• Carbon letters
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• 제11권3호
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• pp.192-200
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• 2010

Common reed (Fragmites australis), a local invasive grass, was investigated as a possible feedstock for the production of activated carbon. Dried crushed stems were subjected to impregnation with phosphoric acid (30, 40 and 50%) followed by pyrolysis at $400{\sim}500^{\circ}C$ with final washing and drying. Obtained carbons were characterized by determining: carbon yield, ash content, slurry pH, textural properties and capacity to remove color bodies from factory-grade sugar liquor. Produced carbons possessed surface area up to 700 $m^2/g$, total pore volumes up to 0.37 $cm^3/g$, and proved to be microporous in nature. Decolorization of hot sugar liquor at $80^{\circ}C$ showed degrees of color removal of 60 up to 77% from initial color of 1100~1300 ICU, at a carbon dose of 1.0 g/100 ml liquor. No correlation seems to hold between synthesis conditions and % R but depends on the degree of microporosity. A commercial activated carbon N showed a comparative better color removal capacity of 91%. Common reed proved to be a viable carbon precursor for production of good adsorbing carbon suitable for decolorization in the sugar industry, as well as in other environmental remediation processes.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1995년도 추계학술대회 논문집
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• pp.393-396
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• 1995

In this syudy, the researches classifying the artificial and natural flaws in welding parts are performed using the smart pattern recognition technology. For this purpose the smart signal pattern recognition package including the user defined function was developed and the total procedure including the digital signal processing,feature extraction , feature selection and classifier selection is treated by bulk. Specially it is composed with and discussed using the statistical classifier such as the linear disciminant function classifier, the empirical Bayesian classifier. Also, the smart pattern recognition technology is applied to classification problem of natural flaw(i.e multiple classification problem-crack,lack of penetration,lack of fusion,porosity,and slag inclusion, the planar and volumetric flaw classification problem). According to this results, if appropriately learned the neural network classifier is better than ststistical classifier in the classification problem of natural flaw. And it is possible to acquire the recognition rate of 80% above through it is different a little according to domain extracting the feature and the classifier.

• Computers and Concrete
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• 제26권2호
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• pp.175-183
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• 2020

Fly ash has become an important component of concrete as supplementary cementitious material with the development of concrete technology. To make use of fly ash efficiently, four types of fly ash with particle size distributions that are in conformity with four functions, namely, S.Tsivilis, Andersen, Normal and F distribution, respectively, were prepared. The four particle size distributions as functions of the strength and pore structure of concrete were thereafter constructed and investigated. The results showed that the compressive and flexural strength of concrete with the fly ash that conforming to S.Tsivilis, Normal, F distribution increased by 5-10 MPa and 1-2 MPa, respectively, compared to the reference sample at 28 d. The pore structure of the concrete was improved, in which the total porosity of concrete decreased by 2-5% at 28 d. With regarding to the fly ash with Andersen distribution, it was however not conducive to the strength development of concrete. Regression model based on the grey multiple linear regression theory was proved to be efficient to predict the strength of concrete, according to the characteristic parameters of particle size and pore structure of the fly ash.

• 한국분말재료학회지
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• 제18권6호
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• pp.488-495
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• 2011

This study was performed to fabricate the porous titanium foam by space holder method using NaCl powder, and to evaluate the effect of NaCl volume fractions (33.3~66.6 vol.%) on the porosities, compressive strength, Young's modulus and permeability. For controlling pore size, CP titanium and NaCl particles were sieved to different size range of 70~150 ${\mu}m$ and 300~425 ${\mu}m$ respectively. NaCl of green Ti compact was removed in water followed by sintered at $1200^{\circ}C$ for 2 hours. Total porosities of titanium foam were in the range of 38-70%. Pore shape was a regular hexahedron similar that of NaCl shape. Porous Ti body showed that Young's modulus and compressive strength were in the range of 0.6-6 GPa and 8-127 MPa respectively. It showed that pore size and mechanical properties of Ti foams was controllable by NaCl size and volume fractions.

• 한국식품저장유통학회지
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• 제17권2호
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• pp.223-229
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• 2010

20 L 부피의 발효용기에서 어간장을 발효하면서 용기의 내부 온도 변화와 염도, pH, 산도, 총질소, 유리아미노산, 미생물 변화를 분석하였고 4개월 발효후의 어간장의 관능적 품질을 평가하였다. 발효용기로는 새 옹기와 재사용한 옹기, 스테인레스, 플라스틱 용기를 사용하였고 발효숙성은 외기조건에서 이루어졌다. 옹기가 가지는 통기성 및 보온성으로 인하여 발효 중 관여하는 미생물의 생육환경을 적절하게 조성하여 여러 가지 품질에 긍정적인 영향을 미치는 것을 확인할 수 있었다. 특히 옹기는 새 것보다는 재사용한 옹기에서 제품의 발효에 좋은 영향을 미쳐서, 높은 총질소, 유리아미노산함량, 향, 맛 전체적인 수용도의 관능적 품질을 보여주었다.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2481-2485
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• 2007

Spatially resolved, quantitative, non-destructive analysis using synchrotron x-ray reflectivity (XR) with subnano-scale resolution was successfully performed on the nanoporous organosilicate thin films for low dielectric applications. The structural information of porous thin films, which were prepared with polymethylsilsesquioxane and thermally labile 4-armed, star-shaped poly(ε-caprolactone) (PCL) composites, were characterized in terms of the laterally averaged electron density profile along with a film thickness as well as a total thickness. The thermal process used in this work caused to efficiently undergo sacrificial thermal degradation, generating closed nanopores in the film. The resultant nanoporous films became homogeneous, well-defined structure with a thin skin layer and low surface roughness. The average electron density of the calcined film reduced with increase of the initial porogen loading, and finally leaded to corresponding porosity ranged from 0 to 22.8% over the porogen loading range of 0-30 wt%. In addition to XR analysis, the surface and the inner structures of films are investigated and discussed with atomic force and scanning electron microscopy images.

• 한국세라믹학회지
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• 제52권1호
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• pp.48-55
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• 2015

Hardened cement-based materials exposed to the high temperatures of a fire are known to experience change in the pore structure as well as microstructural changes that affect their mechanical properties and tend to reduce their durability. In this experimental investigation, hardened Portland cement pastes were exposed to elevated temperatures of 200, 400, 600, 800, and $1000^{\circ}C$ for 60 minutes, and the resulting damage was studied by thermogravimetry (TG), mercury intrusion porosimetry (MIP) and density measurements. These results revealed that the residual compressive strength is increased at temperatures greater than $400^{\circ}C$ due to a small pore size of 3 nm and/or rehydration of the dehydrated cement paste. However, a loss of the residual strength occurs at temperatures exceeding 500 and $600^{\circ}C$. This can be attributed to the decomposition of hydrates such as portlandite and to an increase in the total porosity.

• Membrane and Water Treatment
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• 제11권4호
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• pp.237-245
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• 2020

The effects of the mixed two solvents, Dimethylacetamide (DMAc) and Dimethylformamide (DMF), and Polyethylene glycol (PEG) and Polyvinylpyrrolidone (PVP) as additives on performance of Polyvinylidene fluoride (PVDF) membranes were studied. Initially, PEG200 was used as a primary additive at fixed percentage of 5% wt. PVP was then blended with PEG200 in different concentrations. PVDF and DMAc were used as polymer and solvent in the casting solutions, respectively. To control the diffusion rate of PVP in the presence of PEG200 and PVP blend, mixtures of DMAc and DMF were used as the mixed solvent in the casting solutions. Asymmetric PVDF membranes were prepared via phase inversion process in a water bath and the effects of two additives and two solvents on the membrane morphology, pure water flux (PWF), hydrophilicity and rejection (R) were investigated. Attenuated Total Reflection Fourier Transform Infrared Spectra (ATR-FTIR) analysis was used to show the residual PVP on the surface of the membranes. Atomic Force Microscopy (AFM) was utilized to determine roughness of membrane surface. The use of mixed solvents in the casting solution resulted in reduction of PVP diffusion rate and increment of PEG diffusion rate. Eventually, PWF and R values reduced, while porosity and hydrophilicity increased.

• 공업화학
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• 제20권1호
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• pp.67-74
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• 2009

오늘날 대규모 건설사업에 따른 골재의 고갈과 환경보호 측면에서 폐콘크리트 순환골재의 재활용이 절실히 요구되고있다. 폐콘크리트 순환골재를 재활용한 폴리머 복합재료를 개발하기 위하여 순환골재의 치환율을 5단계로 변화시키고(0, 25, 50, 75, 100%) 또 폴리머-시멘트비도 5단계로 변화시켜(0, 5, 10, 15, 20%) 총 25종류의 공시체를 제조하였다. 공시체의 제 성능을 조사하기 위하여 공시체의 압축 및 휨강도, 흡수시험, 내열수성시험, 총세공량 및 공극률에 대하여 조사하였다. 시험결과, 폴리머 복합재료의 물성은 폴리머 시멘트비의 증가에 따라 현저히 증가되었으나 폐콘크리트 순환골재의 치환율 증가에 따라서는 크게 저하되었다.

• Carbon letters
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• 제9권4호
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• pp.298-302
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• 2008

Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.