• Title/Summary/Keyword: Transition curve

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Coil-to-globule transition of thermo-responsive γ-substituted poly (ɛ-caprolactone) in water: A molecular dynamics simulation study

  • Koochaki, Amin;Moghbeli, Mohammad Reza;Nikkhah, Sousa Javan
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1313-1319
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    • 2018
  • The coil-to-globule behavior of poly{${\gamma}$-2-[2-(2methoxyethoxy)ethoxy]ethoxy-3-caprolactone} (PMEEECL) as a ${\gamma}$-substituted poly (${\varepsilon}$-caprolactone) was investigated via atomistic molecular dynamics (MD) simulation. For this purpose, radius of gyration, end-to-end distance and radial distribution function of the chain in the presence of water were calculated. Consequently, the lower critical solution temperature (LCST) of PMEEECL chain at which the coil-to-globule transition takes place, was determined in each calculated parameter curve. The simulation results indicated that the LCST of PMEEECL was occurred at close to 320 K, which is in a good agreement with previous experimental results. Additionally, the appearance of sudden change in both Flory-Huggins interaction parameter (${\chi}$) and interaction energy between the PMEEECL chain and water molecules at about 320 K confirmed the calculated LCST result. The radial distribution function (RDF) results showed that the affinity of the PMEEECL side chain to water molecules is lower than its backbone.

A Study on the Storage-Yield Relationship of Reseroir (저수지의 Storage-Yield에 관한 연구)

  • 이순탁;장인수
    • Water for future
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    • v.18 no.3
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    • pp.253-264
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    • 1985
  • Basically, there are two ways viewing the reservoir storage-yield relationship., The most common viewpoint is the determination of the storage required at a given reservoir to supply a required yield. This type of problem is usually encountered in the planning and early design phases of a reservoir. The second viewpoint is the determination of yield from a given amount of storage. This often occurs in the final design phases or in re-evaluation of an existing reservoir for a more comprehensive analysis. The purpose of this study is to improve the present methodology estimating the storage-yield relationship for a reservoir design or a reservoir operation. The Residual Mass curve Technique, the slightly modified version of Low Flow Techniques and the Transition Probability Matrix Technique are reviewed and examined for the best fit technique to find the reservoir storage-yield realtionship. The historical data during 1917~1940 at the proposed Hongchun damsite and the synthetic data simulated by Thomas-Fiering model are utilized to examine the reservoir storge-yield relationship with three techniques in detail. After the three techniques which estimate the reservoir storage-yield relationship were reviewed extensively, it was concluded that the Residual Mass Curve Technique and the slightly modified version of Low Flow Techniques were suitable for a preliminary design, but the Transition Probability Matrix Technique Provided satisfactory results as a final design technique because it reflected the variation of a monthly yield as well as seasonlly.

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An Experimental Study and Numerical Analysis on Load Transfer Characteristics of Drilled Shafts (현장타설말뚝의 하중전이 특성에 대한 실험 및 해석적 연구)

  • Eonsang Park;Seungdo Park
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.1
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    • pp.5-14
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    • 2023
  • In this study, the load transfer characteristics of the base and skin of drilled shafts were analyzed and the load sharing ratio was calculated by performing a load transfer large-scale model test and three-dimensional numerical analysis considering the similarity of drilled shafts, which is the design target. From the linear behavior of drilled shafts shown in the large-scale model test and 3D numerical analysis results, the skin load transition curve for the design conditions of this study was proposed by Baquelin et al., and the base load transition curve was proposed by Baquelin et al. For the horizontal load transition curve, the formula proposed by Reese et al. was confirmed to be appropriate. The test value was slightly larger than the numerical analysis value for the axial load at the rock socketing, but the load sharing ratio at the rock socketing increased, on average, about 27.8% as the vertical load increased. The analysis value of the vertical settlement of the pile head under the vertical load was evaluated to be slightly smaller than the test value, and the maximum vertical settlement of the pile head in the model test and analysis maximum vertical load was 10.6 mm in the test value and 10.0 mm in the analysis value, and the maximum vertical settlement value at the base of the pile was found to be a test value of 2.0 mm and an analysis value of 1.9 mm. The horizontal displacement at the head of the column (ground surface) and the head of the pile during the horizontal load was found to agree relatively well with the test value and the analysis value. As a result of the model soil test, the horizontal load measured at the maximum horizontal displacement of 38.0 mm was evaluated to be 24,713 kN, and the horizontal load in the numerical analysis was evaluated to be 26,073 kN.

A Viscoelastic Study of Glass Transition and Degradation Processes of Phenolic Resin/Carbon Fiber Composites (페놀수지/탄소섬유 열경화성 복합재료의 유리전이와 고온 분해과정에서 관찰되는 점탄성 특성 연구)

  • ;J. C. Seferis
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.9-17
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    • 1999
  • Viscoelastic characteristics of cured phenolic resin/carbon fiber composite materials were investigated through glass transition and degradation reaction processes in the high temperature region up to $400^{\circ}C$. A typical glass transition of the cross-linked thermoset polymer was followed by irreversible degradation reactions, which were exhibited by the increasing storage modulus and loss modulus peak. A degradation master curve was constructed by using the vertical and horizontal shift factors, both of which complied well with the Arrhenius equation in light of the kinetic expression of degradation rate constants. Using an analogy to the Havriliak-Negami equation in dielectric relaxation phenomena, a viscoelastic modeling methodology was developed to characterize the frequency- and temperature-dependent complex moduli of the degrading thermoset polymer composite systems. The temperature-dependent relaxation time of the degrading composites was determined in a continuous fashion and showed a minimum relaxation time between the glass transition and degradation reaction regions. The capability of the developed modeling methodology was demonstrated by describing the complex behavior of the viscoelastic complex moduli of reacting phenolic resin composite systems.

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MoTE-ECC Based Encryption on MSP430

  • Seo, Hwajeong;Kim, Howon
    • Journal of information and communication convergence engineering
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    • v.15 no.3
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    • pp.160-164
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    • 2017
  • Public key cryptography (PKC) is the basic building block for the cryptography applications such as encryption, key distribution, and digital signature scheme. Among many PKC, elliptic curve cryptography (ECC) is the most widely used in IT systems. Recently, very efficient Montgomery-Twisted-Edward (MoTE)-ECC was suggested, which supports low complexity for the finite field arithmetic, group operation, and scalar multiplication. However, we cannot directly adopt the MoTE-ECC to new PKC systems since the cryptography is not fully evaluated in terms of performance on the Internet of Things (IoT) platforms, which only supports very limited computation power, energy, and storage. In this paper, we fully evaluate the MoTE-ECC implementations on the representative IoT devices (16-bit MSP processors). The implementation is highly optimized for the target platform and compared in three different factors (ROM, RAM, and execution time). The work provides good reference results for a gradual transition from legacy ECC to MoTE-ECC on emerging IoT platforms.

Dynamic Deformation Behavior of Rubber Under High Strain-Rate Compressive Loading by Using Plastic SHPB Technique (플라스틱 SHPB기법을 사용한 고무의 고변형률 하중 하에서의 동적변형 거동)

  • 이억섭;김경준
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.11
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    • pp.158-165
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    • 2003
  • A specific experimental method, the Split Hopkinson pressure bar (SHPB) technique has been widely used to determine the dynamic material properties under the impact compressive loading conditions with strain rate of the order of 10$^3$/s∼l0$^4$/s. In this paper, dynamic deformation behaviors of rubber materials widely used for the isolation of vibration from structure under varying dynamic loading are determined by using plastic SHPB technique. A transition point to scope with the dynamic deformation behavior of rubber-like material is defined in this paper and used to characterize the specifics of the dynamic deformation of rubber materials.

Mechanical Behavior of Steel Fiber Reinforced Lightweight Polymer Concretese (강섬유보강 경량 폴리머 콘크리트의 역학적 거동)

  • Youn, Joon-No;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.2
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    • pp.63-72
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    • 2005
  • In this study, the physical and mechanical properties of steel fiber reinforced lightweight polymer concrete were investigated experimentally with various steel fiber contents. All tests were performed at room temperature, and stress-strain curve and load-deflection curve were plotted up to failure. The unit weight of steel fiber reinforced lightweight polymer concrete was in the range of $1,020{\sim}1,160\;kg/m^3$, which was approximately $50\%$ of that of the ordinary polymer concrete, The compressive strength, splitting tensile strength, flexural toughness and flexural load-deflection curves after maximum load were shown with increase of steel fiber content. The stress-strain curves of steel fiber reinforced lightweight polymer concrete were bilinear in nature with a small transition zone, Based on these results, steel fiber reinforced lightweight polymer concrete can be widely applied to the polymer composite products.

Evaluation of Speed Limit of Tilting Trains Including Passenger's Comfort in Conventional Line (틸팅특성과 승차감을 고려한 틸팅열차의 곡선부 제한속도 평가)

  • Eum Ki-Young;Um Ju-Hwan;Yeo In-Ho;You Young-Hwa
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.927-934
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    • 2004
  • For the purpose of speed-up of conventional lines with many curves, the introduction and operation of tilting train is under process. Those are Joong-Ang, Jang-Hang and Ho-nam lines etc. Tilting trains can run a curve section faster than existing trains without a significant violation of passenger's comfort and enable to reduce operating time in the lines with many curves. In this study, the trains speeds are evaluated, based on the alignment of conventional line, criteria for passenger's comfort and investigated field conditions of the sections where the curves exist. Decision on whether the alignment(transition line) needs to be modified or not is also made. Relative efficiency on curve sections of tilting train to existing trains is approximately $50\%$ in average.

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Study for the advancement of vechilc's passing speed on the curve (차량의 선진화에 따른 기존선의 곡선부 통과속도 향상에 관한 연구)

  • Nam Ki-Jeon;Choi Yun-Sik;Kim Hoon;Kim Dae-Youl;Kim Do-Han
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.942-947
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    • 2004
  • After a lot of hard effort during last 50 years, we have been finally beared fruit of a high speed vehicle. But, A large percentage of the existing railways are actually being lasted it's last popularity because of the backward speed. The object of this research isn't supposed to make an effort for developing vehicle's speed with lower budget, but to evaluate it's efficiency. The time has come for upgrading train's lower speed with at the minimum of rail's changing. To solve this problem, we are describing that is how to control a transition curve of the railway.

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Computer Curve-Fitting of Crystallization Peak of Amorphous $Pb(Fe_{2/3}W_{1/3})O_3$ Ceramics (비정질 $Pb(Fe_{2/3}W_{1/3})O_3$ 결정화 피크의 컴퓨터 합성)

  • 김남경
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1202-1208
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    • 1994
  • On heating amorphous Pb(Fe2/3W1/3)O3 ceramics, glass transition occurred at 35$0^{\circ}C$, crystallization at 394~420, 485~550 and 540~571$^{\circ}C$ (depending on the heating rates of 2.5~8$0^{\circ}C$/min), phase transformation at 680 and 73$0^{\circ}C$, and melting at 935$^{\circ}C$. A curve-fitting computer program was made using FORTRAN, based on a kinetic equation. Reconstructed thermograms (using the program) turned out to be very close to the measured DSC results for all the heating rates, with average deviation of only 4% at maximum.

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