• Title/Summary/Keyword: Trace analysis

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Analysis of Trace Trichlorosilane in High Purity Silicon Tetrachloride by Near-IR Spectroscopy (근적외선 분광법을 이용한 고순도 SiCI4 중의 미량 불순물 SiHCI3의 분석)

  • Park, Chan-Jo;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.87-90
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    • 2002
  • The content of $SiHCl_3$ as a trace impurity in $SiCl_4$ was analyzed by Near IR spectrophotometer with optical fiber. The strong absorption bands of $5345{\sim}5116cm^{-1}$ and $4848{\sim}4349cm^{-1}$ were used for analysis of $SiHCl_3$, and the detection limit of impurity $SiCl_3$ was appeared to be 0.005 % in the spectrum. The quantitative analysis by Near IR spectrophotometry showed the analytical possibility of trace impurity in $SiCl_4$ without sample pre-treatment not only in the laboratory but also in the field.

Trace impurities analysis of the electronic polymer resins by neutron activation analysis (중성자방사화분석법에 의한 전자소재용 고분자수지의 불순물 분석법연구)

  • Yoon, Yoon Yeol;Cho, Soo Young;Lee, Kil Yong;Yang, Myung Kwon;Shim, Sang Kwon;Chung, Yong Sam
    • Analytical Science and Technology
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    • v.17 no.4
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    • pp.308-314
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    • 2004
  • When the polymer was used for the guard raw materials of electronic device, the content of U, Th and their daughter nuclides were known as a factor of soft error. Because emitted alpha ray could be caused of mis-operation. And ionic impurities such as Cl, Fe, Na could shorten the device life-time. For the analysis of trace impurities in the polymer, neutron activation analysis(NAA) and ICP/AES have been studied. To improve the accuracy and sensitivity of the trace and ultratrace metallic impurities in the epoxy and phenol polymer, sample pretreatment method and optimum analytical condition of NAA were developed. Using the above method, U, Th and other 23 trace impurity elements were analyzed.

Elemental Analysis of herbal medicine, Foundry Air and Hair for the Study of Human Surroundings (인체 환경 연구를 위한 한약재, 작업장 공기 및 모발의 원소분석)

  • 강상훈;이상순;조승연;정용삼
    • Journal of Environmental Health Sciences
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    • v.28 no.3
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    • pp.64-71
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    • 2002
  • Hair provides important information about the body's mineral status. Therefore, we have studied the trace elemental distribution in human hair under different inhalation and ingestion environment using neutron activation analysis (NAA). NAA is a powerful analytical method which can be used successfully to determine trace elements in environmental and biological materials. Total diet and six different herbal medicine were analysed to study ingestion environment. Airborne dust in foundry was analysed and compared with outdoor dust to study inhalation environment. Human hairs of common person, herbal medicine taker and foundry worker were analysed to estimate the trace elemental distribution of people under different inhalation and ingestion environment. Analytical results show that herbal medicines contain higher micronutrients such as Ca, Mg, Mn and Cu that total diet and airborne dust in foundry has high Cr. The concentration of Ca, Mg and Mn in hair of herbal medicine taker is two times higher than in hair of common person and Cr con-centration in hair of foundry worker is about three times higher than in hair of common person. These results show that NAA can be used importantly to monitor human health through biological and environmental samples.

Trace Elements Characterization of PM10 in Seoul Area (서울지역의 PM10 중 미량원소의 특성 평가)

  • 신은상;최민규;영선우;정용삼
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.363-372
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    • 2002
  • PM$_{10}$ aerosols were collected using low volume air sampler every month intervals from September 1992 to August 1991 in Seoul. These samples were analyzed for 20 trace elements (Al, As, Ba, Br, Ca, Cl, Co, Cr, Fe, K, Mn, Na, Ni, Pb, Sc, Se, Si, Ti, V and Zn) by INAA (instrumental neutron activation analysis), XRF (x-ray fuorescence spectrometer), and ICP (inductively coupled plasma). PM$_{10}$ mass concentrations higher than 70 $\mu$g/m$^3$ were 32% of 60 samples and had significantly higher concentrations in spring and winter than in summer and fall (p-value<0.001). The elements of As, Br, Cl, Ni, Pb, Se, V, and Zn are enriched by factors of 20 to 2,000 relative to their natural abundance in crustal soil. To further identify common sources of pollution-related trace elements, factor analysis was applied to the trace elements concentration data. Major sources that contribute to the atmospheric loading of these elements were found to include fossil fuel combustion, automobile and waste incineration (33.2%), metal processing industry (18.2%), and soil(29.8%).8%).

Clean techniques for trace metal analysis in natural waters (자연수 중의 미량금속 분석을 위한 청결기술)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Cho, Sung-Rok;Park, Jun-Kun;Moon, Deok-Soo;Kim, Hyeon-Ju
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.43-49
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    • 2007
  • The metals we are familiar with(Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc) are common elements and conservative pollutants. Although metals are often vital constituents of the metabolism of living organisms(trace elements}, a number of them are toxic if their concentration exceeds a certain threshold. It has long been recognized that measurements of trace metals in natural waters are often subject to large errors in terms of precision and accuracy. Since 1975 in US and European countries, seawater concentration of many trace metals have been shown to be factors of 10-1,000 lower than those previously accepted. Vertical profiles have been found to be consistent with known biological, physical and/or geochemical processes. These are resulted from major advances in analytical instrumentation and methodology for trace elements, and greater attention has been given to assuring the elimination of contamination during sampling, storage, and analysis.

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A Study on Trace Metal Contents and Correlation Analysis between Cereal and Soils in the Vicinity of Industrial Area Korea (일부 공업지역 주변의 토양과 곡류중에 미량금속 함량 및 상관관계에 관한 조사연구)

  • 김동술;김종욱;이용욱
    • Journal of Food Hygiene and Safety
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    • v.11 no.2
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    • pp.135-142
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    • 1996
  • In order to grasp, status of trace metals contained and corelation analysis between cereal and soils, the samples which have been collected from four myeons in Ulju-ku Ulsan-city were 48 for cereal and 48 for soils. The average Hg containing level of samples is 0.006 ppm for cereal and 0.062 ppm for soil, Pb is 0.302 ppm for cereal and 0.885 ppm for soil, and Zn is 7.853 ppm for cereal and 2.366 ppm for soil. Corelation analysis between cereal and soils showed statistical significance for Hg, Pb and Cu, but it didn't show any significance for Cd and Zn.

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Heterogeneous Operating Systems Integrated Trace Method for Real-Time Virtualization Environment (다중 코어 기반의 실시간 가상화 시스템을 위한 이종 운영체제 통합 성능 분석 방법에 관한 연구)

  • Kyong, Joohyun;Han, In-Kyu;Lim, Sung-Soo
    • IEMEK Journal of Embedded Systems and Applications
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    • v.10 no.4
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    • pp.233-239
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    • 2015
  • This paper describes a method that is integrated trace for real-time virtualization environment. This method has solved the problem that the performance trace may not be able to analyze integrated method between heterogeneous operating systems which is consists of real-time operating systems and general-purpose operating system. In order to solve this problem, we have attempted to reuse the performance analysis function in general-purpose operating system, thereby real-time operating systems can be analyzed along with general-operating system. Furthermore, we have implemented a prototype based on ARM Cortex-A15 dual-core processor. By using this integrated trace method, real-time system developers can be improved productivity and reliability of results on real-time virtualization environment.

Research on the Evaluation of the Differences in Financial Variablesof Chain Restaurants Using Multivariate Analysis of Variance (다변량 분산분석을 이용한 체인 레스토랑의 재무변수 차이 평가 연구)

  • Kang, Seok-Woo
    • Culinary science and hospitality research
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    • v.14 no.1
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    • pp.21-38
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    • 2008
  • This research aimed to analyze the differences in financial variables classifying chain restaurants. A total of 126 samples were drawn from financial statements for $2001{\sim}2006$. As a result of analysis, there was a significant difference in Pillai's Trace, Wilks' Lambda, Hotelling's Trace, and Roy's Largest Root values at the significant probability value(p<0.05) based on F value in terms of stability among chain restaurants. Difference was found only in current rate and liabilities in ANOVA. There was a great difference in current rate among institutional restaurants, fast food restaurants, and cafeterias. There was a significant difference in Pillai's Trace, Wilks' Lambda, Hotelling's Trace, and Roy's Largest Root values at the significant probability value(p<0.05) based on F value in terms of restaurants' profitability. In ANOVA, difference was found only in net profits to net sales. It was revealed that all factors showed no significant differences in multiple comparison. All multi-variant test statistics showed a significant difference in growth and turnover. ANOVA showed a significant difference in net sales growth rate, net profit growth rate, and total assets growth rate.

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Determination of Trace Elements in Airborne Particulates by Instrumental Neutron Activation Analysis (중성자 방사화분석법을 이용한 대기분진시료의 정량)

  • Chung, Yong-Sam;Chung, Young-Ju;Jeong, Eui-Sik;Cho, Seung-Yeon
    • Nuclear Engineering and Technology
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    • v.27 no.2
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    • pp.234-247
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    • 1995
  • Trace elements in airborne particulates were analyzed by instrumental neutron activation analysis (INAA) under the optimum analytical condition. Neutron irradiation for sample was done at the irradiation hole(neutron flux 1$\times$10$^{13}$ n/$\textrm{cm}^2$.s) of TRIGA MARK-III research reactor in the Korea Atomic Energy Research Institute. For the verification of the analytical method, NIST SRM-1648 and NIES CRM No.8 ore chosen and analyzed. The accuracy and precision of the analysis of 40 and 24 trace elements in the samples were compared with the certified and reported values, respectively. The analytical method was found to be reliable enough when the analytical data of NIES sample were compared with those of different counties. In the analytical result of two or both of standard reference materials, relative standard deviation wes within the 15% except a few elements and the relative error was within the 10%. We used this method to analyze 30 trace elements in airborne particulates collected with the high volume air sampler(PM-10) at too different locations and also confirmed the possibility to use this method as a routine monitoring tool to find out environmental pollution sources.

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