• 제목/요약/키워드: Transfer adhesive

검색결과 70건 처리시간 0.023초

Temperature-dependent studies on catalytic hydrosilation of polyalkylsiloxane using NMR

  • Sul, Hyewon;Lee, Tae Hee;Lim, Eunsoo;Rho, Yecheol;Kim, Chong-Hyeak;Kim, Jeongkwon
    • 분석과학
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    • 제30권4호
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    • pp.213-219
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    • 2017
  • Polyalkylsiloxane has been spotlighted in pressure-sensitive adhesive (PSA) application due to excellent physical properties and good biocompatibility. Thermal behaviour of polyalkylsiloxane mixtures, such as thermal stability and heat flow, were studied using TG-DTA during catalytic hydrosilation. To understand reaction kinetics of cross-linking, catalytic hydrosilation of polyalkylsiloxane was monitored using variable temperature nuclear magnetic resonance (VT-NMR) as increased temperature. The formation of cross-linking bond $Si-CH_2-CH_2-Si$ was directly observed using distortionless enhanced by polarization transfer (DEPT) technique. Successfully polyalkylsiloxane PSA samples exhibited excellent adhesion properties by cross-linking reaction.

INDIRECT BONDING TECHNIQUE에 대한 고찰 (CLINICAL CONSIDERATION OF INDIRECT BONDING TECHNIQUE)

  • 이경환;김상철
    • 대한치과교정학회지
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    • 제19권2호
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    • pp.155-163
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    • 1989
  • Indirect bonding is done by placing the brackets on a model in the laboratory and using a template or tray to transfer the laboratory positioning to the teeth. The advantages of this technique are 1. decreased chair time 2. less patient discomfort 3. accuracy of a attachment placement 4. good adaptation of attachment to tooth contour 5. occlusal relationship of brackets and opposing teeth can be checked The disadvantages of the technique are 1. complex laboratory procedure 2. sometimes difficult on very short clinical crowns 3. teeth with crowns, large buccal restoration will not bond 4. may not be fitted close, if poor adaptation 5. likely to be disturbed setting Several indirect bonding techniques have proved reliable in clinical practice. However, they differ in the way the brackets are attached temporarily to the model, the type of transfer tray or other mechanism used, the adhesive or sealant employed, whether segmented or full bonding used, and the way the transfer is removed so as not to exert excessive force on a still maturing bond.

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표면부착된 분포형 광섬유 센서의 유한요소해석 (FEM Analysis of Distributed Optical Fiber Sensors for the Strain Transfer)

  • 김상훈;이정주;권일범;허증수
    • 센서학회지
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    • 제10권1호
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    • pp.16-23
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    • 2001
  • 국부적인 측정을 수행하는 일반적인 광섬유 센서에 비해 분포형 광섬유 센서는 광섬유의 길이방향을 따라 모든 위치에서 측정이 가능하며 보다 넓은 영역의 측정을 수행할 수 있다. 브릴루인 산란 분포형 광섬유 센서를 구조물의 건전성 감시에 이용할 때에는 광섬유 센서의 일반적인 부착 방법인 에폭시를 이용한 표면부착 방법을 사용하게 된다. 본 논문에서는 에폭시를 이용하여 브릴루인 분포형 광섬유 센서를 구조물의 표면에 부착하였을 때 구조물의 변형률 변화를 광섬유 센서가 정확히 측정해 낼 수 있는지에 대해 유한요소법을 통한 검증을 수행하였다. 구조물로부터 에폭시, 광섬유 코팅, 클래딩을 통해 코어로 전달되는 변형률의 전달률을 해석을 통해 확인하였으며 변형률 분포로부터 에폭시 끝 단의 자유 경계면이 미치는 영향을 살펴보았다.

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식품연포장용 라미네이트 수성 감압점착제의 친환경적 적용에 대한 연구 (Design and Properties of Laminating Waterborne PSA for Eco-friendly Flexible Food Packaging)

  • 이진경;심명식;진인주
    • 접착 및 계면
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    • 제17권2호
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    • pp.49-55
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    • 2016
  • 본 연구는 식품연포장 적층 라미네이트에 주로 사용되는 유성접착제를 대체하기 위해 아크릴 수성화방법을 활용하여 친환경적인 수성 점착제를 설계하였다. 방법으로는 음이온/비이온 그리고 인산에스테르 계면활성제들의 조합과 분자량조절제(chain transfer agent, CTA)의 양을 달리하고, 기능성단량체(functional monomer)의 종류를 달리하였다. 합성된 점착제의 가교 정도와 분자량의 영향을 각각 실험군 8종으로 점착제를 설계 합성하고 조사하였다. 그리고 별도로 분자량이 서로 다른 styrene/alpha-methyl styrene/acrylic acid (SAA) semipolymer 분산제(Mw = 13,000과 Mw = 8,600)를 기존의 계면활성제를 대신하여 사용해 감압점착제(Pressure Sensitive Adhesive, PSA)의 물성을 조사하였다. 합성된 10종의 감압점착제가 유연포장용 기본 물성 규격에 적합한지를 DSC, 입자크기, adhesion, 분자량의 물성 분석으로 평가하였다. 실험 결과 계면활성제는 음이온/비이온 조합으로, CTA는 0.2%로 기능성 단량체는 HEA, GMA를 사용한 점착제 2개의 실험군에서 유연포장에 적용 가능한 분자량과 유연성, 낮은 접착력, 작은 입자의 물성을 확인하였다.

섬유금속적층판 연결접합 부위의 하중전달 거동 연구 (Load Transfer Behaviors near the Spliced Joint of the Fiber Metal Laminates)

  • 최흥섭;노희석;장용훈
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1388-1393
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    • 2003
  • In this study, analytic stress-displacement solutions are obtained by using a shear lag modeling constructed for the spliced joint area with a splicing gap filled with adhesive material of elastic modulus $E_{a}$ in the fiber metal laminate (FML) which is known to have excellent fatigue, corrosion and fire-flame resistant characteristics while with relatively low densities compared to the conventional aluminum alloys for lightweight structures.

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연결이음 접합된 섬유금속적층판의 하중전달 거동 연구 (Load Transfer Behaviors of the Splice-Jointed Fiber Metal Laminates)

  • 노희석;최원종;하민수;최흥섭
    • 대한기계학회논문집A
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    • 제29권2호
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    • pp.220-227
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    • 2005
  • In this study, stress-displacement analytic solutions are obtained by a shear lag modeling method constructed for the spliced joint area with a splicing gap in the fiber metal laminate (FML). This gap can be empty or be filled with an adhesive material of elastic modulus $E_a$. Two splicing types are considered for spliced shear models, one for spliced in the center metal layer, the other for spliced in the outer metal layer. It is shown that from the viewpoint of the load transfer efficiency and the avoidability of disbond generation due to the shear and axial stresses at the interface between metal layer and composite layer of the gap-front in the spliced area, the center spliced type (k=2) is much preferable to the outer spliced type (k=1).

분자량 조절제의 함량에 따른 수계 아크릴 점착부여제의 합성 및 점착 특성 연구 (Study on Synthesis and Adhesion Properties of Water-based Acrylic Tackifier According to the Content of Chain Transfer Agent)

  • 백란지;정부영;김세진;허필호;천정미;천제환
    • 접착 및 계면
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    • 제23권3호
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    • pp.80-86
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    • 2022
  • 본 연구에서는 수계형 아크릴 점착제의 성능 및 점착 물성을 향상시키기 위해 분자량 조절제인 1-dodecanethiol(n-DM)의 함량이 다른 수계 아크릴 점착부여제를 합성하였으며 수계 아크릴 점착부여제의 투입량에 따른 물성 변화 확인을 위해 수분산성 아크릴 에멀젼에 수계 아크릴 점착부여제를 10/20/30 phr로 투입하여 물성을 측정하였다. 합성된 수계 아크릴 점착부여제의 분자량 및 유리전이온도(Tg)는 n-DM의 함량이 증가함에 따라 감소하는 경향을 나타내었다. 수분산성 아크릴 에멀젼에 수계 아크릴 점착부여제를 첨가하였을 때의 점착력 및 내열 유지력은 증가하였으며 수계 아크릴 점착부여제를 10 phr 또는 20 phr로 투입하였을 때에 가장 우수한 값을 나타내었다.

VPT 형광막 제조용 ITO Paste의 개발 (The Development of ITO Paste for VPT Phosphor Screen Manufacture)

  • 이미영;우진호;김영배;남수용;이상남;문명준
    • 한국인쇄학회지
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    • 제22권2호
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    • pp.73-82
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    • 2004
  • A thermal transfer method was developed novel method to form the phosphor screen for monochrom VPT. This method have advantages of simple process, clean environment, saving raw material and running-cost. But now applying phosphor screen for thermal transfer method has been formed three layers (phosphor layer, ITO layer and thermal adhesive layer) on the PET film as substrate. This is complex process, consumption of raw-material and require of high cost. Also ITO paste at present has been imported from Japan. To improve these problems, we have developed ITO paste as conductive paste by using ITO sol and binder resin (AA3003). Ito paste as developed in this study has both conductive and excellent thermal transfer abilities. Thus we could manufacture phosphor screen formed two layers (phosphor layer and ITO layer).

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완전 자동화된 단속형 가변적층쾌속조형공정을 위한 절단 경로 데이터 생성 (Generation of cutting Path Data for Fully Automated Transfer-type Variable Lamination Manufacturing Using EPS-Foam)

  • 이상호;안동규;김효찬;양동열;박두섭;심용보;채희창
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 추계학술대회 논문집
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    • pp.599-602
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    • 2002
  • A novel rapid prototyping (RP) process, an automated transfer type variable lamination manufacturing process (Automated VLM-ST) has been developed. In Automated VLM-ST, a vacuum chuck and linear moving system transfer the plate type material with two pilot holes to the rotation stage. A four-axis synchronized hotwire cutter cuts the material twice to generate Automated Unit Shape Layer (AUSL) with the desired width, side slopes, length, and two reference shapes in accordance with CAD data. Each AUSL is stacked on the stacking plate with two pilot pins using the pilot holes in AUSL and the pilot pins. Subsequently, adhesive is supplied to the top surface of the stacked AUSL by a bonding roller and pressure is simultaneously applied to the bottom surface of the stacked AUSL. Finally, three-dimensional shapes are rapidly fabricated. This paper describes the procedure for generating the cutting path data (AUSL data) f3r automated VLM-ST. The method for the generation of the Automated Unit Shape Layer (AUSL) in Automated VLM-ST was practically applied and fabricated for a various shapes.

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A State-of-the-Art Review on Debonding Failures of FRP Laminates Externally Adhered to Concrete

  • Kang, Thomas H.K.;Howell, Joe;Kim, Sang-Hee;Lee, Dong-Joo
    • International Journal of Concrete Structures and Materials
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    • 제6권2호
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    • pp.123-134
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    • 2012
  • There is significant concern in the engineering community regarding the safety and effectiveness of fiber-reinforced polymer (FRP) strengthening of RC structures because of the potential for brittle debonding failures. In this paper, previous research programs conducted by other researchers were reviewed in terms of the debonding failure of FRP laminates externally attached to concrete. This review article also discusses the influences on bond strength and failure modes as well as the existing experimental research and developed equations. Based on the review, several important conclusions were re-emphasized, including the finding that the bond transfer strength is proportional to the concrete compressive strength; that there is a certain bond development length that has to be exceeded; and that thinner adhesive layers in fact lower the chances of a concrete-adhesive interface failure. It is also found that there exist uncertainty and inaccuracy in the available models when compared with the experimental data and inconsistency among the models. This demonstrates the need for continuing research and compilation of data on the topic of FRP's bond strength.