• Bulletin of the Korean Chemical Society
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• 제12권5호
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• pp.569-574
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• 1991

Methyl red diffusion in polymer solutions was studied by a transient holographic method, forced Rayleigh scattering. In semi-dilute solutions of a polystyrene, where no specific interaction with the probe exists, we found within experimental uncertainty that the retardation of diffusion rate of methyl red is independent of the solvents used. This indicates that the hydrodynamic interaction in polymer coils is not affected by the nature of solvents enough to exhibit a detectable change in the diffusion rate of the probe. On the other hand, a substantial reduction of diffusion rate was observed in poly(methyl methacrylate) solutions in toluene. Together with the similar observation reported with poly(vinyl acetate), it is confirmed that hydrogen bond between the probe and the polymer is responsible for the retarded diffusion. The decay-growth-decay profile found in this system reveals a finite difference in diffusion coefficients of cis and trans isomer of methyl red. We estimate the difference and suggest that the cis isomer interacts with the polymer more strongly than the trans isomer.

• 한국재료학회지
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• 제29권9호
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• pp.547-552
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• 2019

In the present study, the thermal conductivity of a silicon nitride($Si_3N_4$) thin-film is evaluated using the dual-wavelength pump-probe technique. A 100-nm thick $Si_3N_4$ film is deposited on a silicon (100) wafer using the radio frequency plasma enhanced chemical vapor deposition technique and film structural characteristics are observed using the X-ray reflectivity technique. The film's thermal conductivity is measured using a pump-probe setup powered by a femtosecond laser system of which pump-beam wavelength is frequency-doubled using a beta barium borate crystal. A multilayer transient heat conduction equation is numerically solved to quantify the film property. A finite difference method based on the Crank-Nicolson scheme is employed for the computation so that the experimental data can be curve-fitted. Results show that the thermal conductivity value of the film is lower than that of its bulk status by an order of magnitude. This investigation offers an effective way to evaluate thermophysical properties of nanoscale ceramic and dielectric materials with high temporal and spatial resolutions.

• 한국지반공학회논문집
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• 제27권7호
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• pp.17-33
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• 2011

천연 골재자원의 고갈로 인해 송배전관로 되메움재의 대체골재로서 재생 순환골재 이용에 많은 관심이 집중되고 있다. 그러나 순환골재를 송매전관로 메움재로 적용하기 위해서는 물리적, 열적 특성 규명이 선행되어야 한다. 본 논문에서는 송배전관보 되메움재로 활용하기 위한 폐콘크리트 순환골재의 적용성을 평가하였다. 각 지역에서 채취한 순환골재와 대조군인 일반 강모래를 대상으로 실내다짐시험을 수행한 후, 비정상 열선법과 비정상 탐침법을 이용하여 열저항을 측정하였다. 저함수비 구간에서 비정상 탐침법을 이용한 열저항 측정값은 탐침관입에 따른 시료교란 효과로 인해 비정상 열선법보다 상대적으로 크게 측정되었다. 전체 순환골재의 열저항 측정 결과, 대조군인 강모래와 유사하게 함수비 증가에 따른 열저항의 감소를 보였다. 또한, 기존 열전도도(열저항) 예측 모델에 의한 열저항 예측값과 순환골재의 측정 결과를 비교하였으며, 순환골재에 열저항 예측에 적합한 예측식을 제안하였다. 본 연구결과를 바탕으로 재생 순환골재를 송배전판로 되메움재로 활용 가능함을 알 수 있다.

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3391-3396
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• 2012

Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

• 설비공학논문집
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• 제20권9호
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• pp.614-623
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• 2008

This paper presents the results of a laboratory study on the thermal conductivity of and(silica, quartzite, limestone, sandstone, granite and two masonry sands)-water mixtures used for ground heat exchanger backfilling materials. Nearly 260 tests were performed in a thermal conductivity measuring system to characterize the relationships between the thermal conductivity of mixtures and the water content. The experimental results show hat the thermal conductivity of mixtures increases with increasing dry density and with increasing water content. The most widely used empirical prediction models for thermal conductivity of soils were found inappropriate to estimate the thermal conductivity of unsaturated sand-water mixtures. An improved model using an exponential relationship to compute the thermal conductivity of dry sands and empirical relationship to assess the normalized thermal conductivity of unsaturated sand-water mixtures is presented.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.761-768
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• 2008

This paper presents the results of a laboratory study on the thermal conductivity of sand(silica, quartzite, limestone, sandstone, granite and masonry sand)-water mixtures used in ground heat exchanger backfilling materials. Nearly 260 tests were performed in a thermal conductivity measuring system to characterize the relationships between the thermal conductivity of mixtures and the water content. The experimental results show that the thermal conductivity of mixtures increases with increasing dry density and with increasing water content. The most widely used empirical prediction models for thermal conductivity of soils were found inappropriate to estimate the thermal conductivity of unsaturated sand-water mixtures. An improved model using a exponential relationship to compute the thermal conductivity of dry sands and empirical relationship to assess the normalized thermal conductivity of unsaturated sand-water mixtures is presented.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
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• pp.98-101
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• 2002

The switching-mode power converter has been widely used because of its features of high efficiency and small weight and size. These features are brought by the ON-OFF operation of semiconductor switching devices. However, this switching operation causes the surge and EMI(Electromagnetic Interference) which deteriorate the reliability of the converter themselves and entire electronic systems. This problem on the surge and noise is one of the most serious difficulties in AC-to-DC converter. In the case of carrier frequency selection, output-voltage of steady state and transient state is fully regulated. A RPWM control method was proposed in order to smooth the switching noise spectrum and reduce it's level. Experimental results are verified by converter operating at 300V/1kW with 5%${\sim}$30% white noise input. Spectrum analysis is performed on the Phase current and the CM noise voltage. The former is measured with Current Probe and the latter is achieved with USN. which are connected to the spectrum analyzer respectively.

• 설비공학논문집
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• 제20권5호
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• pp.342-350
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• 2008

This paper presents the results of a laboratory study on the thermal conductivity of sand (silica, quartzite, limestone and masonry sand)-water mixtures used in ground heat exchanger backfilling materials. Nearly 150 tests were performed in a thermal conductivity measuring system (TPSYS02) to characterize the relationships between the thermal conductivity of mixtures and the water content. The results show that the thermal conductivity of mixtures increases with increasing dry density and with increasing water content. The results also show that for constant water contents and a dry density value, the thermal conductivity of mixtures increases with increasing thermal conductivity of solid particles. The measurement results were also compared with the most widely used empirical prediction models for the thermal conductivity of soils.

• 대한기계학회논문집B
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• 제34권2호
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• pp.153-156
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• 2010

나노유체로 기공이 채워진 규사와 같은 2상 물질의 고온에서의 유효 열전도도를 비정상열침법을 사용하여 측정하였다. 본 연구의 나노유체는 물과 0.1% 체적률의 입경이 45 nm 인 알루미나 나노입자의 혼합유체이다. 본 연구의 측정방법은 액체가 모래의 미세한 기공 내에 존재하므로, 열전도도의 측정에서의 액체의 대류에 의한 문제가 적다. 본 연구의 모래에 대한 예측모델을 사용하여 나노유체와 모래입자의 2상 물질의 유효 열전도도의 측정결과로부터, 고온의 나노유체의 열전도도를 결정하였다. 실험결과, $30^{\circ}C\sim80^{\circ}C$의 온도 범위에서 순수한 물에 대한 본 연구의 나노유체의 열전도도의 증가율은 4.87% ~ 5.48% 의 범위에서 변화하는 것으로 나타났다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 학술대회 논문집 전문대학교육위원
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• pp.154-158
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• 2006

The switching-mode power converter has been widely used because of its features of high efficiency and small weight and size. These features are brought by the ON-OFF operation of semiconductor switching devices. However, this switching operation causes the surge and EMI(Electromagnetic Interference) which deteriorate the reliability of the converter themselves and entire electronic systems. This problem on the surge and noise is one of the most serious difficulties in AC-to-DC converter. Random Pulse Width Modulation (RPWM) is peformed by adding a random perturbation to switching instant while output-voltage regulation of converter is performed. RPWM method for reducing conducted EMI in single switch three phase discontinuous conduction mode boost converter is presented. The more white noise is injected, the more conducted EMI is reduced. But output-voltage is not sufficiently regulated. This is the reason why carrier frequency selection topology is proposed. In the case of carrier frequency selection, output-voltage of steady state and transient state is fully regulated. A RPWM control method was proposed in order to smooth the switching noise spectrum and reduce it's level. Experimental results are verified by converter operating at 300v/1kW with $5%{\sim}30%$ white noise input. Spectrum analysis is performed on the Phase current and the CM noise voltage. The former is measured with Current Probe and the latter is achieved with LISN, which are connected to the spectrum analyzer respectively.