• Journal of Biosystems Engineering
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• 제41권3호
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• pp.208-220
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• 2016

Purpose: Fusel oil is a potent volatile aroma compound found in many alcoholic beverages. At low concentrations, it makes an essential contribution to the flavor and aroma of fermented alcoholic beverages, while at high concentrations, it induced an off-flavor and is thought to cause undesirable side effects. In this work, we introduce Fourier transform near-infrared (FT-NIR) spectroscopy as a rapid and nondestructive technique for the quantitative determination of fusel oil in the Korean alcoholic beverage "soju". Methods: FT-NIR transmittance spectra in the 1000-2500 nm region were collected for 120 soju samples with fusel oil concentrations ranging from 0 to 1400 ppm. The calibration and validation data sets were designed using data from 75 and 45 samples, respectively. The net analyte signal (NAS) was used as a preprocessing method before the application of the partial least-square regression (PLSR) and principal component regression (PCR) methods for predicting fusel oil concentration. A novel variable selection method was adopted to determine the most informative spectral variables to minimize the effect of nonmodeled interferences. Finally, the efficiency of the developed technique was evaluated with two different validation sets. Results: The results revealed that the NAS-PLSR model with selected variables ($R^2_{\upsilon}=0.95$, RMSEV = 100ppm) did not outperform the NAS-PCR model (($R^2_{\upsilon}=0.97$, RMSEV = 7 8.9ppm). In addition, the NAS-PCR shows a better recovery for validation set 2 and a lower relative error for validation set 3 than the NAS-PLSR model. Conclusion: The experimental results indicate that the proposed technique could be an alternative to conventional methods for the quantitative determination of fusel oil in alcoholic beverages and has the potential for use in in-line process control.

• 분석과학
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• 제13권2호
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• pp.250-257
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• 2000

페인트, 섬유, 잉크 등은 범죄현장에 유류되는 많은 증거물 중 가장 빈번하게 접하게 되는 법과학 증거물로서 이들에 대한 분석 결과는 범죄현장과 피해자 또는 피의자, 피해자와 피의자간의 상황 재구성 및 인과관계, 도주 용의 차랑 등의 추적에 결정적인 역할을 하고 있다. 그러나 이들 시료는 육안으로 거의 확인이 되지 않을 만큼 극미량의 미세한 시료가 대부분이므로 법과학분야에서 미세시료에 대한 체계적인 분광학적 분석법이 대두되고 있다. 본 연구에서는 현미 자외/가시광선 현미분광광도계를 이용하여 섬유 14종, 국내 자동차 차체 페인트 2개 색상 44종 및 3개 회사의 컬러 프린트용 잉크로 인쇄한 4개 색상 12종에 대해 자외선/가시광선 영역(240-780nm)에서 투과 및 반사 측정법으로 측정하였으며, 각각 특징적인 흡수대로 섬유, 페인트 및 잉크의 이동식별이 가능하였다.

• Nuclear Engineering and Technology
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• 제52권11호
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• pp.2585-2593
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• 2020

Swift heavy ion (SHI) beam irradiation can generate desirable defects in materials by transferring sufficient energy to the lattice that favours huge possibilities in tailoring of materials. The effect of Ag¹⁵⁺ ion irradiation with energy 200 MeV on spray deposited V₂O₅ thin films of thickness 253 nm is studied at various ion doses from 5 × 10¹¹ to 1 × 10¹³ ions/㎠. The XRD results of pristine film confirmed orthorhombic structure of V₂O₅ and its average crystallite size was found to be 20 nm. The peak at 394 cm^-1 in Raman spectra confirmed O-V-O bonding of V₂O₅, whereas 917 cm^-1 arise because of distortion in stoichiometry by a loss of oxygen atoms. Raman peaks vanished completely above the ion fluence of 5 × 10¹² ions/㎠. Optical studies by UV-Vis spectroscopy shows decrement in transmittance with an increase in ion fluence up to 5 × 10¹² ions/㎠. The red shift is observed both in the direct and indirect band gaps until 5 × 10¹² ions/㎠. The surface topography of the pristine film revealed sheath like structure with randomly distributed spherical nano-particles. The roughness of film decreased and the density of spherical nanoparticles increased upon irradiation. Irradiation improved the conductivity significantly for fluence 5 × 10¹¹ ions/㎠ due to band gap reduction and grain growth.

• 한국안광학회지
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• 제5권2호
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• pp.193-199
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• 2000

수소화된 비정질 탄소 박막은 PECVD 방법으로 제작하였으며 박막의 증착률은 아세틸렌 가스의 함량에 의존하였다. 이것은 메탄 기체를 사용하였을 때와 비교해 조금 높았다. 박막의 광학적 밴드 갭은 1.4~1.8eV였으며 아세틸렌 함량에 밀접한 연관성을 보여주었다. Raman과 FTIR 분광에 의하여 $sp^3/sp^2$의 정성적인 분율을 결정할 수 있었으며 이러한 결과로부터 아세틸렌 함량 13.8%의 박막이 최적의 조건이었다.

• 한국결정성장학회지
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• 제10권1호
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• pp.5-12
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• 2000

Silicon carbide(SiC)는 뛰어난 전기적, 열적, 물리적 특성 때문에 내환경 전자소자용 반도체 재료로 널리 연구되고 있다. 본 연구에서는 화학기상증착법으로 단결정 6H-SiC 동종박막을 성장시키고 이의 성장 특성을 조사하였다. 특히, 몰리브덴 (Mo)-plate를 이용하여 SiC를 코팅하지 않은 graphite susceptor를 사용한 6H-SiC 동종박막 성장조건을 성공적으로 얻었다. 대기압 상태의 RF-유도가열식 챔버에서 CVD성장을 수행하였고, <1120> 방향으로 $3.5^{\circ}$off-axis된 기판을 사용하였다. 성장 박막의 결정성을 평가하기 위하여 Nomarski 관찰, 투과율 측정 , 라만 분광, XRD, 광발광(PL) 분광, 투과전자현미경(TEM) 측 정 등의 방법을 이용하였다. 이상과 같은 실험을 통하여, 본 연구에서는 성장온도 $1500^{\circ}C$, C/Si flow ratio ($C_3H_8$ 0.2 sccm, $SiH_4$ 0.3 sccm)인 성장조건에서 결정성이 가장 좋은 6H-SiC 동종박막을 얻을 수 있었다.

• 한국전기전자재료학회논문지
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• 제29권6호
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• pp.348-352
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• 2016

In this paper, GaN film was grown on AlN/PSS by hydride vapor phase epitaxy compared with GaN on planar sapphire. Thin AlN layer for buffer layer was deposited on patterned sapphire substrate (PSS) by metal organic chemical vapor deposition. Surface roughness of GaN/AlN on PSS was remarkably decreased from 28.31 to 5.53 nm. Transmittance of GaN/AlN grown on PSS was lower than that of planar sapphire at entire range. XRD spectra of GaN/AlN grown on PSS corresponded the wurzite structure and c-axis oriented. The full width at half maximum (FWHM) values of ${\omega}$-scan X-ray rocking curve (XRC) for GaN/AlN grown on PSS were 196 and 208 arcsec for symmetric (0 0 2) and asymmetric (1 0 2), respectively. FWHM of GaN on AlN/PSS was improved more than 50% because of lateral overgrowth and AlN buffer effect.

• 한국전기전자재료학회논문지
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• 제27권12호
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• pp.831-836
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• 2014

One-dimensional (1D) photonic crystals (PCs) were prepared by $TeO_x(2&lt;x&lt;3)/SiO_2$ with the difference refractive index, and fabricated by sputtering technique from a $TeO_2$ and $SiO_2$ target. The $TeO_x$(2$Ar:O_2=40:10$). A 10-pair $TeO_x(2&lt;x&lt;3)/SiO_2$ 1D PCs were fabricated with the structure parameters of filling factor=0.5185, and period=410 nm. The properties of 1D PCs with and without a defect layer were evaluated by UV-VIS-NIR. A normal mode 1D PC have a photonic band gap (PBG) in the near infrared (NIR) region from 1,203 to 1,421 nm. In the case of 1D PC containing a defect layer, a defect level appears at 1,291 nm. The measured transmittance (T) spectra are nearly corresponding to calculated results. After He-Cd laser exposure, the defect level is shifted from 1,291 nm to 1,304 nm.

• Advances in nano research
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• 제7권4호
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• pp.233-240
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• 2019

The present research work reports in-vitro anti-cancer activity of biologically synthesized ZnO nanoparticles (ZnO NPs) against human carcinoma cells viz SCC-40, SK-MEL-2 and SCC-29B using Sulforhodamine-B (SRB) Assay. ZnO NPs were synthesized by a unique and novel biological route using Temperature-gradient phenomenon where the extract of combination of Catharanthus roseus (L.) G. Don (C. roseus), Azadirachta indica (A. indica), Ficus religiosa (F. religiosa) and NaOH solution were used as synthesis medium. The morphology of the ZnO NPs was characterized by Transmission Electron Microscopy (TEM). TEM images reveal that particle size of the samples reduces from 76 nm to 53 nm with the increase in reaction temperature and 68 nm to 38 nm with the increase in molar concentration of NaOH respectively. XRD study confirms the presence of elements and reduction in crystallite size with increase in reaction temperature and NaOH concentration. The diffraction peaks show broadening and a slight shift towards lower Bragg angle ($2{\theta}$) which represents the reduction in crystallite size as well as presence of uniform strain. The FTIR spectra of the extract show transmittance peak fingerprint of Zn-O bond and presence of bioactive molecules These NPs exhibit inhibition greater than 50% for SCC-40, SK-MEL-2 and SCC-29B cell lines and more than 50% cell kill for SCC-29B cells at concentrations < $80{\mu}g/ml$. Nanoparticles with smallest size have shown better anti-cancer activity and peculiar cell-selectivity. The combination of extracts of these plants with ZnO NPs can be used in targeted drug delivery as an effective anti-cancer agent, a potential application in cancer treatment.

• 한국재료학회지
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• 제33권10호
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• pp.400-405
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• 2023

Tb³⁺-doped CaNb₂O₆ (CaNb₂O₆:Tb³⁺) thin films were deposited on quartz substrates at a growth temperature of 300 ℃ using radio-frequency magnetron sputtering. The deposited thin films were annealed at several annealing temperatures for 20 min and characterized for their structural, morphological, and luminescent properties. The experimental results showed that the annealing temperature had a significant effect on the properties of the CaNb₂O₆:Tb³⁺ thin films. The crystalline structure of the as-grown CaNb₂O₆:Tb³⁺ thin films transformed from amorphous to crystalline after annealing at temperatures greater than or equal to 700 ℃. The emission spectra of the thin films under excitation at 251 nm exhibited a dominant emission band at 546 nm arising from the ⁵D₄→⁷F₅ magnetic dipole transition of Tb³⁺ and three weak emission bands at 489, 586, and 620 nm, respectively. The intensity of the ⁵D₄→⁷F₅ (546 nm) magnetic dipole transition was greater than that of the ⁵D₄→⁷F₆ (489 nm) electrical dipole transition, indicating that the Tb³⁺ ions in the host crystal were located at sites with inversion symmetry. The average transmittance at wavelengths of 370~1,100 nm decreased from 86.8 % at 700 ℃ to 80.5 % at an annealing temperature of 1,000 ℃, and a red shift was observed in the bandgap energy with increasing annealing temperature. These results suggest that the annealing temperature plays a crucial role in developing green light-emitting CaNb₂O₆:Tb³⁺ thin films for application in electroluminescent displays.

• 한국잡초학회지
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• 제13권2호
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• pp.138-150
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• 1993

본(本) 실험(實驗)은 환경요인(環境要因)의 변동(變動)에 따른 벗풀의 생장(生長) 및 지하경번식체(地下莖繁殖體) 생산량(生産量)을 조사(調査)하여 벗풀의 합리적(合理的)인 방제법(防除法)을 확립(確立)하는데 기초자료(基礎資料)로 활용(活用)하고자 하였는 바 다음과 같은 결과(結果)를 얻었다. 1. 광량(光量)의 차이(差異)에 따른 벗풀의 엽수(棄數)와 화경수(花莖數)는 차광정도(遮光程度)가 클수록 감소(滅少)하였고 엽폭(葉幅)은 증가(增加)하였으며 초장(草長)은 노지(露地)에서 가장 짧았다. 벗풀의 지상부(地上部) 건물중(乾物重), 지하경(地下莖)의 수(數) 및 생체중(生體重)은 50%이하(以下) 광량(光量)에서는 광량(光量)간 유의차(有意差)가 없었으나 30% 이하(以下) 광량(光量)에서는 현저(顯著)히 저하(低下)되었다. 2. 광질(光質)의 차이(差異)에 따른 벗풀의 초장(草長)은 노지(露地)에서 가장 짧았으나 엽수(葉數)는 가장 많았다. 엽장(葉長)은 녹색(綠色)필름처리(處理)에서 가장 짧았고 엽폭(葉幅)은 노지(露地)와 수명(透明)필름처리(處理)에서 좁았다. 지상부(地上部) 건물중(乾物重)은 수명(透明) 및 녹색(綠色)필름처리(處理)에서 많았고 기타(其他) 광량간(光量間)에는 유의차(有意差)가 없었다. 지하경(地下莖)의 수(數)와 생체중(生體重)은 녹색(綠色)필름처리(處理)에서 가장 적었고 노지(露地)와 수명(透明)필름처리(處理)에서 많았다. 3. 초장(草長)은 0-5cm 담수심(湛水深)에서보다 10-20cm 담수심(湛水深)에서 길었고, 담수심(湛水深)이 깊어질수록 엽수(棄數)는 적었다. 엽장(葉長)과 화경수(花莖數)는 담수심(湛水深) 변동(變動)에 큰 영향(影響)이 없었다. 지상부(地上部) 건물중(乾物重), 지하경(地下莖)의 수(數) 및 생체중(生體重)은 0cm 담수심(湛水深)에서 가장 많았고 20cm 담수심(湛水深)에서 가장 적었다. 4. 벗풀의 초장(草長), 엽수(棄數)및 엽장(葉長)은 시비량(施把量)이 많을수록 증가(增加)하는 경향(傾向)이었으나 화경수(花莖數)는 시비량(施把量)에 영향(影響)이 적엇다. 벗풀의 지상부(地上部) 건물중(乾物重) 및 지하부(地下部) 번식체(緊植體) 생산량(生産量)은 시비량(施把量)의 증가(增加)에 따라 증가(增加)하였다. 5. 벗풀 지하경(地下莖)의 중량(重量)의 차이(差異)는 생육(生育)에 영향(影響)이 적었고, 지상부(地上部) 건물중(乾物重)에도 큰 영향(影響)이 없었으나 지하부(地下部) 번식(緊植) 생산량(生産量)은 재식(栽植)한 지하경(地下莖)의 중량(重量)이 클수록 증가(增加)하였다. 6. 출수기(出穗期)의 온도조건(溫度條件)에 따른 벗풀의 생육량(生育量)은 $35^{\circ}C$에서 보다$25^{\circ}C$에서 다소(多少) 적었고 생성(生成)된 지하경(地下莖)의 수(數)와 생체중(生體重)도 적었다.