• Progress in Superconductivity
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• 제13권3호
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• pp.178-183
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• 2012

Two $RuSr_2(EuCe)Cu_2O_z$ samples (as prepared and after $N_2$ treatment) have been investigated by thermogravimetric (TC) analysis, high-resolution x-ray powder diffraction and magnetization measurements. TG measurements which were carried out in $H_2/Ar$ atmosphere showed that the $N_2$ treatment of the as-prepared sample at $650^{\circ}C$ for 2h leads to a decrease in the oxygen content z by about 0.25. This oxygen depletion was accompanied by an increase in the magnetic transition temperature from 54.0 K to 114.9 K. This magnetic behavior is discussed in connection with the results of Rietveld analysis of the x-ray diffraction data which showed that the $N_2$ treatment resulted in both a significant increase in the rotation angle of the $RuO_6$ octahedra and a decrease in c-lattice parameter of the sample.

• 한국광물학회지
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• 제29권4호
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• pp.191-198
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• 2016

인회석 광물 군에 속하는 녹연석($Pb_{4.85}(P_{1.02}O_4)_3Cl_{1.04}$)에 대한 상온-고압 상태방정식 연구를 시행하였다. 대칭형 다이아몬드 앤빌기기를 이용하여 33.4 GPa까지 압력을 증가시키면서 각분산 X-선 회절법과 방사광을 이용하여 회절 데이터를 검출하였으며, 시료에 가해준 압력은 루비 형광파의 파장변화를 측정하여 결정하였다. 본 고압실험에서 시행한 압력의 범위 내에서 상변이는 관찰되지 않았으며, 정압상태에서 체적탄성률($K_0$)은 $K{_0}^{\prime}=13(2)$일 때 80(7) GPa로 계산되었다. 본 연구에서 결정된 상온상태에서 녹연석의 체적탄성률 신뢰도를 정규화압력 및 정규화응력변형 분석을 하여 평가하였다.

• 한국응용과학기술학회지
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• 제27권2호
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• pp.129-136
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• 2010

A series of noble poly(amide-imide)s and copoly(amide-imide)s bearing 1,2-bis(4-phenoxy)benzene units were synthesized by the direct polycondensation of 1,2-bis(4-trimellitimidophenoxy)benzene[1,2-PTPB] with a combination of commercially available aromatic diamines and diacids such as m-phenylene diamine, p-phenylene diamine(PPD), isophthalic acid and terephthalic acid(TA) in N-methyl-2-pyrrolidone(NMP) using triphenyl phosphite and pyridine as a condensing agent in the presence of dehydrating agent ($CaCl_2$). The resulting polymers had inherent viscosities in the range of 0.37~0.78 dL/g and most of them were soluble m common organic solvents including NMP, dimethylacetamide, dimethylsulfoxide, dimethylformamide, and m-cresol. Wide-angle X-ray diffractograms revealed that the copoly(amide-imide) derived from PPD with mixed acids of 1,2-BTPB and TA, showed crystalline nature, whereas all of the other polymers were found to be amorphous. The glass transition temperatures of the polymers occurred over the temperature range of $270{\sim}323^{\circ}C$ in their differential scanning calorimetry curves and their 10% weight loss temperature, determined by thermogravimetric analysis in air and nitrogen atmosphere, were in the range $465{\sim}535^{\circ}C$, $500{\sim}550^{\circ}C$, respectively, indicating their good thermal stability.

• 대한기계학회논문집B
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• 제25권10호
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• pp.1355-1364
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• 2001

Characteristics of secondary vortices is topologically investigated in the near-wake region of a circular cylinder, where the Taylor's hypothesis does nut hold. The three-dimensional flow fields in the wake-transition regime were measured by a time-resolved PIV for various planes of view. The convection velocities of the Karman and secondary vortices are evaluated from the trajectory of the vortex center. Then, saddle points are determined by applying the critical point theory. It is shown that the inclination angle of the secondary vortices agrees well with the previous experimental data. The flow fields in a moving frame of reference have several critical points and the mushroom-like structure appears in the streamline patterns of the secondary vortices. Since the distributions of fluctuating Reynolds stresses defined by triple decomposition are closely related with the existence of secondary vortices, the physical meaning of them is explained in conjunction with the vortex center and saddle point trajectories.

• 한국재료학회지
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• 제4권2호
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• pp.233-240
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• 1994

Pt/Co인공격자다층막($[Pt10.7\;{\AA}/Co2.8\;{\AA}]{\times}12$)의 자기특성 및 기록특성이 시료제작시의 조건 (sputtering gas압력, sputtering gas 종류, buffer층의 유무 및 etching)에 따라 어떻게 변화하는지를 알아보았다. Pt/Co다층막의 자기특성은 Tb-Fe-Co계 아몰퍼스재료와 거의 동등한 특성이 얻어졌으며 이다층막을 이용한 광자기디스크의 기록특성은 kerr회전각, 1.23도, 기록 power 특성, 36dB(레이저파장: 780nm)을 나타내어 Pt/Co다층막이 차세대광자기디스크용 재료로서의 실용화가능성을 보여주었다.

• 한국철도학회논문집
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• 제12권4호
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• pp.512-517
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• 2009

알루미늄합금 철도차량의 차제를 조립하기 위하여 적용하는 용접방식으로는 가스 메탈 아크용접과 가스 텅스텐 아크용접이 주로 적용되고 있다. 그러나 알루미늄합금은 강재에 비해 용접성이 불리하며, 용접결함을 제어하기 위하여 보다 엄격한 용접조건과 용접설비의 작업환경이 요구된다. 따라서 선진국을 중심으로 비 용융 고상접합 방식인 마찰교반용접(FSW)이 널리 상용화 되고 있다. 본 연구에서는 대형 중공형 알루미늄합금 차량에 적용되는 압출재 A6005 소재의 마찰교반용접 시 용접변수에 따른 용접부의 기계적 특성을 평가하고, 적용 공구에 대한 최적의 용접조건을 파악하고자 하였다.

• Bulletin of the Korean Chemical Society
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• 제29권2호
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• pp.377-380
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• 2008

Ground state structures and ring flipping transition states of eight- and seven-membered silicon containing heterocyclic compounds such as dithienodisilacyclooctatriene and oxadithienodisilacycloheptadiene derivatives, respectively have theoretically been investigated. Although the bithienylene moiety of the derivatives does not change the ground state structures, they significantly increase the ring flipping barrier by 13-17 kcal/mol in the case of the eight-membered rings (2, 3, and 4) in comparison with that of silicon containing heterocyclic compound 6, chosen as a model. The same moiety increases the flipping barrier of seven-membered ring (5) is only slightly (3.3 kcal/mol) in comparison with that of model compound 7. Hence, it has been concluded that not only the existing ring strain of eight-membered ring but also the bithienylene moiety collectively increases the ring flipping barrier so as to prevent such conformational changes explaining anomalous NMR behaviour of dithienodisilacyclooctatriene derivatives (2-4). In contrast, the effect of substituents R1 and R2 at the olefinic carbons of the eight-membered ring on the flipping barrier turned out to be mild.

• Wind and Structures
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• 제25권3호
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• pp.301-328
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• 2017

Multivariate fluctuating pressures acting on a 2:1 rectangular section (2-D) with dimensions of 9 cm by 4.5 cm has been studied using wind tunnel experiments under uniform and smooth flow condition for various angles of wind incidence. Based on the variation of mean pressure coefficient distributions along the circumference of the rectangular section with angle of wind incidence, and with the aid of skin friction coefficients, three distinct flow regimes with two transition regimes have been identified. Further, variations of mean drag and lift coefficients, Strouhal number with angles of wind incidence have been studied. The applicability of Universal Strouhal number based on vortex street similarity of wakes in bluff bodies to the 2:1 rectangular section has been studied for different angles of wind incidence. The spatio-temporal correlation features of the measured pressure data have been studied using Proper Orthogonal Decomposition (POD) technique. The contribution of individual POD modes to the aerodynamic force components, viz, drag and lift, have been studied. It has been demonstrated that individual POD modes can be associated to different physical phenomena, which contribute to the overall aerodynamic forces.

• 대한조선학회지
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• 제21권2호
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• pp.9-17
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• 1984

Laminar and turbulent boundary layers on a rotating sector and a helical blade are calculated by differential method. The estimation of three dimensional viscous flows provide quite useful informations for the design of propellers and turbo-machinery. A general method of calculation is presented in this paper. Calculated laminar boundary layer on a sector shows smooth development of flows from Blasius' solution at the leading edge to von Karman's solution of a rotating disk at the down-stream. Eddy viscosity model is adopted for the calculation of turbulent flows. Turbulent flows on a rotating blade show similar characters as laminar flows. But cross-flow angle of turbulent flows are reduced in comparison with laminar boundary layers. Effects of rotation make flow structures significantly different from two-dimensional flows. In the range of Reynolds number of model scale propellers, large portion of the blade are still in the transition region from laminar to turbulent flows. Therefore viscous flow pattern might be quite different on the blade of model propeller. The present method of calculation is to be useful for the research of scale effects, cavitation, and roughness effects of propeller blades.

• Journal of Magnetics
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• 제14권3호
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• pp.117-119
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• 2009

Polycrystalline samples of LaFe$O_3$-BaTi$O_3$ were synthesized to examine the structural and magnetic behavior. X-ray diffraction confirmed that the ceramics had tetragonal symmetry with less tetragonal strain (c/a) than BaTi$O_3$. The magnetic hysteresis measured at room temperature suggested that the magnetic nature deviates from that of the parent LaFe$O_3$, which has antiferromagentic with a G-type spin structure. Improved magnetic behavior of the solid solution compound might be due to the increase in the canting angle of the spin. The presence of oxygen vacancies and fluctuating Fe valence, arising from the substitution of $Ba^{2+}$ and $Ti^{4+}$ at the A- and B-sites of the lattice, might contribute to bulk magnetization. The temperature dependent magnetization indicated that magnetization was higher at low temperatures and showed a decreasing trend with increasing temperature to room temperature. The magnetic transition temperature of these samples was 665 K and 743 K for the mixed system and LaFe$O_3$, respectively.