• Fire Science and Engineering
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• v.29 no.4
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• pp.61-66
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• 2015

PVC pipe has excellent corrosion resistance and chemical resistance and is broadly used. However there are no regulations regarding exposed piping material in buildings. There is growing concern about the vulnerability of piping to fires and generating toxic gas. Exposed piping should be made of incombustible materials to prevent spreading of toxic gas and to minimize damage to life and property in case of fire. Many big structures are being built, and concerns regarding damage by fire are continuously growing. In these circumstances, we should reinforce fire safety standards for buildings and heighten safety consciousness to become a well-developed country. For these reasons, we investigated the materials used for exposed piping and the standards of well-developed countries to enhance safety. We tried to figure out the alternatives by examining the actual conditions of each region's buildings. Based on the use of incombustible materials for exposed piping in each region, we tried to enhance the effectiveness for safety by suggesting revisions for related laws and regulations.

• Bulletin of the Korean Chemical Society
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• v.26 no.4
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• pp.529-536
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• 2005

Measurement of toxicologically relevant polychlorinated biphenyl (PCB) congeners such as non-ortho(IUPAC#) 77, 81, 126, 169 and mono-ortho 105, 114, 118, 123, 156, 157, 189 and di-ortho 170, 180 and polybrominated diphenyl ethers (PBDEs) such as 47, 66, 85, 99, 100, 138, 153, 154 in environmental samples become almost mandatory in several countries now. However, most of the available methods involve expensive instrumentations such as HRGC-HRMS or ECNI-LRMS, apart from expensive extraction and clean-up (with large volume of solvents) steps. A method has been devised combining the analytical separation power of PYE [2-(1-pyrenyl)ethyldimethysilylated silica] column HPLC and high-resolution gas chromatographic techniques including micro-electron capture detection (ECD) and two dimensional gas chromatograpy-ECD techniques to determine these eco-toxic substances at parts-per-trillion (ppt) levels. This combination resolves co-elution of congeners that occur in disproportionate ratios (e.g. CB-110 and -77) and allows accurate congener-specific determination of target compounds. This method is cost effective as it requires only hexane, that in small quantities (10 mL) and GC-ECD. The elution and analysis time are optimized to less man hours. This method is effectively utilized in the analysis of co-planar PCBs and PBDEs from archived solvent extracts of samples previously analyzed for pesticides and PCBs. Structure based separation of contaminant classes improves GCECD determination at ppt levels.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.795-798
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• 2003

Toxic organics are of great environmental concern primarily because they are toxic to mammals and birds, and are relatively soluble in water to contaminate surface water and groundwater. In this study, the decomposition of phenol, a widely used organic, in aqueous solutions by Boron doped diamond(BDD) electrode was examined. Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond (BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work. we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte. Decomposition of phenol concentration in the reaction solution by photolytic ozonation( $UV/O_3$) was analyzed by HPLC epuipped with a UV detector.

• Fire Science and Engineering
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• v.20 no.3 s.63
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• pp.15-20
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• 2006

In this study the flow characteristics of smoke and heat on a bank type platform of the underground subway station are studied numerically by considering two different emergency operation modes. Effects of the natural flow through the tunnel and the stair ways are considered in the numerical simulations by using the measured velocities presented in Part I as the boundary condition. Distributions of heat, smoke, visible range and toxic gas on the platform are analysed for different smoke extraction flowrates corresponding to the two different emergency operation modes. The numerical results show that the extraction flowrate affects the smoke control performance significantly by improving the smoke removal performance as the extraction flowrate is increased.

• Journal of Biosystems Engineering
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• v.30 no.6 s.113
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• pp.333-339
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• 2005

The pesticide is raising public interest in the world, because it causes damage to an environmental pollution and the human health remaining agricultural products and an ecosystem, in spite of the advantages. Particularly, each country restricts the residual pesticide and induces observance about the safety and usage standard so that they can control the amount of pesticide used and defend the safety of agricultural products. The habitual practice for the analysis of the residual pesticide depends on GC (gas chromatography), HPLC (high performance liquid chromatography) and GC/MS (gas chromatography/mass spectroscopy), which triturate the fixed quantity of samples, abstract and purify as a suitable organic solvent. These methods have the highly efficient in aspects of sensitivity and accuracy. On the other hand, they need the high cost, time consuming, much effort, expensive equipment and the skillful management. Carbofuran is highly toxic by inhalation and ingestion and moderately toxic by dermal absorption. As with other carbamate compounds, it is metabolized in the liver and eventually excreted in the urine. The half-life of carbofuran on crops is about 4 days when applied to roots, and longer than 4 days if applied to the leaves. This research was conducted to develop immunoassay for detecting carbofuran residue quickly on the basis of surface plasmon resonance and to evaluate the measurement sensitivity. Gold chip used was CM5 spreaded dextran on the surface. An applied antibody to Immunoassay was GST (glutathione-s-transferase). The association and the dissociation time were 176 second and 215 second between GST and carbofuran. The total analysis time using surface plasmon resonance was 13 minutes including regeneration time, on the other hand HPLC and GC/MS was 2 hours usually. The minimum detection limit of a permissible amount for carbofuran in the country is 0.1 ppm. The immunoassay method using surface plasmon resonance was 0.002 ppm.

• Journal of the Korean Society of Marine Environment & Safety
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• v.21 no.6
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• pp.704-711
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• 2015

In this study, we have conducted a survey of AHP technique through the ocean experts to derive new items and revise assessment items and indices for risk of sunken ships based on the survey results. As a result of the survey, two new items such as accident cause and tidal current are derived. And it shows that existing items such as toxic liquid substance, remaining oil and explosive gas which were evaluated as one group are desirable to be evaluated respectively. Accordingly, we analyze the indices of the new eleven assessment items adjusted from the existing seven assessment items. As a result, the indices are ordered by toxic liquid substance, possibility of leaking, explosive gas, carrying capacity of fuel oil, sensitivity of sea environment, marine traffic environment, cause of accident, tidal current, keel clearance, ship type, and ship size. Especially, as compared with the indices of existing assessment items, the indices of sensitivity of sea environment and possibility of leaking are higher and the index of keel clearance is lower.

• Journal of the Korean Institute of Gas
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• v.17 no.3
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• pp.33-38
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• 2013

The chemical industries have used large amounts of chemicals. If an accident occurs, it caused physical and human damage. We intended to investigate risk assessment for the prevention of accidents. The risk assessment by HAZOP technique has been applide to major chemical industries, and that result has been utilized efficiently. In this study, we analyzed Bow-Tie and HAZOP technique, and risk assesment was performed by Bow-Tie on toxic material process. As a result, the risk that can not be found in the risk assessment of the other is derived, and improvements of 14 to remove the dangers derived. Bow-Tie risk assessment is suitable to derive the applicability of risk factors in the field and to establish the improvement measures.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.27 no.1
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• pp.23-37
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• 2017

Objectives : This study was conducted to evaluate the level of exposure to volatile organic compounds (VOCs) among workers handling rust preventive oils. Methods : A total of 30 bulk samples and 54 personal air samples were collected using diffusive samplers at 22 workplaces handling rust preventive oils in Daegu and Gyongsangbuk-do Province from March to October 2013. We also investigated detailed information on the related work conditions, such as kinds of products, handling methods, local exhaustive ventilation systems, and the status of the wearing personal protective equipment. All bulk samples and air samples were analyzed using gas chromatography mass spectrometry (GC-MS) to identify components to which workers potentially were exposed. Quantitative airborne concentrations of VOCs were confirmed using gas chromatography with flame ionized detectors. Results : In terms of qualitative analyses for the 30 bulk samples, we found carcinogenic, mutagenic and reproductive toxic(CMR) substances such as butane(carcinogenic Group 1A, mutagenic Group 1B), butoxy ethanol(carcinogenic Group 2), cumene (carcinogenic Group 2), ethyl benzene(carcinogenic Group 2), methyl isobutyl ketone(carcinogenic Group 2) and toluene (reproductive toxic, Group 2). As a result of full-shift based personal air samples, eight substances such as n-hexane, n-heptane, octane, nonane, decane, toluene, ethyl benzene and xylene were detected. Among them, n-hexane and n-heptane were detected in all of 54 air samples with $13.13mg/m^3$ and $8.61mg/m^3$ of maximum concentration, respectively. The level of airborne concentration from all of samples were bellow the occupational exposure limit in Korea. Conclusions : Based on the results of this study, workers handling rust preventive oils could be exposed to CMR substances contained in rust preventive oils and n-hexane and n-heptane were found as the most frequent sources of VOC exposure.

• Journal of the Korean Institute of Gas
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• v.2 no.4
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• pp.7-17
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• 1998

This study is to develop the consequence modeling methodology for quantitative prediction of the hazard distance(or toxic buffer distance) for two-phase flow continuous releases from the pressurized chlorine saturated liquid storage tank of the chemical plant facilities. The source term modeling was peformed by the refined analysis method based on USEPA's guideline and SuperChems model self-calculation, respectively. The hazard distance was predicted for STEL, IDLH and ERPGs(ERPG-2 and ERPG-3) concentrations being used as the toxic regultaion concentration in hazard estimation. To use as hazard estimation guideline for the establishment of the emergency response planning, the effects of source characteristics and meteorological vaiations on the hazard distance was especially considered for ERPG-2 concentration.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.23 no.11
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• pp.1371-1376
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• 2019

In case of fire in a structure, it is difficult to suppress fire because it can not accurately grasp the location of fire in case of fire. In this paper, we propose a system algorithm that can guide the optimal evacuation route in case of deep learning-based (RNN) structure disaster. The present invention provides a service to transmit data detected by sensors to a server in real time by using installed sensor, to transmit and analyze information such as temperature, heat, smoke, toxic gas around the sensor, to identify the safest moving path within a set threshold, to transmit information to LED guide lights and direction indicators in a structure in real time to avoid risk factors. This is because the information of temperature, heat, smoke, and toxic gas in each area of the structure can be grasped, and it is considered that the optimal evacuation route can be guided in case of structure disaster.