• Safety and Health at Work
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• 제14권2호
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• pp.215-221
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• 2023

Background: There is little information about the airborne hazardous agents released during the heat treatment when manufacturing a welding material. This study aimed to evaluate the airborne hazardous agents generated at welding material manufacturing sites through area sampling. Methods: concentration of airborne particles was measured using a scanning mobility particle sizer and optical particle sizer. Total suspended particles (TSP) and respirable dust samples were collected on polyvinyl chloride filters and weighed to measure the mass concentrations. Volatile organic compounds and heavy metals were analyzed using a gas chromatography mass spectrometer and inductively coupled plasma mass spectrometer, respectively. Results: The average mass concentration of TSP was 683.1±677.4 ㎍/m³, with respirable dust accounting for 38.6% of the TSP. The average concentration of the airborne particles less than 10 ㎛ in diameter was 11.2-22.8×10⁴ particles/cm³, and the average number of the particles with a diameter of 10-100 nm was approximately 78-86% of the total measured particles (<10 ㎛). In the case of volatile organic compounds, the heat treatment process concentration was significantly higher (p < 0.05) during combustion than during cooling. The airborne heavy metal concentrations differed depending on the materials used for heat treatment. The content of heavy metals in the airborne particles was approximately 32.6%. Conclusions: Nanoparticle exposure increased as the number of particles in the air around the heat treatment process increases, and the ratio of heavy metals in dust generated after the heat treatment process is high, which may adversely affect workers' health.

• 한국입자에어로졸학회지
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• 제13권3호
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• pp.119-125
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• 2017

A novel two stage cylindrical cyclone was developed for a 3 phase separator in shale oil production industry. The cyclone performance was compared with a cone type cyclone and multi cyclone at the same experimental condition using water and oil mists generated by a humidifier and atomizer at the flow rate 1 to $2m^3/min$. The removal efficiency of total suspended water droplets by the novel cyclone, calculated using inlet and outlet concentrations measured by an optical particle counter, was 99% which is higher than 90% of oil droplet removal efficiency at $2m^3/min$. It might be due to the evaporation of small water droplets during the tests. The water and oil droplet removal performance of the novel cyclone based on the quality factor which is a function of pressure drop and removal efficiency was the highest among three cyclones. The results indicate that the cyclone could be an economical device to remove water and oil mists from shale gas generation processes where a huge three phase separator is commonly used.

• 한국도로학회논문집
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• 제11권3호
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• pp.141-149
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• 2009

본 연구는 고속도로 강우 유출수에서 입도 크기 분포 특성(PSD)을 이해하기 위하여 수행하였다. 경기도내 4곳의 포장도로 지역에서 2번의 강우사상동안 강우유출수 샘플 모니터링을 수행하였고, 시료내 입자의 크기분포를 분석하였다. 또한, 강우량, 유량 및 각 오염물질들을 분석하였다. 시료내 입자의 시간별 변화농도는 강우유출수의 시작 시 높은 값을 보였다가 급속히 감소하였으며 탁도, 총부유물질, BOD, 총질소 및 총인과 같은 오염물질과 유사한 유출경향을 보여주었다. 특히 총부유물질과 탁도와의 높은 상관성을 보여주었다. 강우유출수와 퇴적물내에 포함된 중금속에 있어서 구리, 납, 아연은 높은 농도를 보였으며 대부분의 중금속은 넓이에 대한 부피의 비율이 큰 세립입자에 강하게 결합된 형태로 존재한다.

• 한국수자원학회논문집
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• 제54권8호
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• pp.607-616
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• 2021

본 연구는 가는 모래로 이루어진 하상으로부터 침식된 부유사의 농도분포 계산결과에 차폐효과가 미치는 영향을 살펴보는 것을 목적으로 수행되었다. 하상재료의 입도분포를 고려하여 침식율을 산정할 수 있는 유사이동 모형을 개발하였으며, 측정자료와의 비교를 통해 수치모형의 적용가능성을 검토하였다. 수치모의결과로부터 하상재료 입도분포의 기하표준편차가 1.5보다 작은 경우 차폐효과가 부유사 농도의 연직방향 분포 계산결과에 미치는 영향은 매우 작은 것으로 나타났다. 또한 기하표준편차가 1.5이하인 가는 모래로 이루어진 하상으로부터 침식된 유사 농도를 계산하는 경우, 균일사로 가정 후 대표입경을 바탕으로 농도를 산정하여도 합리적인 결과가 얻어지는 것으로 확인되었다.

• Environmental Analysis Health and Toxicology
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• 제5권3_4호
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• pp.19-28
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• 1990

Nitroarenes are ubiquitous environmental pollutants displaying potent mutagenicity in bacteria and carcinogenicity in mammal. In this study, the concentration of nitroarenes in coarse and fine particles and mutagenicity of POC$\_$N/ fraction was investigated in suspended particulates at the Shinchon and Bulkwang area of Seoul. The suspended particulates were collected bimonthly by a high volume cascade impactor air sampler from July 1987 to May 1988. Extractable organic matter was obtained by ultrasonic extraction on diethly ether/cyclohexane (8/2, v/v). Neutral fraction was obtained by liquid-liquid extraction. Polar neutral organic compounds (POC$\_$N/) was fractionated by thin-layer chromatography. Finally, the concentrations of nitroarenes in POC$\_$N/ fraction were measured and determined by capillary gas chromatography. Direct and indirect mutagenicity of POC$\_$N/ fraction were measured using Salmonella typhimurium TA 98. The result were as follows: 1) Major nitroarenes at the Shinchon area was 1-nitropyrene and at the Bulkwang area it was 2,7-dinitro-9-fluorenone during the year. 2) Average concentration of total nitroarenes measured was 67.26 ng/m$^3$in fine particles which was 1,3 folds higher that in coarse particle (52.30 ng/m$^3$). 3) Annual pattern of nitroarenes concentrations revealed that concentration during heating season (Feb., Jan., Mar.) was 2.2 folds higher than that in non heating season (May, Jul., Sep.). Concentration of each season has 157.68 ng/m$^3$and 80.39 ng/m$^3$. 4) The mutagenic activity of POC$\_$N/ fraction from fine particles was higher compared to that of coarse particles and was increased when metabolically activated, with 59 mixture. Mutagenicities, Metabolically activated, were significantly different between Shinchon and Bulkwang area, 322.8 rev/250 $\mu\textrm{g}$/plate and 286.8 rev/250 $\mu\textrm{g}$/plate, respectively. 5) Annual pattern of mutagenicity of POC$\_$N/ fraction revealed that mutagenicity during the heating season was 1.7 folds higher at Shinchon area and 1.2 folds higher at Bulkwang than during the non heating season. The variable contents and levels of nitroarenes in suspended particulates may affect human health significantly. Further studies such as risk assessment should be conducted on the basis of these kind of studies.

• 한국직업건강간호학회지
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• 제4권호
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• pp.58-83
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• 1995

The small scale industries which have less than 30 employees occupy 86.5% of total number of industries in Korea. And though they have higher accident rate and lower environmental condition than big industries, it has been not mandatory to appointing health care manager at factory. So, from 1993, government subsidizes to the health care management of small industries. The purpose of this study is to identify the real feature of health care status in small industries, and to evaluate the level of health care management, before and after the subsidiary program. 65 small plating industries which have been managed by the same health care management support institution in 1993 were selected for study. Of the 65 industries, 3 which have not taken both environmental evaluation and health screening in 1994, and 9 which have closed were excluded from study sample. And the remaining 53 were analyzed by using the results of environmental evaluation and health screening, reported to the Ministry of Labor, before and after the subsidiary program, the analysis was done by the comparison of the two year paired data of the same industry. Over-permissible-limit rate, health screening implementation rate, above grade C rate were calculated and compared. The status of health care management ; 1. Of the sample industries, 96.9% provide protective equipment and 80.0% set up ventilating system. Protective gloves (89.2%) and protective clothing (80.0%) are widely provided, but ear plugs (4.6%) are rarely provided. 21.5% of the protective equipment are well put on, and 40.4% of the ventilating systems function well. 2. In 1993, 35 industries, 53.8% of the sample, checked working environment twice. Over-permissible-limit rates of heavy metal (12.2%), suspended particle (11.1%), noise (5.5%) were high. To put on protective equipment and to set up local ventilating system were pointed out by the examiners. 3. General health screening was done at 63.1% of the sample industries and 35.3% of total workers were examined. Specific health screening was done at 93.8% of the sample industries and 75.4% of workers were examined. 15.5% of workers was provided to be above grade C and to have digestive system disease (43.3%), circulatory disease (18.9%), and hematopoietic disease (14.2%), etc. 4. In 1993, the subsidiary program of health care management was provided in forms of health education, health counseling, and rounding check of working field. And 61.5%, 83.0%, 55.4% of sample industries respectively received it. The average visit per industry was 1.8. Comparisons of the level of occupational health before and after the subsidiary program ; 1. Over-permissible-limit rates of hazardous factors of 1993 and that of 1994 were compared. The rates of suspended particle, noise, organic solvent of 1994 (37.5%, 13.4%, 24.2% respectively) were higher than that of 1993 (25.0%, 6.0%, 6.3% respectively). In the case of acid, there was no difference between the rate of 1993 and that of 1994. Only the rate of heavy metal decreased from 12.9% in 1993 to 3.0% in 1994. 2. General health screening was done at 38.7% of the sample industries in 1993 and at 44.6% in 1994. But the implementation rate of specific health screening decreased from 72.4% in 1993 to 64.6% in 1994. 3. The implementation rate of specific health screening was analyzed by some health factors. The rate of suspended particle increased from 61.8% in 1993 to 91.2% in 1994. But the rates of the others-noise, organic solvent, heavy metal, specific chemical substances-decreased. 4. Above grade C rate in health screening increased from 27.8% in 1993 to 35.5% in 1994. But that of endocrine disorders and pulmonary disease decreased.

• 한국환경보건학회지
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• 제46권6호
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• pp.719-725
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• 2020

Objectives: With the growth of national interest in fine particulate matter, many complaints about pollutants emitted from air pollution emitting facilities have arisen in recent years. In particular, it is thought that a large volume of particulate pollutants are discharged from workplaces that use Solid Refuse Fuel (SRF). Therefore, particulate contaminants generated from SRF were measured and analyzed in this study in terms of respective particle sizes. Methods: In this study, particulate matter in exhaust gas was measured by applying US EPA method 201a using a cyclone. This method measures Filterable Particulate Matter (FPM), and does not consider the Condensable Particulate Matter (CPM) that forms particles in the atmosphere after being discharged as a gas in the exhaust gas. Results: The mass concentration of Total Suspended Particles (TSP) in the four SRF-using facilities was 1.16 to 11.21 mg/Sm3, indicating a very large concentration deviation of about 10 times. When the fuel input method was the continuous injection type, particulate matter larger than 10 ㎛ diameter showed the highest particle size fraction, followed by particulate matter smaller than 10 ㎛ and larger than 2.5 ㎛, and particulate matter of 2.5 ㎛ or less. Contrary to the continuous injection type, the batch injection type had the smallest particle size fraction of particulate matter larger than 10 ㎛. The overall particulate matter decreased as the operating load factor decreased from 100% to 60% at the batch input type D plant. In addition, as incomplete combustion significantly decreased, the particle size fraction also changed significantly. Both TSP and heavy metals (six items) satisfied the emissions standards. The measured value of the emission factor was 38-99% smaller than the existing emissions factor. Conclusions: In the batch injection facility, the particulate matter decreased as the operating load factor decreased, as did the particle size fraction of the particulate matter. These results will help the selection of effective methods such as reducing the operating load factor instead of adjusting the operating time during emergency reduction measures.

• 한국수산과학회지
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• 제35권4호
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• pp.327-335
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• 2002

Effects of available food on growth of commercially cultured Pacific oysters, Crassostrea gigas in Goseong Bay on the south coast were studied using a numerical model. levels of total protein, carbohydrate and lipid in particulate organic matter in the water column as well as chlorophyll a concentration were determined for estimating total available food for oyster growth. Environmental parameters including water temperature, salinity and total suspended solid were also monitored for the model. Oyster growth was also monitored by means of measuring shell length and tissue wet weight increase on a monthly basis. Simulation results from the numerical model indicated that chlorophyll a is not a good representative of available food for the oysters in Goseong Bay. In contrast, available food in the water column measured by filtration of the organic particles and analyzed in terms of total lipids, carbohydrates and protein was well matched with simulated oyster growth in the Bay which is similar to observed growth. The model also suggested that oysters have relatively low retention efficiency of $50\%$ or less. This result indicates that oysters in the bay utilize only a part of food particle available in the water column, as reported in other studies.

• 한국대기환경학회지
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• 제14권3호
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• pp.229-236
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• 1998

Visibility is a good indicator of comprehensive alto quality. The prevailing visibility in Seoul is no better than the past although the average concentration of SO2 and TSP (total suspended particulate) has decreased quite significantly in the past decade, owing to the government efforts to reduce the emission. Then, a question arises why visibility has not been improved. In order to answer this question we have investigated which components of air pollutants are most responsible for the visibility degradation in Seoul. Analysis on the visibility vs the aerosol sixte distribution measured by an optical particle counter shows that the particles of the size interval between 0.5mm and 2.5mm are most responsible for the visibility degradation. Among the criteria air Pollutants, NOB concentration is found to be moot responsible, rather than PM10. ton analysis of the particulate collected by a high volume sampler shows that the nitrate component increases more significantly than other ions when visibility becomes very poor. Therefore, we conclude that the major causes of visibility degradation in Seoul are the increase of NOB, nitrates and the particles of the size range between 0.5mm and 2.5mm.

• 한국대기환경학회지
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• 제12권3호
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• pp.297-305
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• 1996

Aerosol measurements were carried out at Kosan, Cheju Island, Korea for the period from July 20 to August 10, 1994. Total suspended particles were collected by high volume samplers and PM 2.5 particles with gaseous volatile species were collected by a filter pack sampler and their ionic composition are analyzed. The average mass concentration of PM 2.5 particles was comparable to that of PM 3 particles collected during March, 1994 at the same site but the average non sea-salt sulfate concentration was higher that that of PM 3 particles, implying the fraction of anthropogenic air apllutants during this period is higher than that during March, 1994. During the measurement period, two distincitive patterns were observed, high concentrations of mass and water soluble ions were observed between July 20 and August 1 while those during after August 2 were low. Back trajectory analysis results show that air masses arriving at Kosan during the earlier period were mainly from Korea and Japan while those during the later period were from the North Pacific Ocean. It is suggested that the particle ion concentrations during the later period are marine background concentrations at Kosan during the summertime.