• Title/Summary/Keyword: Transport Phenomena

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Geometrically Inhomogeneous Random Configuration Effects of Pt/C Catalysts on Catalyst Utilization in PEM Fuel Cells (연료전지 촉매층 내 촉매활성도에 대한 탄소지지 백금 촉매의 기하학적 비등방성 효과에 관한 연구)

  • Shin, Seungho;Kim, Ah-Reum;Jung, Hye-Mi;Um, Sukkee
    • Journal of the Korean Society for Precision Engineering
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    • v.31 no.10
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    • pp.955-965
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    • 2014
  • Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

\Transport Phenomena of Alkali Metal Chlorides theough Poly(2-Hydroxyethyl Methacrylate) Hydrogel Membrane (Poly(2-Hydroxyethyl Methacrylate) 수화겔 막에 대한 알카리 금속 염화물의 수송현상)

  • Seong, Yong-Gil;Lee, Chun-Gi;Jeon, Mu-Sik
    • Journal of Biomedical Engineering Research
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    • v.8 no.2
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    • pp.123-134
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    • 1987
  • The transport phenomena of alkali metal chlorides through poly(2 hydroxyethyl methacrylate) hydrogel membrane have been studied using electrodialysis. The hydrogel membranes were prepared by the polymerization of 2-hydroxvethyl methacrylate in the presence of 45%(V/V) H2O and ethyleneglycodimethacrylate. The initiator used in the polymerization was azobismethylisobutyrate (AMIB) prepared from azobisiobtyronitrile (AIBN) using Mortimer method. The permeability of alkali metal chlorides such LiCl, NaCl and KCI at 50 voltage was obtained. The permeability of NaCl was also observed at 30, 40, 50, and 60 voltages respectively. The concentration of solutes permeated through the membrane was measurer by flame photometry. The experimental results have been discussed with the comparison of apparent solute molecular size, the self-diffusion coefficient of solutes, the transport number of cations in aqueous solution. These indic aloes that poly(2 hydroxyethyl methacrylate) hydrogel membrane shows a specific selectivity for sodium ion.

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A Study of River-Bed Variation from Goan to Indogyo due to Flood in Han River (홍수시 한강 하류부의 하상변동에 관한 연구)

  • 박정응;김경수
    • Water for future
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    • v.24 no.2
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    • pp.109-119
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    • 1991
  • The river-bed variation and the sediment transport in an alluvial stream are very complicated physical phenomena, especially in a stream where the dam construction prevents the supply of earth and sand from upper tributaries Therefore, the mathematical modeling is needed to establish. The purpose of this study is to apply river-bed variation to the Han River downstream by the conception of gradually varied unsteady flow instead of that of steady flow in order to decrease errors. For the variation and forecast of river-bed, the numerical analysis has been made in this study by way of discharge variation and river-bed variation. In conclusion, the numerical analysis shows that river-bed variation, sediment transport , and their forecast have similarity to natural phenomena and that river-bed variation is greatly affected in sediment transport by discharge variation and retention time(duration). Therefore, the errors of numerical analysis can be reduced by the application of flood data instead of continuous discharge data.

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Novel adsorption model of filtration process in polycarbonate track-etched membrane: Comparative study

  • Adda, Asma;Hanini, Salah;Abbas, Mohamed;Sediri, Meriem
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.479-487
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    • 2020
  • Current assumptions are used in the formulation of pseudo-first (PFO) and second-order (PSO) models to describe the kinetic data of filtration based on ideal operating conditions. This paper presents a new model developed with pseudo nth order and based on real assumption. A comparison was performed between PFO, PSO and the new model to highlight their performance and the optimisation of the pseudo-order equation, using MATLAB software. Adsorption characteristic of bovine serum albumin adsorption on the track-etched membrane are used as a medium based on protein filtration data were extracted from the literature for different concentrations to demonstrate the comparison between PFO/PSO and the new model. The pseudo first and second-order kinetic models were applied to test the experimental data and they did not provide reasonable values. The results show that the predicted values are consistent with experimental values giving a good correlation coefficient R2 = 0.997 and a minimum root mean squared error RMSE = 0.0171. Indeed, the experimental results follow the new model and the optimal pseudo equation order n = 1.115, the most suitable curves for the new model. As a result, we used different experimental adsorption data from the literature to examine and check the applicability and validity of the model.

A CLOSED-FORM SOLUTION FOR TURBULENT WAVE BOUNDARY LAYERS

  • Larson, Magnus
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 1995.10a
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    • pp.66-70
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    • 1995
  • The oscillatory boundary layer that develops when surface waves propagate over the sea bottom affects many flow-pendent phenomena in the coastal zone. Examples of such phenomena are wave energy dissipation due to bottom friction and the initiation and transport of sediment (Grant and Madsen 1986). In nature the boundary layer under waves will almost always be turbulent (Nielsen 1992). (omitted)

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A new theoretical model for the dynamical analysis of Nano-Bio-Structures

  • Di Sia, Paolo
    • Advances in nano research
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    • v.1 no.1
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    • pp.29-34
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    • 2013
  • The conversion of mechanical energy into electrical energy at nanoscale using piezoelectric nanowire arrays has been in detail shown by deflection of nanowires. Recently it has performed an analytical model, both at classical and at quantum level, for describing the most important quantities concerning transport phenomena; the model predicts interesting peculiarities, as high initial charge diffusion in nanodevices constituting by nanowires and permits also in particular to deduce interesting informations about the devices sensitivity, focusing on the correlation between sensitivity and high initial diffusivity of these materials at nanometric level.

A Study on the Topography Change of Hyeya River and Jinha Beach (회야강 하구 및 진하해수욕장의 지형변화에 관한 연구)

  • 민병형;민일규;이동수
    • Journal of Ocean Engineering and Technology
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    • v.8 no.1
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    • pp.84-95
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    • 1994
  • In recent years Jin-Beach and Hyeya River mouth have experienced severe erosion phenomena. The cause of erosion is examined using a 3-dimensional nunumerical sediment transport model. The model is composed of three components : wave model, wave-induced current model and 3-dimensional sediment transport model. In the wave analysis component we consider refraction, diffraction and reflection based on Maruyama and Kajima method. For the wave-induced current model we use depth-integrated continuty equation and momentum equations. For the 3-dimensional sediment transport model we consider bed load and suspended load simutaneously. Model results obtained for Jin-ha Beach and Hyeya River mouth agreed well with experimental results.

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Analysis of Electron Transport Coefficients in Binary Mixtures of TEOS Gas with Kr, Xe, He and Ne Gases for Using in Plasma Assisted Thin-film Deposition

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • v.11 no.2
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    • pp.455-462
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    • 2016
  • The electron transport coefficients in not only pure atoms and molecules but also in the binary gas mixtures are necessary, especially on understanding quantitatively plasma phenomena and ionized gases. Electron transport coefficients (electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient) in binary mixtures of TEOS gas with buffer gases such as Kr, Xe, He, and Ne gases, therefore, was analyzed and calculated by a two-term approximation of the Boltzmann equation in the E/N range (ratio of the electric field E to the neutral number density N) of 0.1 - 1000 Td (1 Td = 10−17 V.cm2). These binary gas mixtures can be considered to use as the silicon sources in many industrial applications depending on mixture ratio and particular application of gas, especially on plasma assisted thin-film deposition.