• Title/Summary/Keyword: Total porosity

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Potential of Activated Carbon Derived from Local Common Reed in the Refining of Raw Cane Sugar

  • D-Abdullah, Ibrahim;Girgis, Badie S.;Tmerek, Yassin M.;Badawy, Elsaid H.
    • Carbon letters
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    • v.11 no.3
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    • pp.192-200
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    • 2010
  • Common reed (Fragmites australis), a local invasive grass, was investigated as a possible feedstock for the production of activated carbon. Dried crushed stems were subjected to impregnation with phosphoric acid (30, 40 and 50%) followed by pyrolysis at $400{\sim}500^{\circ}C$ with final washing and drying. Obtained carbons were characterized by determining: carbon yield, ash content, slurry pH, textural properties and capacity to remove color bodies from factory-grade sugar liquor. Produced carbons possessed surface area up to 700 $m^2/g$, total pore volumes up to 0.37 $cm^3/g$, and proved to be microporous in nature. Decolorization of hot sugar liquor at $80^{\circ}C$ showed degrees of color removal of 60 up to 77% from initial color of 1100~1300 ICU, at a carbon dose of 1.0 g/100 ml liquor. No correlation seems to hold between synthesis conditions and % R but depends on the degree of microporosity. A commercial activated carbon N showed a comparative better color removal capacity of 91%. Common reed proved to be a viable carbon precursor for production of good adsorbing carbon suitable for decolorization in the sugar industry, as well as in other environmental remediation processes.

A Study on the Digital Signal Processing for the Pattern fiecognition of Weld Flaws (용접결함의 패턴인식을 위한 디지털 신호처리에 관한 연구)

  • 김재열;송찬일;김병현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.10a
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    • pp.393-396
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    • 1995
  • In this syudy, the researches classifying the artificial and natural flaws in welding parts are performed using the smart pattern recognition technology. For this purpose the smart signal pattern recognition package including the user defined function was developed and the total procedure including the digital signal processing,feature extraction , feature selection and classifier selection is treated by bulk. Specially it is composed with and discussed using the statistical classifier such as the linear disciminant function classifier, the empirical Bayesian classifier. Also, the smart pattern recognition technology is applied to classification problem of natural flaw(i.e multiple classification problem-crack,lack of penetration,lack of fusion,porosity,and slag inclusion, the planar and volumetric flaw classification problem). According to this results, if appropriately learned the neural network classifier is better than ststistical classifier in the classification problem of natural flaw. And it is possible to acquire the recognition rate of 80% above through it is different a little according to domain extracting the feature and the classifier.

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A model to characterize the effect of particle size of fly ash on the mechanical properties of concrete by the grey multiple linear regression

  • Cui, Yunpeng;Liu, Jun;Wang, Licheng;Liu, Runqing;Pang, Bo
    • Computers and Concrete
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    • v.26 no.2
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    • pp.175-183
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    • 2020
  • Fly ash has become an important component of concrete as supplementary cementitious material with the development of concrete technology. To make use of fly ash efficiently, four types of fly ash with particle size distributions that are in conformity with four functions, namely, S.Tsivilis, Andersen, Normal and F distribution, respectively, were prepared. The four particle size distributions as functions of the strength and pore structure of concrete were thereafter constructed and investigated. The results showed that the compressive and flexural strength of concrete with the fly ash that conforming to S.Tsivilis, Normal, F distribution increased by 5-10 MPa and 1-2 MPa, respectively, compared to the reference sample at 28 d. The pore structure of the concrete was improved, in which the total porosity of concrete decreased by 2-5% at 28 d. With regarding to the fly ash with Andersen distribution, it was however not conducive to the strength development of concrete. Regression model based on the grey multiple linear regression theory was proved to be efficient to predict the strength of concrete, according to the characteristic parameters of particle size and pore structure of the fly ash.

Characteristics of Porous Titanium Fabricated by Space-holder Method using NaCl (NaCl을 Space holder로 이용한 타이타늄 다공체의 특성)

  • Son, Byoung-Hwi;Hong, Jae-Geun;Hyun, Yong-Taek;Kim, Seung-Eon;Bae, Seok-Choun
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.488-495
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    • 2011
  • This study was performed to fabricate the porous titanium foam by space holder method using NaCl powder, and to evaluate the effect of NaCl volume fractions (33.3~66.6 vol.%) on the porosities, compressive strength, Young's modulus and permeability. For controlling pore size, CP titanium and NaCl particles were sieved to different size range of 70~150 ${\mu}m$ and 300~425 ${\mu}m$ respectively. NaCl of green Ti compact was removed in water followed by sintered at $1200^{\circ}C$ for 2 hours. Total porosities of titanium foam were in the range of 38-70%. Pore shape was a regular hexahedron similar that of NaCl shape. Porous Ti body showed that Young's modulus and compressive strength were in the range of 0.6-6 GPa and 8-127 MPa respectively. It showed that pore size and mechanical properties of Ti foams was controllable by NaCl size and volume fractions.

Effect of Reuse of Onggi Containers on the Quality of Anchovy Soy Sauce (옹기의 재 사용이 어간장의 품질에 미치는 영향)

  • Chung, Sun-Kyung;Choi, Dong-Man;Joung, Yong-Myeon;Shin, Dong-Ju
    • Food Science and Preservation
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    • v.17 no.2
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    • pp.223-229
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    • 2010
  • Anchovy soy sauce was fermented at ambient temperature in 20 L new Onggi, used Onggi, stainless steel, and plastic containers, and sauce quality was analyzed. Microporous insulated Onggi containers were found to promote fermentative microbial growth, thus creating desirable conditions for the preparation of good-quality anchovy soy sauce. The use of used Onggi containers yielded an anchovy soy sauce with high contents of total nitrogen and free amino acids, which afforded good sensory qualities with respect to odor, taste, and overall acceptability.

Synchrotron X-ray Reflectivity Studies on Nanoporous Low Dielectric Constant Organosilicate Thin Films

  • Oh, Weon-Tae;Park, Yeong-Do;Hwang, Yong-Taek;Ree, Moon-Hor
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2481-2485
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    • 2007
  • Spatially resolved, quantitative, non-destructive analysis using synchrotron x-ray reflectivity (XR) with subnano-scale resolution was successfully performed on the nanoporous organosilicate thin films for low dielectric applications. The structural information of porous thin films, which were prepared with polymethylsilsesquioxane and thermally labile 4-armed, star-shaped poly(ε-caprolactone) (PCL) composites, were characterized in terms of the laterally averaged electron density profile along with a film thickness as well as a total thickness. The thermal process used in this work caused to efficiently undergo sacrificial thermal degradation, generating closed nanopores in the film. The resultant nanoporous films became homogeneous, well-defined structure with a thin skin layer and low surface roughness. The average electron density of the calcined film reduced with increase of the initial porogen loading, and finally leaded to corresponding porosity ranged from 0 to 22.8% over the porogen loading range of 0-30 wt%. In addition to XR analysis, the surface and the inner structures of films are investigated and discussed with atomic force and scanning electron microscopy images.

Pore Structure Changes in Hardened Cement Paste Exposed to Elevated Temperature (고온 환경에 노출된 시멘트 경화체의 공극 구조 변화)

  • Kang, Seung-Min;Na, Seung-Hyun;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.48-55
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    • 2015
  • Hardened cement-based materials exposed to the high temperatures of a fire are known to experience change in the pore structure as well as microstructural changes that affect their mechanical properties and tend to reduce their durability. In this experimental investigation, hardened Portland cement pastes were exposed to elevated temperatures of 200, 400, 600, 800, and $1000^{\circ}C$ for 60 minutes, and the resulting damage was studied by thermogravimetry (TG), mercury intrusion porosimetry (MIP) and density measurements. These results revealed that the residual compressive strength is increased at temperatures greater than $400^{\circ}C$ due to a small pore size of 3 nm and/or rehydration of the dehydrated cement paste. However, a loss of the residual strength occurs at temperatures exceeding 500 and $600^{\circ}C$. This can be attributed to the decomposition of hydrates such as portlandite and to an increase in the total porosity.

Morphology control in PVDF membranes using PEG/PVP additives and mixed solvents

  • Rajabi, Shima;Khodadadi, Foroogh;Mohammadi, Toraj;Tavakolmoghadam, Maryam;Rekabdar, Fatemeh
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.237-245
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    • 2020
  • The effects of the mixed two solvents, Dimethylacetamide (DMAc) and Dimethylformamide (DMF), and Polyethylene glycol (PEG) and Polyvinylpyrrolidone (PVP) as additives on performance of Polyvinylidene fluoride (PVDF) membranes were studied. Initially, PEG200 was used as a primary additive at fixed percentage of 5% wt. PVP was then blended with PEG200 in different concentrations. PVDF and DMAc were used as polymer and solvent in the casting solutions, respectively. To control the diffusion rate of PVP in the presence of PEG200 and PVP blend, mixtures of DMAc and DMF were used as the mixed solvent in the casting solutions. Asymmetric PVDF membranes were prepared via phase inversion process in a water bath and the effects of two additives and two solvents on the membrane morphology, pure water flux (PWF), hydrophilicity and rejection (R) were investigated. Attenuated Total Reflection Fourier Transform Infrared Spectra (ATR-FTIR) analysis was used to show the residual PVP on the surface of the membranes. Atomic Force Microscopy (AFM) was utilized to determine roughness of membrane surface. The use of mixed solvents in the casting solution resulted in reduction of PVP diffusion rate and increment of PEG diffusion rate. Eventually, PWF and R values reduced, while porosity and hydrophilicity increased.

Physical Properties of Polymer Composite Recycling Recycled Aggregate (순환골재를 재활용한 폴리머 복합재료의 물성)

  • Hwang, Eui-Hwan;Jeon, Jong-Ki
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.67-74
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    • 2009
  • Nowadays, recycling of recycled aggregates from the waste concrete is seriously demanded for the protection of environment and the shortage of aggregates owing to the large scale construction project. In this study, for the development of polymer composite recycling recycled aggregates from the waste concrete, twenty five specimens of the polymer composite were prepared with the five levels of replacement ratios of recycled aggregates (0, 25, 50, 75, 100%) and polymer-cement ratios (0,5, 10, 15, 20%), respectively. For the evaluation of the performance of polymer composite specimens, various physical properties such as compressive and flexural strengths, water absorption, hot water resistance, total pore volume and porosity were investigated. As a result, physical properties of polymer composite were remarkably improved with an increase of polymer cement ratios, but greatly decreased with the replacement ratios of recycled aggregates.

Electromagnetic Interference Shielding Properties of CO2 Activated Carbon Black Filled Polymer Coating Materials

  • Hu, Quanli;Kim, Myung-Soo
    • Carbon letters
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    • v.9 no.4
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    • pp.298-302
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    • 2008
  • Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.