• 제목/요약/키워드: Transition-state

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Excited State Absorption and Nonradiative Transition from the Lowest 5d State of $Ce^{3+}:YAlO_3$ ($Ce^{3+}:YAlO_3$ 단결정의 5d 상태 흡수 및 비발광 천이)

  • 김지병;임기수;이건준;김동호;한재민
    • Korean Journal of Optics and Photonics
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    • v.6 no.1
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    • pp.33-38
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    • 1995
  • We have measured the excited state absorption in $Ce:YAlO_{3}$, crystals for the first time and assigned it for a 5d$\rightarrow$conduction band transition. Two broad absorption bands were observed at 555 nm and 465 nm fowllowing the 308 nm XeCl laser excitation and their cross sections and oscillator strengths were calculated. We have also measured the fluorescence lifetimes in between 300 K and 700 K to study the nonradiative relaxation from the lowest 5d state of $Ce^{3+}$ ions and explained ESA and the transition process from the state in terms of a configurational coordinate.dinate.

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Decreased entropy of unfolding increases the temperature of maximum stability: Thermodynamic stability of a thioredoxin from the hyperthermophilic archaeon Methanococcus jannaschii

  • Lee, Duck-Yeon;Kim, Kyeong-Ae;Kim, Key-Sun
    • Journal of the Korean Magnetic Resonance Society
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    • v.8 no.1
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    • pp.1-18
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    • 2004
  • A thioredoxin from hyperthermophile, Methanococcus jannashii (MjTRX) was characterized by use of the differential scanning calorimetry to understand the mechanisms of thermodynamic stability. MjTRX has an unfolding transition temperature of 116.5$^{\circ}C$, although the maximum free energy of the unfolding (9.9 Kcal/mol) is similar to that of E. coli thioredoxin (ETRX, 9.0 Kcal/mol). However, the temperature of maximum stability is higher than ETRX by 20$^{\circ}C$, indicating that the unfolding transition temperature increased by shifting the temperature of maximum stability. MjTRX has lower enthalpy and entropy of the unfolding compared to ETRX maintaining a similar free energy of the unfolding. From the structure and the thermodynamic parameters of MjTRX, we showed that the unfolding transition temperature of MjTRX is increased due to the decreased entropy of the unfolding. Decreasing the unfolded state entropy and increasing the folded state entropy can decrease the entropy of the unfolding. In the case of MjTRX, the increased number of proline residues decreased the unfolded state entropy and the increased enthalpy in the folded state increased the folded state entropy.

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Initial State and Transition State Solvation for the Solvolysis of trans-$[Co(N-eten)_2Cl_2]$+ in Binary Aqueous Mixtures: Excess Free Energy, Free Energy Cycle and Reacton Mechanism

  • Park, Yu-Chul;Cho, Young-Je
    • Bulletin of the Korean Chemical Society
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    • v.11 no.4
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    • pp.309-313
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    • 1990
  • The rates of solvolysis of trans-$[Co(N-eten)_2Cl_2)$+ (N-eten; N-ethylethylenediamine) have been investigated using spectrophotometric method in binary aqueous mixtures containing methyl alcohol, isopropyl alcohol, t-butyl alcohol, ethylene glycol and glycerol. The values of ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ obtained from temperature effect on the rate constants were $80{\sim}84 kJmol^{-1}$ and $- 28{\sim} - 45 JK^{-1}mol^{-1}.$ Extrema found in the variation of the enthalpy and entropy of activation with solvent composition correlated very well with extrema in the variation of the physical properties of mixture which relate to sharp change in the solvent structure. The reaction mechanism was discussed in terms of correlation diagrams involving the exess molar Gibbs function of mixing for the binary mixtures. The behavior of this cobalt(Ⅲ) complex was compared with that of t-butyl chloride. The application of free energy cycle to the process initial state to transition state in water and in the mixture showed that the solvation of transition state had dominant effect on the rates in the mixtures. It was found that $S_N1$ character was increased with increasing the content of co-solvent in the mixture.

A Study on the Development of a Lanchester-Type Model Incorporating Firing & Observing States in the Direct Fire Engagement (Firing State와 Observing State를 갖는 Lanchester형 전투모형에 관한 연구)

  • Ham Il-Hwan;Choe Sang-Yeong;Song Mun-Ho
    • Journal of the military operations research society of Korea
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    • v.17 no.2
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    • pp.44-53
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    • 1991
  • This paper is aimed to develop a Lanchester type combat model for the direct-fire engagement. This model incorporates number of combatants, inter-firing time, detection time by movement, detection probability by the signature of fire, where the inter-firing time and the detection time are assumed to follow a negative exponential distribution. The approach to modeling is as follows : in the process of an engagement, a combatant takes one of the states('observing' state or 'firing' state), a combatant is initially in the observing state, if the combatant detects a target, he changes his state from 'observing' to 'firing' and will cause attrition to the opposing forces. Thus this transition mechanism is embodied into the differential equation form with each transition rate. A limited examination of the validity has been conducted by comparison with the Monte-Carlo simulation model 'BAGSIM', and with a traditional Deterministic Lanchester model.

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A Study on Construction of the Advanced Sequential Circuit over Finite Fields

  • Park, Chun-Myoung
    • Journal of Multimedia Information System
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    • v.6 no.4
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    • pp.323-328
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    • 2019
  • In this paper, a method of constructing an advanced sequential circuit over finite fields is proposed. The method proposed an algorithm for assigning all elements of finite fields to digital code from the properties of finite fields, discussed the operating characteristics of T-gate used to construct sequential digital system of finite fields, and based on this, formed sequential circuit without trajectory. For this purpose, the state transition diagram was allocated to the state dependency code and a whole table was drawn showing the relationship between the status function and the current state and the previous state. The following status functions were derived from the status function and the preceding table, and the T-gate and the device were used to construct the sequential circuit. It was confirmed that the proposed method was able to organize sequential digital systems effectively and systematically.

An Analysis on the State-Dependent Nature of DS/SSMA Unslotted ALOHA

  • Park Seong-Yong;Lee Byeong-Gi
    • Journal of Communications and Networks
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    • v.8 no.2
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    • pp.220-227
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    • 2006
  • In this paper, we present a novel approach to analyze the throughput of direct-sequence spread spectrum multiple access (DS/SSMA) unslotted ALOHA system. In the unslotted system, the departure rate of interfering transmissions is proportional to the number of current interferers that can be regarded as the system state. In order to model this state-dependency, we introduce a two-dimensional state transition model that describes the state transition of the system. This model provides a more rigorous analysis tool for the DS/SSMA unslotted ALOHA systems with both fixed and variable packet lengths. Numerical results reveal that this analysis yields an accurate system performance that coincides with the simulation results. Throughout the analysis we have discovered that the state-dependency of the departure rate causes interference averaging effect in the unslotted system and that this effect yields a higher throughput for the unslotted system than for the slotted system when supported by a strong channel coding.

Magnetic Properties of Ordered L12 FePt3: A First Principles Study

  • Kim, Dong-Yoo;Hong, Ji-Sang
    • Journal of Magnetics
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    • v.16 no.3
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    • pp.197-200
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    • 2011
  • Using the full potential linearized augmented plane wave (FLAPW) method, the influences of uniform and tetragonal strains on the magnetic state have been explored for chemically ordered bulk $L1_2$ $FePt_3$. The ordered state displays antiferromagnetic $Q_1$ (AFM-$Q_1$) state but it transitions into antiferromagnetic $Q_2$ (AFM-$Q_2$) state at about 10% uniform strain. The ferromagnetic (FM) state is observed at 11% uniform strain. For tetragonal strain, it is also seen that the transition from AFM-$Q_1$ to AFM-$Q_2$ depends on the strength and direction of the applied strain. The FM state does not appear in this case. Magnetocrystalline anisotropy (MCA) calculations for tetragonal distortion reveal that the spin reorientation transition occurs. In addition, we find that the direction of magnetization and the magnitude of magnetic anisotropy energy strongly depend on the c/a ratio.

A Construction Theory of Multiple-Valued Logic Sequential Machines on $GF(2^M)$

  • 박춘명;김흥수
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.24 no.5
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    • pp.823-832
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    • 1987
  • This pper presents a method for constructing multiple-valued logic sequential machines based on Galois field. First, we assign all elements in GF(2**m) to bit codes using mathematical properties of GF(2**m). Then, we realized the sequencial machine circuits with and withoutm feed-back. 1) Sequential machines with feed-back are constructed by using only MUX from state-transition diagram expressing the information of sequential machines. 2) Sequential machines without feed-back are constructed by following steps. First, we assigned states in state-transition disgram to state bit codes, then obtained state function and predecessor table explaining the relationship between present states and previous states. Next, we obtained next-state function from state function and predecessor table. Finally we realized the circuit using MUX and decoder.

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A New TRZF Delay Model for the Effcient Hazard Analysis in a 5-valued Logic Simulation (5치 논리 시률레이션에서 효율적인 헤저드 분석을 위한 TRF 지연 모델)

  • Gang, Min-Seop
    • The Transactions of the Korea Information Processing Society
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    • v.4 no.4
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    • pp.1004-1012
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    • 1997
  • This paper proposes a new TRF(Transition Rise\Fall)delay model for the effcient hazard analysis in a 5-valued logic sumulation enviroment.For the hazzard for a given logic circuit, the timing analysis is first performed by means of a 5-valued logic simulator which uses the TRF delay model which incorporates the response delay for a reponse state with the transition delay for a transition state of an elment, and then hazards are detected through investigating timing relations.Simulation examples and experimental results are also given to demostrate the pradticability of the proposed methods.

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Effect of Transition Metal on the Thermal Stability and Mechanical Property of Fe-based Amorphous Alloys (Fe기 비정질합금의 열적안정성 및 기계적 성질에 미치는 천이금속의 영향)

  • Gook, Jin Seon;Yoon, Dong Joo
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.6
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    • pp.345-349
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    • 2001
  • This study has investigated the effect of thermal stability and mechanical property of $Fe_{80-X}P_{10}C_6B_4M_X$(X=2, 4, 6, M=transition metal) amorphous alloys fabricated by the melt-spun process. The glass transition temperature($T_g$), crystallization temperature($T_x$) and hardness increase with decreasing electron concentration (e/a) from about 7.38 to 7.18. The decrease of e/a implies the increase in the attractive bonding state between the M elements and other constituent element. The decrease in a/e leads to the enhancement of the attractive bonding state among the constituent elements which is favorable for the increase in $T_g$, $T_x$ and hardness.

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