali metal chlorides such LiCl, NaCl and KCI at 50 voltage was obtained. The permeability of NaCl was also observed at 30, 40, 50, and 60 voltages respectively. The concentration of solutes permeated through the membrane was measurer by flame photometry. The experimental results have been discussed with the comparison of apparent solute molecular size, the self-diffusion coefficient of solutes, the transport number of cations in aqueous solution. These indic aloes that poly(2 hydroxyethyl methacrylate) hydrogel membrane shows a specific selectivity for sodium ion.

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홍수시 한강 하류부의 하상변동에 관한 연구 (A Study of River-Bed Variation from Goan to Indogyo due to Flood in Han River)

  • 박정응;김경수
    • 물과 미래
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    • 제24권2호
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    • pp.109-119
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    • 1991
  • 댐 건설로 인하여 상류로 부터 토사공급이 중단 상태인 하천에 있어서의 하상변동이나 유사 이송 현상은 상당히 복잡한 물리적 현상이기 때문에 이에 관련된 수치모형의 설정이 필요하다. 본 연구에서는 하상변동에 대한 수치해석방법으로 정류개념보다는 점변부정류 개념을 적용하였으며, 홍수기록과 하상변동에 관한 자료가 비교적 풍부한 한강하류부에 이 수치모형을 적용하여 유량변화(홍수기록, 특정계획유량) 및 하상고 변동(기존, 계획)을 모의 하였다.

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Novel adsorption model of filtration process in polycarbonate track-etched membrane: Comparative study

  • Adda, Asma;Hanini, Salah;Abbas, Mohamed;Sediri, Meriem
    • Environmental Engineering Research
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    • 제25권4호
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    • pp.479-487
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    • 2020
  • Current assumptions are used in the formulation of pseudo-first (PFO) and second-order (PSO) models to describe the kinetic data of filtration based on ideal operating conditions. This paper presents a new model developed with pseudo nth order and based on real assumption. A comparison was performed between PFO, PSO and the new model to highlight their performance and the optimisation of the pseudo-order equation, using MATLAB software. Adsorption characteristic of bovine serum albumin adsorption on the track-etched membrane are used as a medium based on protein filtration data were extracted from the literature for different concentrations to demonstrate the comparison between PFO/PSO and the new model. The pseudo first and second-order kinetic models were applied to test the experimental data and they did not provide reasonable values. The results show that the predicted values are consistent with experimental values giving a good correlation coefficient R2 = 0.997 and a minimum root mean squared error RMSE = 0.0171. Indeed, the experimental results follow the new model and the optimal pseudo equation order n = 1.115, the most suitable curves for the new model. As a result, we used different experimental adsorption data from the literature to examine and check the applicability and validity of the model.

A CLOSED-FORM SOLUTION FOR TURBULENT WAVE BOUNDARY LAYERS

  • Larson, Magnus
    • 한국해안해양공학회:학술대회논문집
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    • 한국해안해양공학회 1995년도 정기학술강연회 발표논문 초록집
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    • pp.66-70
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    • 1995
  • The oscillatory boundary layer that develops when surface waves propagate over the sea bottom affects many flow-pendent phenomena in the coastal zone. Examples of such phenomena are wave energy dissipation due to bottom friction and the initiation and transport of sediment (Grant and Madsen 1986). In nature the boundary layer under waves will almost always be turbulent (Nielsen 1992). (omitted)

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A new theoretical model for the dynamical analysis of Nano-Bio-Structures

  • Di Sia, Paolo
    • Advances in nano research
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    • 제1권1호
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    • pp.29-34
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    • 2013
  • The conversion of mechanical energy into electrical energy at nanoscale using piezoelectric nanowire arrays has been in detail shown by deflection of nanowires. Recently it has performed an analytical model, both at classical and at quantum level, for describing the most important quantities concerning transport phenomena; the model predicts interesting peculiarities, as high initial charge diffusion in nanodevices constituting by nanowires and permits also in particular to deduce interesting informations about the devices sensitivity, focusing on the correlation between sensitivity and high initial diffusivity of these materials at nanometric level.

회야강 하구 및 진하해수욕장의 지형변화에 관한 연구 (A Study on the Topography Change of Hyeya River and Jinha Beach)

  • 민병형;민일규;이동수
    • 한국해양공학회지
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    • 제8권1호
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    • pp.84-95
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    • 1994
  • In recent years Jin-Beach and Hyeya River mouth have experienced severe erosion phenomena. The cause of erosion is examined using a 3-dimensional nunumerical sediment transport model. The model is composed of three components : wave model, wave-induced current model and 3-dimensional sediment transport model. In the wave analysis component we consider refraction, diffraction and reflection based on Maruyama and Kajima method. For the wave-induced current model we use depth-integrated continuty equation and momentum equations. For the 3-dimensional sediment transport model we consider bed load and suspended load simutaneously. Model results obtained for Jin-ha Beach and Hyeya River mouth agreed well with experimental results.

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Analysis of Electron Transport Coefficients in Binary Mixtures of TEOS Gas with Kr, Xe, He and Ne Gases for Using in Plasma Assisted Thin-film Deposition

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • 제11권2호
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    • pp.455-462
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    • 2016
  • The electron transport coefficients in not only pure atoms and molecules but also in the binary gas mixtures are necessary, especially on understanding quantitatively plasma phenomena and ionized gases. Electron transport coefficients (electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient) in binary mixtures of TEOS gas with buffer gases such as Kr, Xe, He, and Ne gases, therefore, was analyzed and calculated by a two-term approximation of the Boltzmann equation in the E/N range (ratio of the electric field E to the neutral number density N) of 0.1 - 1000 Td (1 Td = 10−17 V.cm2). These binary gas mixtures can be considered to use as the silicon sources in many industrial applications depending on mixture ratio and particular application of gas, especially on plasma assisted thin-film deposition.