• Title/Summary/Keyword: Transition Structure

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Overhead Rigid Conductor and Transition Structure for High-Speed (Over 250 km/h) I : Structural Design (250 km/h급 고속용 강체전차선 및 이행장치 I : 구조설계)

  • Kim, Bong-Suk;Won, Yong-Hee;Park, Seol-Hee;Bae, Sang-Joon;Jang, Kwang-Dong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.1
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    • pp.7-13
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    • 2016
  • With the increasing running speed of trains, new railway lines in metropolitan areas, and the rising demand for green transportations, the number of underground and tunnel sections are constantly becoming larger, and installations of overhead rigid conductor systems are becoming wider. However, domestic commercial products for overhead rigid conductors are limited to 120 km/h train speeds. In this study, to develop a high-speed (250 km/h) overhead rigid conductor, R-Bar (Rigid Bar), the electrical and mechanical stability was enhanced through the improvement of the cross sectional shape of the R-Bar; the transition structure was also designed for flexibility and natural frequency isolation. In addition, the evaluation of contact forces between a pantograph and the overhead rigid conductor system for 250 km/h train speeds was performed using dynamic analysis.

Structure and Properties of Polynorbornene Derivatives: Poly(norbornene dicarboxylic acid dialkyl ester)s and Poly(norbornene dimethyl dicarboxylate)s

  • Shin, Boo-Gyo;Cho, Tai-Yon;Yoon, Do-Y.;Liu, Binyuan
    • Macromolecular Research
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    • v.15 no.2
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    • pp.185-190
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    • 2007
  • Poly(norbornene dimethyl dicarboxylate)s, (PNDMD)s, were prepared by addition polymerization with palladium(II) catalyst from pure exo-monomers, and their structure and properties were compared with those of poly(norbornene dicarboxylic acid dialkyl ester)s, (PNDADA)s. Both polymer series exhibited good solubility in general organic solvents and excellent thermal stability up to $330^{\circ}C$. Wide-angle X-ray scattering (WAXS) study indicated the presence of nano-scale layer-like order in amorphous PNDADAs, while PNDMDs showed random amorphous structure. The glass transition temperatures and dielectric constants of solid polymers were found to decrease as the alkyl side-chain length increases for both polymer series. However, PNDMDs showed lower glass transition temperatures and higher dielectric constants, as compared with those of PNDADAs containing the same alkyl substituents. This difference, caused by the higher side-group mobility of PNDMDs, may be closely related to the nano-scale order in amorphous PNDADAs and its absence in PNDMDs.

A Study on the Transition of Spatial Structure in Libraries with Special Reference to Rhizome and Hypertext (리좀과 하이퍼텍스트 관점에서 본 도서관 공간구조의 이해)

  • Choi, Yoon-Kyung;Kim, Min-Jung
    • Korean Institute of Interior Design Journal
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    • v.15 no.6 s.59
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    • pp.111-119
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    • 2006
  • The spatial property of contemporary library is now rapidly changing through the spatial expansion of knowledge and information, the reduction of information storing facility, the variation of approaching methods by digital shift and the transition of social recognition as a cultural facility. Also the spatial characteristics with referring characters have developed such as, decentralization, de-construction, de-boundary, individual space, erasing of boundary, flow of space which extends infinitely. The main process of library origination, the systematic classification, and the storage system concluding with the demand and value of the information by changing social demands and the role of the widest ranged facility. And 5 themes, such as, hierarchy, center, storage, boundary, and symbol, as a changed spatial concept and analyzed in the case of library plans and libraries which are actually built. The significant purpose of this research is to propose that rhizomatous intellectuality and hypertext could be a theoretical background of the contemporary architecture and could be a viewpoint of the transition of spatial structure in libraries. A future library should have spatial property embracing various social changes and needs and for this respect, it is necessary to approach and analyze through the architectural explication from diverging points of view.

Study of Order-Disorder Phase Transition of $(Fe_{0.61}Ni_{0.39})_3V$V Alloy by Neutron Diffraction Method (중성자회절법을 이용한 $(Fe_{0.61}Ni_{0.39})_3V$ 합금의 규칙- 불규칙 상전이 연구)

  • 이정수;이창희
    • Korean Journal of Crystallography
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    • v.13 no.1
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    • pp.36-40
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    • 2002
  • The order-disorder phase transition of (Fe/sub 0.61/Ni/sub 0.39/)₃V alloy that is annealed at various temperatures and time conditions was sty(lied with the examination of long-range order parameter(S) by using neutron diffraction method. As a result, the structure of the sample annealed at 680℃ for 94 h was not changed; that is, it existed iii perfect disordered state and showed face-centered cubic structure. Otherwise, samples which were annealed at temperature below 640℃ showed the value of long-range order parameter with 0 < S < 1 and phase transition into simple cubic structure partly. It was found that the annealed sample at 465℃ for 144 h is the most approximated to the thermal equilibrium state from the S-T/T/sub c/ related equation of Cowley.

Phase Transition adn Crystal Structure Analysis Using Rietveld Method in the $(Na_{0.3}Sr_{0.7})(Ti_{0.7}M_{0.3})O_3 (M=Ta, Nb)$ System (Rietveld 법을 이용한 $(Na_{0.3}Sr_{0.7})(Ti_{0.7}M_{0.3})O_3 (M=Ta, Nb)$ 계에서의 결정구조 해석과 상전이 특성)

  • 정훈택;김호기
    • Journal of the Korean Ceramic Society
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    • v.32 no.5
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    • pp.582-586
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    • 1995
  • The crystal structures of (Na0.3Sr0.7)(Ti0.7M0.3)O3 (M=Ta, Nb) compounds were determined using the Rietveld method. Due to the tilting of a oxygen octahedron, (Na0.3Sr0.7)(Ti0.7Nb0.3)O3 had a superlattice of doubled a, b and c of simple perovskite. The crystal structure of (Na0.3Sr0.7)(Ti0.7M0.3)O3 was tetragonal with a space group 14/mmm. The crystal structure of (Na0.3Sr0.7)(Ti0.7M0.3)O3 was a cubic with space group Pm3m, in which no tilting of oxygen octahedron was observed. The difference in the oxygen tilting of these two materials was due to the larger covalency of Nb-O bond than that of Ta-O bond, which induced a strong $\pi$Nb0 bonding in (Na0.3Sr0.7)(Ti0.7M0.3)O3. Therefore, the higher transition temperature of (Na0.3Sr0.7)(Ti0.7M0.3)O3 could be related to the larger tilting of oxygen octahedron.

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Double Transition and Magnetic Phase Transition : An Electron Fluid Condensation Model for Superconductivity (이중 전이와 자화 상전이 : 초전도성에 대한 전자 유체의 응축 모델)

  • Park, Sung-Hoon;Choi, Dong-Seek;Shin, Doo-Soon;Kim, Won-Soo
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.599-606
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    • 1998
  • Since the discovery of ceramic superconductor the various theoretical developments has progressed but there are no definitive description about the superconducting transition mechanism. In special, both the double transition and the various magnetic phase transition add to the complication of the understanding of HTSC. In this paper, we presented the idea of the two-step mechanism for the superconducting transition in view of the condensation model of electron fluid for superconductivity. And these concepts are successfully applied to the double transition and the magnetic phase diagram of various types of superconductivity. Therefore, both the double transition and magnetic phase transition should be the touchstone of general theory for superconductivity.

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TCC behavior of a shell phase in core/shell structure formed in Y-doped BaTiO3: an individual observation (Yttrium이 첨가된 BaTiO3에서 형성된 core/shell 구조에서 shell의 TCC 거동: 독립적 관찰)

  • Jeon, Sang-Chae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.3
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    • pp.110-116
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    • 2020
  • Grains in the BaTiO3, which is used for a dielectric layer in MLCC(Multi-Layer Ceramic Capacitor) are necessary to form core/shell structure for a stable TCC(Temperature Coefficient of Capacitance) behavior. The shell property has been deduced from the whole TCC behavior of core/shell structure due to its tiny size, ~ few ㎛. This study demonstrates the individual TCC behavior of the shell phase measured by micro-contact measurement in a temperature range between 35 and 135℃. Pt electrode pairs deposited on an enlarged core/shell structure in a diffusion couple sample made the measurement possible. As a result, the DPT (Diffusion Phase Transition) behavior of the shell phase was revealed as a different TCC behavior from that of the core: a broad peak with Tm at 65℃. This would be also useful experimental data for a modelling that depicts dielectric-temperature behavior of core/shell structure.

Fabrication, temperature-dependent local structural and electrical properties of VO2 thin films

  • Jin, Zhenlan;Hwang, In-Hui;Park, Chang-In;Han, Sang-Wook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.169.2-169.2
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    • 2015
  • $VO_2$ is a well-known a metal-to-insulator-transition (MIT) material, accompanied with a first order structural phase transition near room temperature. Because of the structural phase transition and the MIT occur near a same temperature, there is an ongoing argument whether the MIT is induced by the structural phase transition. $VO_2$ exhibits a relatively weak anti-oxidization ability and can be oxidized to higher-valence oxides (e.g., $V_4$ $O_7$ or $V_2$ $O_5$) when annealed at a high temperature in an oxygen-rich atmosphere. We fabricated $VO_2$ films on $Al_2$ $O_3$ (0001) substrates using a DC magnetron sputtering deposition process with carefully control the $O_2$ percentage in an atmosphere. X-ray diffraction measurements from the films showed only (0l0) peaks with no extra peaks, indicating b-oriented films. The temperature-dependent local structural properties of $VO_2$ films were investigated by using in-situ X-ray absorption fine structure (XAFS) measurements at the V K edge. XAFS revealed that the structural phase transition was occurred nearly $70^{\circ}C$ for heating process and reproducible. Resistance measurements as a function of temperature (R-T) demonstrated that the resistance of $VO_2$ films was changed by a factor of 4 near $75^{\circ}C$ which was higher than $68^{\circ}C$ reported from a $VO_2$ bulk. We will discuss the MIT of $VO_2$ films, comparing with the local structural properties determined by XAFS measurements.

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About the Influence of the Molecular Structure of selected classes of small molecules on their thermal behavior

  • Richter, Andreas M.;Lischewski, Volker;Felicetti, M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.812-815
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    • 2004
  • The molecular structure influences the thermal behavior of HTM. For OLED the glass transition temperature and evaporation temperature are critical. We report how changes in structure cause changes on both parameters. The results may be of interest for chemists when they design new molecule structures for OLED.

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Ultra-Wideband Microstrip-to-Finite Ground Coplanar Waveguide Transition for Millimeter-Wave Systems (밀리미터파 시스템용 초광대역 마이크로스트립-FGCPW 전이구조 설계)

  • Kim, Young-Gon;Kim, Hong-Rak;Jung, Bae-Ho;Kim, Kang Wook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.8
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    • pp.701-708
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    • 2016
  • A new design for an ultra-wideband microstrip-to-FGCPW(Finite Ground Coplanar Waveguide) transition is presented. The proposed transition provides the electric field and impedance matching between adjacent transmission lines by ground shaping. The transition is designed on the analytical expressions of whole transitional structure. Conformal mapping is applied to obtain the characteristic impedance of FGCPW with bottom aperture within 3.3 % accuracy as compared with the EM-simulation results. As design example, the fabricated transition in back-to-back configuration provides insertion loss less than 1 dB per transition and return loss better than 10 dB for frequencies from 9 GHz to over 40 GHz.