• Title/Summary/Keyword: Transport Mechanism

Search Result 895, Processing Time 0.029 seconds

A Study on Corrosion and Passivation of Cobalt (금속 코발트의 부식과 부동화에 관한 연구)

  • Jung Kyoon Chon;Woon Kie Paik
    • Journal of the Korean Chemical Society
    • /
    • v.18 no.6
    • /
    • pp.391-399
    • /
    • 1974
  • Corrosion and passivation of metallic cobalt was studied by means of electrochemical experiments including potentiostatic and galvanostatic measurements and cyclic voltammograms. The mechanisms of active dissolution and passivation of cobalt at the metal/borate buffer solution interface are deduced from the Tafel slope, pH dependence of the Flade potential, and dissolution kinetic data. Hydroxyl group adsorbed on cobalt surface seems to participate in surface oxidation and formation of the passive layer. The growth kinetic data as measured by the current density suggests a mechanism in which the growth of the passive layer is determined by field-assisted transport of ions through the layer. Thickness of the passive layer was estimated by coulometry to be about 10${\AA}$ at the lowest passive potential and to grow gradually with anodic potential to about 20${\AA}$.

  • PDF

Serum Folate Levels of Maternal-Umbilical Cord Blood and Pregnancy Outcomes (임신말 모체 및 제대 혈청의 엽산 농도와 임심결과)

  • 안홍석;김지선;이금주;김영태
    • Journal of Nutrition and Health
    • /
    • v.33 no.8
    • /
    • pp.840-847
    • /
    • 2000
  • This study was out to evaluate the folate nutritional status of Korean pregnant women and to investigate the relationship between serum folate levels of maternal-umbilical cord blood and pregnancy outcomes. Folate intakes of the pregnants was estimated by dietary folate intakes obtained from semiquantitative frequency questionnaire and supplementary folate intakes. The serum folate levels in both maternal blood and umbilical cord of 29 pregnant women at delivery and 13 nonpregnant controls were measured by redioimmunoassay. The total folate intakes(dietary and supplementary)of the pregnant women was 465. 4$\mu\textrm{g}$/d which was 93% of the Korean RDA for folate. Maternal mean serum folate levels of the pregnants was 6.1$\mu\textrm{g}$/ml, significantly lower than that of nonpregnant women(8.9ng/ml). Mean serumfolate level of umbilical cord blood was 14.2ng/ml, which was 2.3 folds higher than that of maternal blood. This finding indicates that the uptake of folate in the fetus may be due to an active placental transport mechanism. Maternal serum folate level correlated positively with that of umbilical cord blood, showing that folate concentration of umbilical cord blood is affected by maternal status. There was no significant correlation between the serum folate levels in maternal-umbilical cord blood and the pregnancy outcomes.(Korean J Nutrition 33(8) : 840-847, 2000)

  • PDF

The role of large-scale structures in mixing layers (혼합층에서의 큰-크기구조의 역할)

  • Seo, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.22 no.3
    • /
    • pp.316-325
    • /
    • 1998
  • The objective of this study is to investigate the role of large-scale coherent structures in a spatially developing plane mixing layers. To achieve this, we have to look into the mutual interactions between three-dimensional large-scale coherent structures and the mean flow. Our attention will be focused on the energy exchange mechanism between the various modes, and the effects of the nonlinear evolution of the phases of the interacting modes. Linear stability of the three-dimensional viscous shear layer is formulated and solved as the basis for the solution of the nonlinear formulation based on the energy method. The importance of the initial conditions that may affect the evolution of the flow has been examined. It has been numerically calculated the nonlinear effects arising from the interactions among the three-dimensional large-scale coherent structures in a spatially developing plane mixing layers. The results of this study provide useful parametric information for the control of shear layer in practical applications in the mixing and transport augmentation.

Dielectric Properties depending on Frequency in Organic Light-emitting Diodes using $Alq_3$ (Alq3를 이용한 유기 발광 소자의 주파수에 변화에 따른 유전 특성)

  • Oh, Y.C.;Lee, D.K.;Chung, D.H.;Lee, H.S.;Park, G.H.;Kim, T.W.;Lee, J.U.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.11a
    • /
    • pp.293-294
    • /
    • 2005
  • We have investigated dielectric properties depending on frequency in organic light -emitting diodes using 8-hydroxyquinoline aluminum ($Alq_3$) as an electron transport and emissive material. We analyzed the dielectric properties of organic light-emitting diodes using impedance of characteristics. impedance characteristics was measured complex impedance Z and phase $\Theta$ in the frequency range of 40 Hz to $10^8$ Hz. We obtained complex electrical conductivity, dielectric constant, and loss tangent (tan$\delta$) of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

  • PDF

Countermeasures for the Siltation in Small Fishery Harbors (소규모 어항의 항내매몰 방지대책 검토)

  • 김규한
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.13 no.2
    • /
    • pp.169-176
    • /
    • 2001
  • The sediment at the majority of fishery harbors located on the east coast of Korea are affccted by the waves and wave-induced currents as the main external force. And the surroundings of the harbors are composed of sandy beaches. Because many harbors are small and their entrances are located in the wave¬breaking zone, they suffer severe siltation and topographical changes. In order to solve the problems, we have to understand the mechanism through estimations and accurate reproduction of the harbor siltation phenomenon. We suggest economically substantial countermeasures for harbor siltation in the small fishery harbors and investigate the preventive effects using a numerical simulation technique.

  • PDF

Study of Characteristics of Corona Discharge Plasma in a Wire-Cylinder Type Reactor (Wire-Cylinder형 반응로에서의 코로나 방전 플라스마의 특성 연구)

  • 박승자;박인호;고욱희
    • Journal of the Korean Vacuum Society
    • /
    • v.13 no.3
    • /
    • pp.132-138
    • /
    • 2004
  • We used the self-consistent one-dimensional model applied to FCT algorithm and FEM method in a wire-cylinder type reactor to study the characteristics of corona discharge plasma in air at the atmospheric pressure. At the pulsed do voltage and do voltage, we studied the changes of the characteristic of plasma by computing electron density profile according to the changes of voltage and the size of reactor. The changes of active radius from this result are compared with the data of Peek's. The numerical simulation results for a corona discharge plasma explain the physical mechanism of the discharge process and could be used to obtain the optimized parameters for designing the plasma reactor for pollution abatement.

A Seasonal Circulation in the East China Sea and the Yellow Sea and its Possible Cause

  • Oh, Kyung-Hee;Pang, Ig-Chan
    • Journal of the korean society of oceanography
    • /
    • v.35 no.4
    • /
    • pp.161-169
    • /
    • 2000
  • A seasonal circulation in the East China Sea and the Yellow Sea and its possible cause have been studied with CSK data during 1965-1989. Water mass distributions are clear in winter, but not in summer because the upper layer waters are quite influenced by atmosphere. To solve the problem, a water mass analysis by mixing ratio is used for the lower layer waters. The results show that the distribution of Tsushima Warm Current Water expands to the Yellow Sea in winter and retreats to the East China Sea in summer. It means that there is a very slow seasonal circulation between the East China Sea and the Yellow Sea: Tsushima Warm Current Water flows into the Yellow Sea in winter and coastal water flows out of the Yellow Sea in summer. By the circulation, the front between Tsushima Warm Current Water and coastal water moves toward the shelf break in summer so that the flow is faster in the deeper region. The process eventually makes the transport in the Korea Strait increase. The Kuroshio does not seem to influence the process. A possible mechanism of the process is the seasonal change of sea surface slope due to different local effects of surface heating and diluting between the East China Sea and the Yellow Sea.

  • PDF

Mechanism for Bank Erosion and Local Scouring in Estuary of the Hangang River

  • Lee, Samhee;Han, Hyeongjun;Choo, Jeongho
    • Journal of Wetlands Research
    • /
    • v.16 no.4
    • /
    • pp.453-462
    • /
    • 2014
  • The levee and bridge pier in estuary of the Hangang River are exposed in a dangerous condition due to bank erosion and local scouring occurred since the summer season in 2011. At first, it is presumed that the high sandbar formed in river channel of the study area was an important element in the occurrence of bank erosion and local scouring. It can be presumed that the record-breaking depth of freezing due to cold wave for the long term during the winter season between 2010 and 2011 as well as the heavy intensive rainfall of 2011 had a decisive effect on the first damage of A section. The second damage of B section mainly occurred around the bridge pier constructed on the high water channel before it was washed away during the winter season between 2011 and 2012. It is considered that the second damage was caused by ice formation and ice floes.

Investigating Ephemeral Gully Erosion Heads Due To Overland Flow Concentration in Nonpoint Source Pollution Control (비점오염원 관리에서 지표수 집중화로 인한 구강 침식점 조사 방법 연구)

  • Kim, Ik-Jae;Son, Kyong-Ho
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2007.05a
    • /
    • pp.454-458
    • /
    • 2007
  • Nonpoint source (NPS) pollution is a serious problem causing the degradation of soil and water quality. Concentrated overland flow is the primary transport mechanism for a large amount of NPS pollutants from hillslope areas to downslope areas in a watershed. In this study, a soil erosion model, nLS model, to identify transitional overland flow regions (i.e., ephemeral gully head areas) was developed using the kinematic wave overland flow theory. Spatial data, including digital elevation models (DEMs), soil, and landcover, were used in the GIS-based model algorithm. The model was calibrated and validated using gully head locations in a large agricultural watershed, which were identified using 1-m aerial photography. The model performance was better than two previous approaches; the overall accuracy of the nLS model was 72 % to 87 % in one calibration subwatershed and the mean overall accuracy was 75 to 89 % in four validation subwatersheds, showing that the model well predicted potential transitional erosion areas at different watersheds. However, the user accuracy in calibration and validation was still low. To improve the user accuracy and study the effects of DEM resolution, finer resolution DEMs may be preferred because DEM grid is strongly sensitive to estimating model parameters. Information gained from this study can improve assessing soil erosion process due to concentrated overland flow as well as analyze the effect of microtopographic landscapes, such as riparian buffer areas, in NPS control.

  • PDF

CHARACTERISTICS OF LOW-TEMPERATURE PROCESSED DYE-SENSITIZED SOLAR CELL BY ELECTROCHEMICAL IMPEDANCE AND PHOTOCURRENT-PHOTOVOLTAGE TRANSIENT SPECTROSCOPY

  • Li, Yuelong;Lee, Doh-Kwon;Kim, Kyung-Kon;Ko, Min-Jae
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.381-381
    • /
    • 2011
  • In this study, a TiO2 colloidal sol was synthesized by sol-gel process, which was used as a "glue" agent to enhance interconnection of TiO2 particles in low temperature process for plastic dye sensitized solar cell. The crystalline phase of this TiO2 glue is pure anatase with average particles size of 5 nm, which was characterized by powder X-ray diffraction and high revolution-TEM. The viscous alcoholic paste without any organic binder was prepared from the mixture of commercial P25 powder and glue. Paste composition and sintering process parameters were optimized for high photovoltaic performance based on low temperature process. The electrochemical impedance spectroscopy and photocurrent-photovoltage transient spectroscopy were also employed to investigate the mechanism of electron transport in this binder free TiO2 film system.

  • PDF