• Ocean and Polar Research
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• v.42 no.1
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• pp.49-61
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• 2020

We analyzed the morphological characteristics of OCC (Ocean Core Complexes) in the middle part of the Central Indian Ridge (MCIR) using high-resolution geophysical data recorded on the Deep-Tow SideScan Sonar IMI-30 system. In terms of slope-gradient variations calculated from the high-resolution bathymetry data, the normal faults formed by seafloor spreading were associated generally with slopes > 30° and resulted in high backscatter intensities, which reflect more topographic effects than acoustic medium variation. However, the areas associated with gentle slopes < 10° tend to show the backscatter intensities reflecting the acoustic characteristic of the medium. We show that the detachment faults exposing the OCCs were initiated with high-angle normal faults (58°) exhibiting outward and inward dips of a breakaway zone. In order to examine the spatial distribution of OCC structures, we characterized the transition from magmatic-dominant seafloor with abyssal hills to tectonic-dominant seafloor with OCC using the down-slope direction variation. The slope direction of the seafloor generally tends to be perpendicular to the ridge azimuth in the magmatic-dominant zone, whereas it becomes parallel to the given ridge azimuth near the OCC structures. Therefore, this spatial change of seafloor slope directions indicates that the formation of OCC structures is causally associated with the tectonic-dominant spreading rather than magmatic extension. These results also suggest that the topographical characteristics of seafloor spreading and OCC structures can be distinguished using high-resolution geophysical data. Thus, we propose that the high-resolution bathymetry and backscatter intensity data can help select potential areas of exploitation of hydrothermal deposits in MCIR effectively.

• Clean Technology
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• v.18 no.1
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• pp.57-62
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• 2012

Aqueous poly (vinyl alcohol) (PVA) solution was modified by using hydrophobic vinyltriethoxysilane (VTEOS) and then adding different amounts of poly (acrylic acid) (PAA) to the resulting solution. Thermal and mechanical properties, contact angle, water vapor transmission rate (MVTR) and oxygen gas transmission rate ($O_2TR$) of the film samples fabricated by these solutions were investigated. The glass transition temperature (Tg) of the VTEOS-modified films was sightly increased and the value remained unchanged according to the amount of PAA. The tensile strength of the VTEOS-modified films was found to be 9.48~10.72 $kg/mm^2$ which showed no significant difference compared with that of PVA. The film prepared with VTEOS-modified PVA/PAA (= 90/10), of which the swelling and solubility were measured to be 198% and 0%, respectively, showed improved water-resistance. The MVTR and $O_2TR$ for the PET film (thickness 50 ${\mu}m$) coated with VTEOS-modified PVA/PAA (= 90/10) film (thickness 2.5 ${\mu}m$) were measured to be 11.04 $g/m^2/day$ and 3.1 $cc/m^2/day$, respectively.

• Polymer(Korea)
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• v.36 no.2
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• pp.223-228
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• 2012

Temperature and pH sensitive graft copolymers [Pluronic-$g$-poly(NIPAAm-$co$-MMA), Polymer A] and [Pluronic-$g$-poly( NIPAAm-$co$-MAA), Polymer C] were synthesized by macro radical graft polymerization with $N$-isopropylacrylamide (NIPAAM)/$N,N$-diethylaminoethylmethacrylate (DEAEMA) and $N$-isopropylacrylamide (NIPAAm)/methacrylic acid (MAA) based on Pluronic, respectively. The chemical structure and molecular weight of the graft copolymers was characterized by $^1H$ NMR and gel permeation chromatography. The aqueous solution properties of graft copolymers were measured using a UV-visible spectrophotometer, contact angle and dynamic light scattering equipment with different temperature and pH conditions. The obtained graft copolymers showed a very sensitive phase transition in response to temperature and pH in aqueous media which suggested that the amine group of DEAEMA segment and carboxylic group of MAA had a great influence on the lower critical solution temperatures (LCST) in Polymer A and C, respectively. The graft copolymers can be utilized for drug delivery system and molecular switching applications where responses to temperature and pH changes are relevant.

• Korean Journal of Materials Research
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• v.5 no.6
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• pp.748-753
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• 1995

Solid solution of NaNb $O_3$70 mol% and SrTi $O_3$30 mol% was single phase. A broad dielectric peak was found at about l00K. Crystal structure was analysed at room temperature and 12K using Rietveld analysis. The unit cell was assigned to have a a doubled lattice parameter of simple perovskite sturcture at room temperatue, the structure was orthorombic with space group Pmmn. At 12K, the structure was also orthorombic with space group Pnma. This structure change with temperature was due to the distortion of oxygen octahedron. This distortion of oxygen octahedron was made by the decrease of (Ti, Nb)-O bounds length with no variation of (Ti, Nb)-O-(Ti, Nb) bound angle. Therefore the broad dielectirc peak about l00K was attributed to the structural change casued by oxygen octahedron distortion.

• Journal of the Korean Vacuum Society
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• v.18 no.4
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• pp.245-253
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• 2009

For the growth optimization of InAs/GaSb (8/8-ML) strained-layer superlattice (SLS), the structure has been grown under various conditions and modes and characterized by the high-resolution x-ray diffraction (XRD) analysis. In this study, the strain modulation is induced by changing parameters and modes, such as the growth temperature, the ratio of V/III beam-equivalent-pressure (BEP), and the growth interruption (GI), and the strain variation is analyzed by measuring the angle separation of 0th-order satellite peak in XRD patterns. The XRD results reveal that the growth temperature and the V/III(Sb/Ga) ratio are major parameters to change the crystallineity and the strain modulation in SLS structures, respectively. We have observed that the SLS samples with compressive strain prepared in this study are show a transition to tensile strain with decreasing V/III(Sb/Ga) ratio, and the GI process is a sensitive factor giving rise to strain modulation. These results obtained in this study suggest that optimized growth temperature and V/III(Sb/Ga) ratio are $350^{\circ}C$ and 20, respectively, and the appropriate GI time is approximately 3 seconds just before InAs growth that the crystallineity is maximized and the strain relaxation is minimized.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.809-814
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• 2005

In this work, the thermal properties of epoxy coating system on the liner plate in the containment structure of nuclear power plants had been examined by irradiation and design basis accident (DBA) conditions. The effect of immersion in hot water on adhesion strength of the coating system had been also studied. The glass transition temperature ($T_g$) and thermal stability of ET-5290/carbon steel A 32 epoxy coating systems were measured by DSC and TGA analyses, respectively. Contact angle measurements were used to determine the effect of immersion on the surface energetics of epoxy coating system, with a viewpoint of surface free energy. Adhesion tests were also executed to evaluate the adhesion strength at interfaces between carbon steel plate and epoxy resins. As a result, it was found that the irradiation led to an improvement of internal crosslinked structure in cured epoxy systems, resulting in significantly increasing the thermal stability, as well as the $T_g$. Also, the immersion in hot water made a role in the post-curing of epoxy resins and increased the mechanical interlocking of the network system, resulting in increasing the adhesion strength of the epoxy coating system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.12
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• pp.910-917
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• 2018

This paper describes the developments to improve the feeling and safety of the remote control system of unmanned vehicles. Generally, in the case of the remote control systems, a joystick-type device or a simple steering-wheel are used. There are many cases, in which there are operations without considering the feedback to users and driving feel. Recently, as the application area of the unmanned vehicles has been extended, the problems caused by not considering the feedback are emphasized. Therefore, the need for a force feedback-haptic control arises to solve these problems. In this study, the force feedback-haptic control algorithm considering the vehicle parameters is proposed. The vehicle parameters include first the state variables of dynamics, such as the body side-slip angle (${\beta}$) and yawrate (${\gamma}$), and second, the parameters representing the driving situations. Force feedback-haptic control technology consists of the algorithms for general and specific situations, and considers the situation transition process. To verify the algorithms, a simulator was constructed using the vehicle dynamics simulation tool with CAN communication environment. Using the simulator, the feasibility of the algorithms was verified in various scenarios.

• Journal of the Korean Geotechnical Society
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• v.22 no.8
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• pp.129-136
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• 2006

Engineered mixtures, which consist of rigid sand particles and soft fine-grained rubber particles, are tested to characterize their small and large-strain responses. Engineered soils are prepared with different volumetric sand fraction, sf, to identify the transition from a rigid to a soft granular skeleton using wave propagation, $K_{o}-loading$, and triaxial testing. Deformation moduli at small, middle and large-strain do not change linearly with the volume fraction of rigid particles; instead, deformation moduli increase dramatically when the sand fraction exceeds a threshold value between sf=0.6 to 0.8 that marks the formation of a percolating network of stiff particles. The friction angle increases with the volume fraction of rigid particles. Conversely, the axial strain at peak strength increases with the content of soft particles, and no apparent peak strength is observed in specimens when sand fraction is less than 60%. The presence of soft particles alters the formation of force chains. While soft particles are not part of high-load carrying chains, they play the important role of preventing the buckling of stiff particle chains.

• Korean Journal of Ichthyology
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• v.35 no.2
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• pp.75-82
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• 2023

The samples used in this study were collected on two occasions (April 21 and May 16, 2021) from Liobagrus mediadiposalis and spawned egg masses located under rocks in Daeseocheon, Yeongdeok-gun, Gyeongsangbuk-do. Fertilized eggs ranged in size from 3.30~3.92 (average 3.57±0.19) mm (n=30), and it took 152~155 hours to hatch at water temperatures of between 17.0 and 20.0℃. Newly hatched larvae immediately post-hatching had a total length of 6.43~6.67 (6.55±0.07) mm (n=30), and were characterized by the retention of a yolk sac and an incompletely open mouth and anus, consistent with the yolk. On the 9 days post-hatching, the postflexion larvae had grown to length of between 11.0~13.8 (12.3±0.70) mm (n=30), and the caudal bone at the tip of the tail was bent upwards at an angle of 45°, thereby indicating the transition to the late larval growth stage. On the 16 days post-hatching, the total length of juvenile had increased to between 15.8~18.2 (16.8±0.77) mm (n=30), and the number of fins reached a fixed number of 8 dorsal, 17 anal, and 8 pelvic fins. On the basis of the findings of this study, we were able to confirm differences in the size of hatching larvae and fin mottle patterns in the early life history of related species.

• Proceedings of the Membrane Society of Korea Conference
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• 1999.07a
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• pp.39-42
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• 1999

Perfluoropolymers represent the ultimate resistance to hostile chemical environments and high service temperature, attributed to the presence of fluorine in the polymer backbone, i.e. to the high bond energy of C-F and C-C bonds of fluorocarbons. Copolymers of Tetrafluoroethylene (TEE) and 2, 2, 4Trifluoro-5Trifluorometoxy- 1, 3Dioxole (TTD), commercially known as HYFLON AD, are amorphous perfluoropolymers with glass transition temperature (Tg)higher than room temperature, showing a thermal decomposition temperature exceeding 40$0^{\circ}C$. These polymer systems are highly soluble in fluorinated solvents, with low solution viscosities. This property allows the preparation of self-supported and composite membranes with desired membrane thickness. Symmetric and asymmetric perfluoropolymer membranes, made with HYFLON AD, have been prepared and evaluated. Porous and not porous symmetric membranes have been obtained by solvent evaporation with various processing conditions. Asymmetric membranes have been prepared by th wet phase inversion method. Measure of contact angle to distilled water have been carried out. Figure 1 compares experimental results with those of other commercial membranes. Contact angles of about 120$^{\circ}$for our amorphous perfluoropolymer membranes demonstrate that they posses a high hydrophobic character. Measure of contact angles to hexandecane have been also carried out to evaluate the organophobic character. Rsults are reported in Figure 2. The observed strong organophobicity leads to excellent fouling resistance and inertness. Porous membranes with pore size between 30 and 80 nanometers have shown no permeation to water at pressures as high as 10 bars. However high permeation to gases, such as O2, N2 and CO2, and no selectivities were observed. Considering the porous structure of the membrane, this behavior was expected. In consideration of the above properties, possible useful uses in th field of gas- liquid separations are envisaged for these membranes. A particularly promising application is in the field of membrane contactors, equipments in which membranes are used to improve mass transfer coefficients in respect to traditional extraction and absorption processes. Gas permeation properties have been evaluated for asymmetric membranes and composite symmetric ones. Experimental permselectivity values, obtained at different pressure differences, to various single gases are reported in Tab. 1, 2 and 3. Experimental data have been compared with literature data obtained with membranes made with different amorphous perfluoropolymer systems, such as copolymers of Perfluoro2, 2dimethyl dioxole (PDD) and Tetrafluorethylene, commercialized by the Du Pont Company with the trade name of Teflon AF. An interesting linear relationship between permeability and the glass transition temperature of the polymer constituting the membrane has been observed. Results are descussed in terms of polymer chain structure, which affects the presence of voids at molecular scale and their size distribution. Molecular Dyanmics studies are in progress in order to support the understanding of these results. A modified Theodoru- Suter method provided by the Amorphous Cell module of InsightII/Discover was used to determine the chain packing. A completely amorphous polymer box of about 3.5 nm was considered. Last but not least the use of amorphous perfluoropolymer membranes appears to be ideal when separation processes have to be performed in hostile environments, i.e. high temperatures and aggressive non-aqueous media, such as chemicals and solvents. In these cases Hyflon AD membranes can exploit the outstanding resistance of perfluoropolymers.