• 제목/요약/키워드: Total porosity

검색결과 282건 처리시간 0.026초

초음파 공진 분석법을 이용한 건식공정 핵연료 소결체의 탄성계수 측정 (Elastic Modulus Measurement of a Dry Process Fuel Pellet by Resonant Ultrasound Spectroscopy)

  • 류호진;강권호;문제선;송기찬;정현규;정용무
    • 한국분말재료학회지
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    • 제11권4호
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    • pp.314-321
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    • 2004
  • The elastic moduli of simulated dry process fuels with varying composition and density were measured in order to analyze the mechanical properties of a dry process fuel pellet. Resonant ultrasound spectroscopy(RUS) which can determine all elastic moduli with one set of measurements for a rectangular parallelepiped sample was used to measure the elastic moduli of UO$_{2}$ and simulated dry process fuel. The simulated dry process fuel showed a higher value of Young's modulus than UO$_2$ due to the presence of metallic precipitates and solid solution elements in the UO$_{2}$ matrix. The correlation between Young's modulus and porosity(P) of simulated dry process fuel was found to be 231.4-651.8 P (GPa) at room temperature. Dry process fuel with a higher burnup showed higher Young's modulus because total content of fission product element was increased.

실리카 흄을 혼입한 콘크리트의 투과특성에 관한 연구 (A Study on the Permeabilities of Concretes Containing Silica Fume)

  • 형원길;장효식;소형석;소승영;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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    • pp.443-448
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    • 1999
  • Tests have been carried out on four concrete containing different levels of silica fume to measure their permeability coefficient using water and oxygen, chloride ion. The total cementitious content was 351kg/㎥, and the water/cementitious materials ratio was 0.55. The results show that a dramatic reduction in permeability of concrete containing silica fume occurs due to formation of a discontinuous macro-pore system which inhibits flow. Porosity estimates from mercury-intrusion porosimetry are used to develop an explanations for the water and air permeability reduction. And, results of the rapid permeability test showed that the resistance of concrete to the penetration of chloride ions increases significantly as a contents of silica-fume is increased. The current intensity passing through the concrete containing silica fume is presented from 664C to 2166C.

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실리카에어로겔의 상압합성 및 특성연구(I) (Syunthesis of Silica Aerogel at Ambient Pressure and Characterization (I))

  • 강신규;최세영
    • 한국세라믹학회지
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    • 제33권12호
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    • pp.1394-1402
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    • 1996
  • The Silica gel with the density of 0.2g/cm3 and porosity of 90% was synthesized. The silica wet gel was dried and heat-treated under the ambient pressure after modification of the wet gel surface by TMCS. Specific surface area total pore volume and mean pore radius of dried gel were all increased with increasing heat treatment temperature and confirmed about 1400m2/g, 4.5cc/g and 8 nm respectively after heat treatment above 25$0^{\circ}C$. But the pore size distribution of dried gel was in the range of 1-100nm and was almost indepen-dent of temperature. As the result of external shape pore characteristics and microstructure of gel using SEM similar properties were observed between the silica gel synthesized in this study and the silica aerogel through the super critical drying.

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Evaluation of Refining Strategies for Combined use of Softwood and Eucalyptus Pulps in Papermaking

  • Manfredi, Vail
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.1
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    • pp.37-42
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    • 2006
  • The paper discusses the combined use of softwood and eucalyptus kraft pulps in the production of printing and writing papers. Looking for process and paper quality optimization, refining pilot plant trails were carried to identify the effects of refining type (mixed or separate) and intensities (specific edge load), and also furnish composition (amount of each pulp in mixture) on final paper quality and process costs. The basic effects on pulp fibers were evaluated against paper quality properties, such as physical strengths, bulk, vessel picking, opacity and porosity, as well as the interactions with papermaking process, such as estimates of paper machine runnability, paper breaks and industrial refining control. The results show that the furnish composition and the type of refining has a significant effect on properties related with both final paper quality and total costs. The best alternative for printing and writing papers was identified for mixed refining, under the lowest refining intensity, and with the highest dosage of eucalyptus pulp.

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증발가스 배출물 억제를 위한 자동차용 캐니스터의 3차원 유동장 해석 (Three-Dimensional Fluid Flow Analysis of Automotive Carbon Canister for Reducing Evaporative Emissions)

  • 정수진;김우승
    • 한국자동차공학회논문집
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    • 제9권6호
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    • pp.85-93
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    • 2001
  • Minimized canister flow restriction and maximized flow uniformity are desired to maximize a purge capability. With the impending ORVR(On Board Refueling Vapor Recovery) systems, the reduction of restriction and increase of flow uniformity in a carbon canister becomes even more critical to meet the stringent regulation. In this study, three-dimensional numerical simulations have been performed to investigate the three-dimensional internal flow patterns in a carbon canister during purge. The effects of the declined angle of the purge pipe and the number of partitions on the pressure drop and purge efficiency in a carbon packed bed are examined. Results show that the purge efficiency and space velocity distribution are affected in the upstream region of 40% of total canister bed by porosity of carbon granule and angle of purge pipe. It is also found that the purge efficiency decreases with increasing the number of partitions.

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The Effect of Porosity of Seiving Particles on the Romoval Efficiency of Organic Substances via Biofilter in the Fixed Bed

  • Park Young Gyu
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제7권1호
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    • pp.31-37
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    • 2002
  • This paper was investigated to clarify the possibility of a biodegradation of materials adsorbed on different porous granular-activated carbons (GACs) such as coal-& coconut-based GAC. Total organic carbon, humic substance and ammonia were used to compare their removal efficiencies. The objective of this study is to determine the adsorption capacity of bioregenerated GAC. When raw water reacted with chloride, the yield of THMs increased as a function of the input amount of chloride. The formation of trihalomethanes (THMs) was investigated in water treated with chlorine when humic acid was used as THM precursor. As the input amount of chloride in raw water increased by two or five-fold to remove the $NH_3$, the chloroform of the THMs significantly increased also five or ten-fold. It was found that the chloroform was significantly removed by the treatment of biological activated carbon (BAG) in comparison with the ozone treatment, and the removal efficiency of THMs in coal-typed GAC was $10-30\%$ better than coconut-typed GAC due to the biological degradation on the surface of the activated carbons.

고강도 시멘트 복합체의 강도특성에 미치는 혼합재료의 영향 (An Effect of Blending Materials on the Strength Characteristics of High Strength Cement Composite)

  • 최일규;김정환;한기성
    • 한국세라믹학회지
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    • 제31권3호
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    • pp.330-336
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    • 1994
  • High strength cement composites (W/C=0.1) were prepared by using various blending materials such as SiC whisker and white carbon (hydrated silica: SiO2·nH2O). The effect of various blending materials on the microstructure and strength of the hardened cement paste were investigated in the view of fracture mechanics. The plain specimen showed 101 MPa of flexural strength, 81 GPa of Young's modulus and 1.32 MPam1/2 of fracture toughness. When the blending materials were added to the composites, their values were enhanced to about 110∼138 MPa, 95∼146 GPa and 1.32∼1.87MPam1/2 respectively. The improvement of the mechanical strength for the hardened cement paste may be due to the removal of macropores, the reduction of total porosity, pozzolanic reaction and the increase of various fracture toughening effect.

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Low Temperature Adsorption of Hydrogen on Nanoporous Materials

  • Jhung, Sung-Hwa;Yoon, Ji-Woong;Kim, Hye-Kyung;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
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    • 제26권7호
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    • pp.1075-1078
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    • 2005
  • Hydrogen adsorption on various porous materials have been studied with a volumetric method at low temperature in the pressure of 0-760 torr. Their hydrogen uptakes depend at least partly on microporosity rather than total porosity. However, it is also necessary to consider other parameters such as pore size and pore architecture to explain the adsorption capacity. The heat of adsorption and adsorption-desorption-readsorption experiments show that the hydrogen adsorption over the porous materials are composed of physisorption with negligible contribution of chemisorption. Among the porous materials studied in this work, SAPO-34 has the highest adsorption capacity of 160 mL/g at 77 K and 1 atm probably due to high micropore surface area, micropore volume and narrow pore diameter.

시멘트 페이스트의 특성에 미치는 흡수성폴리머의 영향 (Effects of Absorbent Polymer on the Moisture Resistance and Hydration Characteristics of Cement Pastes)

  • 나종균;김창은;이승규
    • 한국세라믹학회지
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    • 제36권5호
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    • pp.539-546
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    • 1999
  • Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

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폐플라스틱/제강 Dust 성형제의 용출안전성에 대한 연구 (Elution Safety of Recycled Plastic/EAF Dust Composites by Using Leaching Test)

  • 강영구;송종혁
    • 한국안전학회지
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    • 제18권4호
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    • pp.85-91
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    • 2003
  • In this study, We have investigated leaching characteristics of heavy metals for recycled plastic composites containing EAF(Electric Arc Furnace) dust & EAF slag. EAF dust & EAF slag used that is generated in the 3 steel-making compaines in domestic. The physical and chemical properties of EAF dust & slag was examined by measuring specific surface area. porosity, oil absorption test and chemical wetting analysis etc. Results of total analysis indicated that EAF dust, slag contained significant amount of hazardous metals such as Cu, Pb, Cd and Cr. But, In the leaching test of the recycled plastic composites containing EAF dust, slag by Korean Standard Leaching Procedure, composites shows much lower leaching concentration of heavy metals. It was concluded that the recycled plastic composites containing EAF dust, slag showed good physical and chemical characteristics. This means that the EAF dust, slag can be effectively used as a functional filler.