• Journal of the Korean Ceramic Society
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• v.20 no.1
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• pp.63-69
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• 1983

It is know that $Si_3-N_4$ bonded SiC has almost all the valuable properties needed for the high temperature material and thus has bery wide range of applicability. Si powder and two different sized SiC powder were used as the raw mateials. Specimens were prepared by heating the green compact mode of the raw materials with polyvinyl alcohol binder in the nitrogen atmosphere. The bond-ing of SiC particles is brought about with the formation of reaction bonded silicon nitride phase between the particles he influences of the variation of the relative amounts of the raw materials and the amount of the organic binder on the density and the bend strength of the specimens were investigated. It was shown that the calculation of the amount of the nitridation of Si is somewhat complicated matter since some portion of the organic binder reacts with the Si during the firing process. Fixing the Si amount to 20w/o the distributions of the size of the SiC particles that gives the maximum density and the maximum strnegth were obtained through experiments. It was observed that the two distributions were not equal to each other. As the amount of Si increased the amount of Si reacted with nitrogen and the strength increased. The fracture mode was intergranular for the most part and the transgranular fracture was scarcely observed.

• Journal of the Korean Ceramic Society
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• v.44 no.7
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• pp.343-348
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• 2007

Alumina/silver nanocomposites were fabricated using a soaking method through a sol-gel route to construct an intra-type nanostructure. The pulse electric-current sintering (PECS) technique was used to sinter the nanocomposites. Several specimens were annealed after sintering. The microstructure, mechanical properties, critical frontal process zone (FPZ) size, and thermo-mechanical properties of the nanocomposites were estimated. The relative densities of the specimens sintered at 1350 and $1450^{\circ}C$ were 95% and 99%, respectively. The maximum value of the three-point bending strength was found to be 780 MPa for the $2{\times}2{\times}10 mm$ specimen sintered at $1350^{\circ}C$. The fracture toughness of the specimen sintered at $1350^{\circ}C$ was measured to be $3.60 MPa{\cdot}m^{1/2}$ using the single-edge V-notched beam (SEVNB) technique. The fracture mode of the nanocomposites was transgranular, in contrast to the intergranular mode of monolithic alumina. The fracture morphology suggested that dislocations were generated around the silver nanoparticles dispersed within the alumina matrix. The specimens sintered at $1350^{\circ}C$ were annealed at $800^{\circ}C$ for 5 min, following which the maximum fracture strength became 810 MPa and the fracture toughness improved to $4.21 MPam^{1/2}$. The critical FPZ size was the largest for the specimen annealed at $800^{\circ}C$ for 5 min. Thermal conductivity of the alumina/silver nanocomposites sintered at $1350^{\circ}C$ was 38 W/mK at room temperature, which was higher than the value obtained with the law of mixture.

• Journal of the Korean Ceramic Society
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• v.27 no.1
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• pp.55-61
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• 1990

Effect of Al2O3 addition on the mechanical properties and microstructure of Ce-TZP were studied. 12, 14, 16Ce-TZP containing 0-40wt% Al2O3 were prepared by sintering at 155$0^{\circ}C$ for 2h. in air. Density, linear shrinkage, bending strength, Vickers hardness, microstructuer and the amount of stress induced phase transformation were examined. Vickers hardness increased linearly with increasing amounts of Al2O3. The amount of transformation and fracture toughness decreased linearly with increasing amount of Al2O3. Linear shrinkage and relative density decreased with increasing Al2O3 content in all composition of Ce-TZP. Grain growth of Ce-TZP was inhibited by Al2O3 dispersion and fracture mode of Ce-TZP/Al2O3 composites transformed from intergranular to transgranular fracture as the amount of Al2O3 increased. TEM observation revealed that Al2O3 particles were located mainly at grain boundaries of ZrO2.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.2 s.173
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• pp.303-310
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• 2000

Fracture toughness of five different reactor pressure vessel steels was characterized in the transition temperature region by the ASTM E1921-97 standard method using Charpy-sized small specimens. T he predominant fracture mode of the tested steels was transgranular cleavage in the test conditions. A statistical analysis based on the Weibull distribution was applied to the interpretation of the scattered fracture toughness data. The size-dependence of the measured fracture toughness values was also well predicted by means of the Weibull probabilistic analysis. The measured fracture toughness transition curves followed the temperature-dependence of the ASTM master curve within the expected scatter bands. Therefore, the fracture toughness characteristics in the transition region could be described by a single parameter, so-called the reference temperature (T。), for a given steel. The determined reference temperatures of the tested materials could not be correlated with the conventional index temperatures from Charpy impact tests.

• Korean Journal of Materials Research
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• v.14 no.12
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• pp.863-869
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• 2004

The purpose of this research is to investigate the mechanical property and ductile-brittle transition temperature of Ti-Nb-P added extra low carbon interstitial free steel having a tensile strength of 440 MPa. The mechanical property and transition temperature of hot rolled steel sheets were more influenced by the coiling temperature rather than by the small amount of alloying element. Further, at the same composition, the property of the specimen coiled at low temperature was superior to that obtained at higher coiling temperature. The fracture surface of 0.005C-0.2Si-1.43Mn steel coiled at $630^{\circ}C$ showed a ductile fracture mode at $-100^{\circ}C$, but coiling at $670^{\circ}C$ showed a transgranular brittle fracture mode at $-90^{\circ}C$. The galvannealed 0.006C-0.07Si-1.33Mn steel sheet annealed at $810^{\circ}C$ has tensile strength and elongation of 442.8 MPa and $36.6\%$, respectively. The transition temperature of galvannealed 0.006C-0.07Si-1.33Mn steel sheet was increased with a drawing ratio, and the transition temperature of the galvannealed 0.006C-0.07Si-1.33Mn steel was $-60^{\circ}C$ at a drawing ratio of 1.8

• Korean Journal of Materials Research
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• v.18 no.4
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• pp.181-186
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• 2008

In this study, tantalum (Ta) compacts were fabricated in a spark plasma sintering (SPS) process and their microstructure and mechanical properties were investigated. Ta compacts with a density of 99% were successfully fabricated by controlling the sintering conditions of the current and the temperature. The density and hardness were increased as the sintering temperature increased. The $Ta_2C$ compound was observed at the surface of the compacts due to the contact between the Ta powder and graphite mold during the sintering process. The main fracture mode showed a mixed type with intergranular and transgranular modes having some roughness.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.3
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• pp.548-554
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• 1994

The high temperature fatigue crack growth behavior of SUS 304 stainless steel at $550^{\circ}C$ and $650^{\circ}C$ was investigated under various kinds of stress ratio and frequency in sinusoidal waveform on the basis of the non-linear fracture mechanics. The result arranging crack growth rate by modified J-integral J' showed influence of stress ratio and frequency. All the data obtained under the test at $550^{\circ}C$ were plotted within data band of da/dN-${\triangle}J_f$ relationship for cycle-dependent crack growth. On the basis of static creep and cycle-dependent data band; both time- and cycle-dependent crack growth behavior was observed under loading conditions at $650^{\circ}C$, but cycle-dependent crack growth behavior predominantly appeared and time-dependent crack growth behaviour was little observed under loading conditions at $550^{\circ}C$. Fractographic examinations for fracture surface indicated that the fracture mode was generally transgranular. The stripes were found on fracture surface and each stripe was accompanied by a crack tip blunting and an abrupt increase in the load-point displacement. The $J'_{an}$ had a validity in case of $650^{\circ}C, but scarcely had it in case of $550^{\circ}C$.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.223-230
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• 2001

The Monkman-Grant (M-G) and its modified parameters were estimated for modified type 316LN and $9{\sim}12Cr-1Mo$ steels with chemical variations. Several sets of creep data were obtained by constant-load creep tests in $550-650^{\circ}C$ ranges. The relation parameters, m, $m^*$, C and $C^*$ were proposed and discussed for two alloy systems. In creep fracture mode, type 316LN steel showed domination of the intergranular fracture caused by growth and coalescence of cavities. On the other hand, the Cr-Mo steel showed transgranular fracture of the ductile type caused from softening at high temperature. In spite of the basic differences in creep fracture modes as well as creep properties, the M-G and its modified relations demonstrated linearity within the $2{\sigma}$ standard deviation. The value of the m parameter of the M-G relation was 0.90 in the 316LN steel and 0.84 in the Cr-Mo steel. The value of the $m^*$ parameter of the modified relation was 0.94 in the 316LN steel and 0.89 in Cr-Mo steel. The modified relation was superior to the M-G relation because the $m^*$ slopes almost overlapped regardless of creep testing conditions and chemical variations to the two alloy systems.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.4
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• pp.1123-1132
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• 1996

It has been reported that high temperature structural components represent the phenomenon of material degradation according to a long term service under high temperature and pressure. Especially, fossile power plant components using the fossil fuel and heavy oil are affected by dewpoint corrosion of $H_2SO_4$produced during a combustion. Therefore, the service materials subjected to high temperature and pressure may occur the stress corrosion cracking. The object of this paper is to investigate SCC susceptibility according to the material degradation of the high temperature structural materials in dewpoint corrosive environment-$H_2SO_4$.The obtained results are summarized as follows : 1) In case of secondary superheater tube, the fractograph of dimple is observed at the concentration of $H_2SO_4$-5%. When the concentration of $H_2SO_4$ is above 10%, the fracture mode is shifted from a transgranular fracture to an quasi-intergranular fracture according to the increment of concentration. 2) In the relationship between [$\Delta$DBTT]$_sp$ and SCC susceptibility, it is confirmed that the greater material degradation degree is, the higher SCC susceptibility is. In addition, it can be known that SP test is useful test method to evaluate SCC susceptibility for high temperature structural components. 3) When [$\Delta$DBTT]$_sp$ is above 17$17^{\circ}C$ the SCC fracture behavior is definitely observed with SCC susceptibility of above 0.4.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.2
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• pp.122-127
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• 2000

Microstructural evolutions in ceria-stabilized zirconia (Ce-TZP) and alumina-dispersed Ce-TZP ceramics were investigated as functions of doping and annealing conditions. All of sintered specimens showed the relative density over 99 %. Sintered specimens had linear grain boundaries and normal grain shapes, but ceria-doped specimens had irregular grain shapes and nonlinear grain boundaries due to the diffusion-induced grain boundary migration during annealing at $1650^{\circ}C$ for 2 h. Mean grain boundary length of Ce-TZP with irregular grain shapes was higher than that of normal grain shapes, and was a value of 23pm at the maximum. Alumina particles dispersed in Ce-TZP inhibited the grain growth of zirconia particles. $Al_2O_3$Ce-TZP doped with ceria and annealed at $1650^{\circ}C$ for 2 h showed irregular grain shapes as well as small grain size. Added alumina particles showed the grain growth during sintering or annealing, and they changed the position from grain boundary to inside of the grains during the annealing. The specimens with normal grain shapes showed an intergranular fracture mode, whereas the specimens with irregular grain shapes showed a transgranular fracture mode during the crack propagation.