• 제목/요약/키워드: Transition phase

검색결과 1,991건 처리시간 0.029초

EF-TEM 직접가열 실험을 통한 titanium의 고온 상전이 연구 (A Study of Titanium Phase Transition through In-situ EF-TEM Heating Experiments)

  • 김진규;이영부;김윤중
    • Applied Microscopy
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    • 제33권1호
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    • pp.49-58
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    • 2003
  • EF-TEM 직접가열 실험을 통하여 titanium의 ${\alpha}-{\beta}$상전이를 연구하였다. 통계적 오차를 줄이기 위해 서로 다른 3군데의 titanium foil의 영역을 관찰하였고, 각각의 영역에 대해 단계별로($RT{\rightarrow}600{\rightarrow}900{\rightarrow}RT$) 회절패턴과 이미지를 기록하였다. 이 연구를 통해 얻은 결과는 다음과 같다. (1) Titanium은 $900^{\circ}C$에서 급격히 상전이가 진행된다. 이 온도에서는 ${\alpha}$${\beta}$-상이 같이 존재한다. (2) 상전이가 일어난 ${\beta}$-상의 영역은 쌍정구조를 가진 plate 형태로 나타나며, 그들은 서로 상호 회전 배열되어 있다. (3) 전자회절도형과 EDS 분석 결과, $600^{\circ}C$ 이상의 가열에서는 열적 산화에 의해 Ti의 산화물이 표면에서 생성되기 시작하며 이들은 냉각 시 Ti의 ${\beta}{\rightarrow}{\alpha}$ 가역 상전이를 저해한다.

Febry-Perot 간섭계를 이용한 강유전 P(VDF-TrFE) 폴리머 열광학 특성평가 (Characterization of Thermo-optical Properties of Ferroelectric P(VDF-TrFE) Copolymer Using Febry-Perot Interferometer)

  • 송현철;김진상;윤석진;정대용
    • 한국재료학회지
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    • 제19권4호
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    • pp.228-231
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    • 2009
  • Phase transition in ferroelectric polymer is very interesting behavior and has been widely studied for real device applications, such as actuators and sensors. Through the phase transition, there is structural change resulting in the change of electrical and optical properties. In this study, we fabricated the Febry-Perot interferometer with the thin film of ferroelectric P(VDF-TrFE) 50/50 mol% copolymer, and thermo-optical properties were investigated. The effective thermo-optical coefficient of P(VDF-TrFE) was obtained as $2.3{\sim}3.8{\times}10^{-4}/K$ in the ferroelectric temperature region ($45^{\circ}C{\sim}65^{\circ}C$) and $6.0{\times}10^{-4}/K$ in the phase transition temperature region ($65^{\circ}C{\sim}85^{\circ}C$), which is a larger than optical silica-fiber and PMMA. The resonance transmission peak of P(VDF-TrFE) with the variation of temperature showed hysteretic variation and the phase transition temperature of the polymer in heating condition was higher than in the cooling condition. The elimination of the hysteretic phase transition of P(VDF-TrFE) is necessary for practical applications of optical devices.

기판 예열 온도에 따른 Copper (II) phthalocyane의 phase 변화 및 박막의 결정 변화 (Phase transition of Copper (II) Phthalocyanine and crystal structures due to a heat treatment temperature of substrate)

  • 박미화;윤순일;임은주;이기진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1014-1017
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    • 2003
  • 열증착법을 이용하여 copper(II) phthalocyane (CuPc)의 박막을 제작하였다. 기판의 예열 온도를 달리하여 제작된 CuPc의 박막은 ${\alpha}-phase$${\beta}-phase$로 구분할 수 있으며 phase에 따른 결정 구조를 관찰하기 위해 x-ray diffraction을 사용하고 peak의 위치를 관찰하였다. 또한 SEM, UV visible absorption spectra의 변화를 통해 온도에 따라 상전이가 이행해 가는 모습을 구체적으로 관측하였다. 이러한 결정 구조의 변화는 CuPc 박막의 전기전도 특성에 영향을 달리하여 유기발광 소자에 응용이 가능할 것으로 예상된다.

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철 초전도체에서 스핀 밀도 파와 $\pi$ 위상 차 초전도성의 상전이 그림 (Phase Diagram of Spin Density Wave and $\pi$ Phase Shifted Superconductivity in the Fe Pnictide Superconductors)

  • 이나영;최한용
    • Progress in Superconductivity
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    • 제11권2호
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    • pp.112-117
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    • 2010
  • We examine phase transition of the spin density wave and $\pi$ phase shifted superconductivity in the Fe pnictide superconductors. The phase diagram is described in the plane of the temperature T and the doping x with the combination of Ginzburg-Landau expansion of the free energy near the multi-critical temperature $T_c$ and the self-consistent numerical iterations of the gap equations. The phase separation or coexistence is determined by computing the 4-th order terms of the free energy which is confirmed by the numerical calculations. We can show the phase coexistence when the spin density wave is incommensurate. And the first order phase transition is observed near the boundary between commensurate and incommensurate spin density wave.

부산측후소(釜山測候所)를 중심으로 본 근대기 측후소 건축의 설치과정과 공간적 특성에 관한 고찰 (Study on the Installation process and Spatial characteristics of Modern Meteorological Observatory Construction, Centering on the Busan Meteorological Observatory)

  • 김영분;김기수
    • 건축역사연구
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    • 제23권2호
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    • pp.39-52
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    • 2014
  • This study researched changes over time regarding the location and spatial characteristics of modern meteorological stations, and examined the characteristics of modern meteorological station construction using the location and spatial characteristics of the Busan Meteorological Station. First, meteorological stations were located in port areas, and then moved to high altitude areas for stable meteorological observation beginning in the transition phase. Here, office buildings and residences were joined, but were separated due to the increase in functions from the stabilization phase. Second, as for spatial composition, in the establishment phase, existing buildings were used, and the scale of newly constructed buildings differed according to time and area. However, after the Japan-Korea Annexation, with increased funds and increased observation equipment, floor plans subdivided by function started to appear. In the stabilization phase, space was subdivided with redundancy due to the increase in functions. In the wartime transition phase, '一' shaped floor plans with redundancy became the norm. Meanwhile, the location of the maritime customs where the first meteorological observations took place after the opening of the ports, and the location and construction of the Busan Temporary Observatory built in the meteorological observation transition phase (1905) were investigated. Also, through the investigation of the Busan Meteorological Observatory, newly constructed before 1934, the location and spatial characteristics of modern era meteorological observatories were studied.

PZT 요업체에서 입자 크기가 상전이에 미치는 영향 (Grain size effects on the dielectric phase transition in PZT ceramics)

  • 정훈택;김호기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1989년도 춘계학술대회 논문집
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    • pp.107-109
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    • 1989
  • Based on the ferroelectric microstructural residual stress model, the relation between grain size and residual elastic energy was proposed. It was found that the residual elastic energy increased with decreasing grain size by modeling and DSC results. This residual elastic energy change with grain size which induce the phase transituion mode change was the cause of a diffuse phase transition in small grain size.

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산성광산배수에서 발견되는 흰색침전물의 상전이에 대한 예비 연구 (Preliminary Study on the Phase Transition of White Precipitates Found in the Acid Mine Drainage)

  • 여진우;김영규
    • 한국광물학회지
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    • 제32권2호
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    • pp.79-86
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    • 2019
  • 산성광산배수에서 흰색 알루미늄 침전물은 pH가 상대적으로 높은 하천수와 만나 섞일 때 주로 발생한다. 이 침전물을 구성하는 광물은 산성광산배수 내 중금속 등을 흡착 공침하여 이들 중금속의 거동을 조절하는 중요한 역할을 한다. 이러한 흰색 침전물을 구성하고 있는 광물들은 추후 상변화를 거치며 그러한 과정 중에 중금속의 용해 재흡착 등이 일어날 수 있다. 본 연구는 이러한 흰색 침전물의 상전이 과정에 대한 기본적인 정보를 얻기 위하여 수행되었다. 본 연구에서는 도계광업소 주변의 하천에서 채취한 흰색 침전물을 대상으로 서로 다른 pH와 온도의 조건에서 시간이 지남에 따라 일어나는 광물상의 변화를 살펴보았다. 흰색 침전물은 주로 basaluminite와 비정질 $Al(OH)_3$ 및 미량의 $Al_{13}$-tridecamer의 혼합물로 구성되며, basaluminite의 부조화용해가 먼저 일어나 비정질 $Al(OH)_3$의 함량이 증가한 이후, pseudoboehmite의 전구물질 단계를 거쳐서 pseudoboehmite가 최종 침전되는 상전이 과정을 거친다. $80^{\circ}C$의 온도에서는 이러한 일련의 과정이 잘 나타났지만, 비교적 낮은 온도에서는 basaluminite와 비정질 $Al(OH)_3$가 공존하는 초기 침전물 상태로 남아있었다. 그리고 높은 pH는 basaluminite의 $SO{_4}^{2-}$기의 탈착을 유도하여 pseudoboehmite 전구물질로의 상전이를 촉진하였다. 시간이 지남에 따라 광물의 용해 및 상전이에 의하여 용액의 pH는 낮아지는 경향을 보였으며, 최종산물인 pseudoboehmite가 형성되어도 약간의 입자의 크기 증가만 관찰되고 완전한 결정질의 형태는 보이지 않았다.

Phase-shedding in Boundary Conduction Mode Converter with Optimal Transition Load-level

  • Choi, Wooin;Baek, Jong-Bok;Cho, Bo-Hyung
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2011년도 추계학술대회
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    • pp.73-74
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    • 2011
  • Phase-shedding, one famous technology for multi-phase converters, is implemented in a bi-directional multi-phase converter for ESS. It reduces active operating modules at light load to compensate efficiency. Shedding point, the load level where the converter changes the number of active modules, is important factor that affects the effect of phase-shedding. Loss analysis is done for determining shedding point. Phase-shedding hysteresis is applied so that excessive phase transition is avoided. This paper proposes shedding point correction where the shedding point is adaptively corrected by calculating a new shedding point.

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Bi계 치환 고온 초전도체 (Studies of Element Substitution on Superconductivity in Bi-Sr-Ca-Cu-O Oxides)

  • 권오흥;박천제
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.124-128
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    • 2000
  • The high Tc phase disappeared and low Tc phase increased in the substitution of transition elements for Bi ions. The high Tc phase decreased in the substitution of Si and Sn for Bi ions. The high Tc phase increased in the substitution of Sb, As and P which were the same group of Bi for Bi ions. The substitution of P ions was the most effective and then the high Tc phase was formed in large quantity by replacing Bi ions with 30% of P ions.

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A Long Way from Transfer to Transition: Challenges for Pediatric and Adult Nephrologists

  • Lemke, Johanna;Pape, Lars;Oh, Jun
    • Childhood Kidney Diseases
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    • 제22권1호
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    • pp.7-11
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    • 2018
  • Significant advances in the diagnosis and medical care of children with chronic kidney disease (CKD) are major reasons for the better survival rates of children and adolescents with CKD than the survival rates reported in previous decades. These patients are reaching adulthood, and therefore require a transition to adult medical care. This transition phase is well-recognized to be associated with considerably increased morbidities and medical problems, such as non-adherence, graft loss after transplantation, and loss to follow-up. Low adherence increases morbidity and medical complications and contributes to poorer qualities of life and an overuse of the health care system. However, these tragic outcomes may be avoidable through a structured and well-defined transition program. In the last decade, there has been increasing interest to resolve these medical and psychological problems that occur during the transfer of young adult patients from pediatric to adult renal units. The aims of a successful transition from pediatric to adult medical care include enhancing the individual development of better health-competence and stabilizing, or even improving, the state of health. This review will focus on various aspects of the transition phase of adolescents who have CKD or who underwent kidney transplantation from pediatric to adult nephrology care.