• Macromolecular Research
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• 제15권2호
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• pp.114-128
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• 2007

Polyimides are one of the most important classes of polymers used in the microelectronics and photoelectronics industries. Because of their high thermal stability, chemical resistance, and good mechanical and electric properties, polyimides are often applied in photoresists, passivation and dielectric films, soft print circuit boards, and alignment films within displays. Recently, fully aliphatic and alicyclic polyimides have found applications as optoelectronics and inter layer dielectric materials, due to their good transparencies and low dielectric constants $(\varepsilon)$. The low molecular density, polarity and rare probability of forming inter- or intra-molecular charge transfers, resulting in lowering of the dielectric constant and high transparency, are the most striking characteristics of aliphatic polyimide. However, the ultimate end use of polyimides derived from aliphatic monomers is in their targeted applications that need less stringent thermal requirements. Much research effort has been exerted in the development of aliphatic polyimide with increased thermal and mechanical stabilities, while maintaining their transparencies and low dielectric constants, by the incorporation of rigid moieties. In this article, the recent research process in synthesizing fully aliphatic polyimides, with improved dimensional stability, high transparency and low $\delta$values, as well as the characterizations and future scope for their application in micro electric and photo-electronic industries, is reviewed.

• 한국응용과학기술학회지
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• 제12권1호
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• pp.93-99
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• 1995

미셀반응, 유화중합, 상간이동촉매반응 등에 이용되는 계면활성제가 갖고 있는 문제점을 해결하기 위하여 반응 후 분해되는 분해성 계면활성제를 합성하였다. 케탈이나 아세탈반응에 의하여 이루워진 1,3-디옥솔란 고리가 산수용액 중에서 불안정해 쉽게 가수분해로 계면활성을 띠지 않는 분해성 계면활성제를 합성하였다. 합성된 화합물은 백색결정상태로 얻었으며 수율은 90% 이상이었다. 그리고 이 화합물과 중간생성물은 얇은막 크로마토그래피와 컬럼 크로마토그래피로 분리하여 적외선과 수소핵자기공명 및 원소분석 스텍트라로 그 화합물들의 구조를 확인하였다.

• 한국주조공학회지
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• 제37권4호
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• pp.115-122
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• 2017

The aim of this research is to evaluate the wear properties of (TiB+TiC) paticulate reinforced titanium matrix composites (TMCs) by in-situ synthesis. Different particle sizes (1500, $150{\mu}m$) and contents (0.94, 1.88 and 3.76 mass% for Ti, 1.98 and 3.96 mass% for the Ti6Al4V alloy) of boron carbide were added to pure titanium and to a Ti6Al4V alloy matrix during vacuum induction melting to provide 5, 10 and 20 vol.% (TiB+TiC) particulate reinforcement amounts. The wear behavior of the (TiB+TiC) particulate reinforced TMCs is described in detail with regard to the coefficient of friction, the hardness, and the degree of reinforcement fragmentation during sliding wear. The worn surfaces of each sliding wear condition are shown for the three types of wear studied here: transfer layer wear, particle cohesion wear and the development of abrasive areas. The fine reinforcements of TMCs were easily fragmented from the Ti matrix as compared to coarse reinforcements, and fragmented debris accelerated the decrease in the wear resistance.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.843-845
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• 2009

A polymeric host for triplet emitters composed of N-alkylcarbazole and tetramethylbenzene units was successfully synthesized. Efficient energy transfer was observed between this polymeric host and green phosphorescent dyes. The device fabricated using 5 wt% green 1 in the polymeric host as the emitting layer showed the best performance. Thin films of this host-guest system, exhibiting clear stripe patterns could be prepared through the LITI process. The patterned films were then used to fabricate electrophosphorescent devices, which show performance characteristics similar to those of spin-coated devices. The new host material is a good candidate to be used in polymer-based full-color electrophosphorescent light-emitting displays.

• 한국통신학회논문지
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• 제21권7호
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• pp.1850-1860
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• 1996

We present the results for the design ofantireflection (AR) coatings on facets of a multilayered structure waveguide device. The method, whose results agree very well with the reusults of the rigorous method in the case of a symmetric three layer structure deveice, is extended for the design of AR coatings on the facets of a multilayered structure waveguide device. the field profile in a multilayered structure waveguide necessary for the use of the extended method is obtained from the transfer matrix method. The virtual four layered structure method (VFLM) is proposed to reduce the time for the design ofAR coatings because the time for the design of AR coatings using the extended method increases as the number of layers increases. The optimum coating parameters and tolerance mapsfor two different six layered waveguide devices in Ref. [9] and [10] are obtained using the extendedmethod and the VFLM,and for the three different cases approximated as three layered waveguide devices to compare the results of each case. The results of the VFLM are similar to those of the extended methodcompared to those of the three layered structure waveguide. The main reason for the above results is that the field profile in the device calculated usingthe VFLM is similar to that calculated using the extended method compared to that for three layered structure wavegjide. We conclude that the extended method or VFLM should be used for the design of AR coatings on facets of a deice required for the facet reflectivity less than 10$^{-3}$ such as a semiconductor otical amplifier.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2744-2749
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• 2008

Numerical calculations are carried out for the natural convection induced by temperature difference between a cold outer square cylinder and a hot inner circular cylinder for Rayleigh number of $Ra=10^7$. This study investigates the effect of the inner cylinder location on the heat transfer and fluid flow. The location of inner circular cylinder ($\delta$) is changed vertically along the center-line of square enclosure. The natural convection bifurcates from unsteady to steady state according to $\delta$. Two critical positions of ${\delta}_{C,L}$ and ${\delta}_{C,U}$ as a lower bound and an upper bound are ${\delta}_{C,L}=0.05$ and ${\delta}_{C,U}=0.18$, respectively. Within the defined bounds, the thermal and flow fields are steady state. When the inner cylinder locates at ${\delta}{\geq}{\delta}_{C,U}$, the space between the upper surface of inner cylinder and the top surface of the enclosure forms a relatively shallow layer where the natural convection characterized as the pure Rayleigh-Benard convection forms alternately the upwelling and downwelling plums, as a result that a series of cells known as Benard cells is derived.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2738-2743
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• 2008

We conducted a study by computational simulation about the effects of frost thickness on the pressure drop and heat transfer characteristics as whole heat exchanger configuration changes. In order to perform the analysis for validation, we assumed that frost properties have constant values and the frost layers that are formed on the fin and tube surfaces are uniform. In order to find the constant thermal conductivity of frost layer, a variety of frost thermal conductivities are performed in our work and compared with the results by Lee et al. [4] and Yang et al. [5] proposed many experimental data about the 2-rows and 2-columns finned tube heat exchanger. The numerical results agreed well with the experimental data when frost conductivity is 0.07W/mK. After the validation had performed, we applied this procedure to the finned tube heat exchanger of domestic refrigeration and investigated the thermo-hydraulic characteristic of the heat exchanger affected by frost thickness according to the inlet velocities and temperatures of air considering the configuration change such as fin pitch.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 1997년도 제9회 학술강연회논문집
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• pp.8-9
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• 1997

산업의 발달과 환경에 대한 관심이 높아짐에 따라 고효율, 저공해인 가스터빈의 응용범위가 넓어지고 있는 추세이다. 가스터빈 기관의 효율을 높이기 위해서는 터빈 입구온도를 높이는 것이 필수적인데 이는 재질에 의해 제한 받게 되고 이 때문에 효과적인 냉각방법의 필요성이 대두되었다 충돌제트는 국소적으로 높은 열/물질 전달 효과를 얻을 수 있어서 터빈 블레이드 냉각과 연소기 벽면 냉각에 효과적으로 응용 될 수 있다. 이러한 충돌제트의 냉각효과는 제트출구의 초기조건에 매우 민감한데 Kelvin-Helmholts 불안정은 불안정한 자유전단층에서 자연적인 와류생성(roll up)과 개개의 와류고리 형성의 원인이 되고 이 고리의 성장과 병합(pairing)은 제트의 유동특성에 상당히 영향을 미친다. 제트주위에 생성되는 이러한 와류에 의해 제트중심에서 속도와 난류강도가 변하게 된다. 이러한 제트초기의 불안정성은 하류에서의 와류성장에 영향을 끼치기 때문에 와류의 조절에 의한 충돌 면에의 열 전달 효과 상승을 기대할 수 있다. 이 조절방법은 크게 두 가지로 나눌 수 있는데 하나는 제트주의 환형관에 이차유동을 가하여 와류를 직접 제어함으로써 자유전단류(free shear layer flow)의 안정성 원리를 이용하여 열 전달을 촉진하는 것이고 다른 하나는 음향여기(acoustic exitation)를 사용하여 제트주위의 와류형성을 조절하는 것인데, 자연적으로 형성되는 와류의 주파수(와류의 고유주파수)나 부조화 주파수(subharmonic)로 음향여기 시키는 경우 제트 주위 와류는 더욱 증폭되고 그렇지 않은 경우 제트주위 와류의 형성이 억제되어 더 긴 제트코어의 길이 및 제트코어 주위에서 작은 크기의 와류들이 형성된다.

• Nuclear Engineering and Technology
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• 제45권7호
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• pp.895-910
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• 2013

The reflood test data from the rod bundle heat transfer (RBHT) test facility showed that the grids in the upper portion of the rod bundle could become wet well before the arrival of the quench front and that the sizes of liquid droplets downstream of a wet grid could not be predicted by the droplet breakup models for a dry grid. To investigate the water droplet generation from a wet grid spacer, a viscous linear temporal instability model of the water sheet issuing from the trailing edge of the grid with the surrounding steam up-flow is developed in this study. The Orr-Sommerfeld equations along with appropriate boundary conditions for the flow are solved using Chebyshev series expansions and the Tau-Galerkin projection method. The effects of several physical parameters on the water sheet oscillation are studied by determining the variation of the temporal growth rate with the wavenumber. It is found that a larger relative steam velocity to water velocity has a tendency to destabilize the water sheet with increased dynamic pressure. On the other hand, a larger ratio of steam boundary layer to the half water sheet thickness has a stabilizing effect on the water sheet oscillation. Droplet diameters downstream of the spacer grid predicted by the present model are found to compare reasonably well with the data obtained at the RBHT test facility as well as with other data recently reported in the literature.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.540-548
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• 2019

This study was conducted to develop insulation for solid oxide fuel cell (SOFC). The developed insulation is based on the lamination technology and the radiation shielding technology of the satellite insulation. The insulation material is consisting of insulation material for conduction resistance, spacer, and radiation shielding material. The experimental apparatus consisting vacuum bell jar, pump, heater and temperature recording device has developed to verify the performance of the insulation. The experimental values were used as reference data for the modeling development. In this paper, heat transfer is assumed to be one- dimensional phenomena for the prediction of insulation performance and internal temperature distribution in high temperature region of SOFC. The developed model was used to compare the performance difference of insulation types according to composition materials. The analysis result shows that the insulation including spacer and radiation shielding has better heat insulation performance than other cases. In this study, the thickness reduction effect of about 20% was shown compared to the insulation including only conductive material. It is noted that the radiant shielding material should be carefully selected for durability, because SOFC insulation should be used for a long time at high temperature.