• 제목/요약/키워드: Total phosphorus

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Phosphorus Removal in Pilot Plant Using Biofilm Filter Process from Farm Wastewater

  • Shin, Sung-Euy;Choi, Du-Bok;Lee, Choon-Boem;Cha, Wol-Suk
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제11권4호
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    • pp.325-331
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    • 2006
  • Various environmental conditions affecting total phosphorus removal from farm wastewater in a biofilm filter process were investigated using loess balls and Chromobacterium LEE-38 at a pilot plant. When Chromobacterium LEE-38 was used, the removal efficiency of total phosphorous was approximately 10- or 5-fold higher than that of Acinetobacter CHA-2-14 or Acinetobacter CHA-4-5, respectively. When a loess ball of $11{\sim}14mm$ manufactured at a $960^{\circ}C$ calcining temperature was used, the removal efficiency of total phosphorous was 90.0%. When 70% of the volume fraction was used, the maximum efficiency of total phosphorus removal was 93.1%. Notably, when the initial pH was in the range of 6.0 to 8.0, the maximum removal efficiency of total phosphorus was obtained after 30 days. When the operating temperature was in the range of 30 to $55^{\circ}C$, the maximum removal efficiencies of total phosphorus, 95.6 to 94.6%, were obtained. On the other hand, at operating temperatures below $20^{\circ}C$ or above $40^{\circ}C$, the removal efficiency of total phosphorous decreased. Among the various processes, biofilm filter process A gave the highest removal efficiency of 96.4%. Pilot tests of total phosphorus removal using farm wastewater from the biofilm filter process A were carried out for 60 days under optimal conditions. When Acinetobacter sp. Lee-11 was used, the average removal efficiency in the p-adsorption area was only 32.5%, and the removal efficiencies of chemical oxygen demand (COD) and biological oxygen demand (BOD) were 56.7 and 62.5%, respectively. On the other hand, when Chromobacterium LEE-38 was used, the average removal efficiency was 95.1%, and the removal efficiencies of COD and BOD were 91.3 and 93.2%, respectively.

낙동강 주요 지천의 인 및 질소부하량에 관한 연구 (Phosphorus and nitrogen loading from the main tributaries into the Nakdong River)

  • 허우명;김범철
    • 한국환경과학회지
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    • 제4권3호
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    • pp.187-196
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    • 1995
  • Phosphorus and nitrogen loadings from the main tributaries into the Nakdong River were estimated by measuring phosphorus and nitrogen concentration in the main tributaries, Nakdong River(Kangjung), Kumho River, Heichun, Hwang River, Nam River, Milyang River, and Yangsanchun from May 1994 to October. Total Phosphorus concenuation of Kumho River was vary high, average 1.0 mgP/1. The other rivers were the range 0.05 ~0.15 mgP/1. Total nitrogen concentration of Kumho River was vary high, average 6.27 mgN/1. The other rivers were the range 1.5~3.0 mgN/l. The phosphorus loading from Kumho River, Nakdong River(Kangjung), Nam River, Milyang River, Hwang River, Yangsanchun, and Heichun were calculated to be 1, 108, 603, 198, 57, 34, 23, and 21 tP/yr, respectively. Therefore, the loading from Kumho River accounted for 45 "yo of total loading, 2, 042 tP/yr, The nitrogen loading from Nakdong River (Kangjung), Kumho River, Nam River, Milyang River, Hwang River, Heichun, and Yangsanchun were calculated to be 12, 636, 7, 411, 2, 611, 1, 523, 779, 608, and 391 tN/yr, respectively. Therefore, the loading from Nakdong River(Kangiung) and Kumho River accounted for 50 % and 30% of total loading, 25, 959 tN/yr, respectively.vely.

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고농도(高農度) 인산(燐酸) 수경액(水耕液)중에서 뽕나무의 Zn과 Cu 흡수(吸收) (Effects of High Phosphorus Supply on Zn and Cu Uptake by Mulberry(Morus alba L.))

  • 이완주;최영철
    • 한국토양비료학회지
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    • 제26권4호
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    • pp.249-252
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    • 1993
  • 인산(燐酸)을 고농도(高濃度)로 공급하였을 때, 양분의 흡수(吸收) 특히 Zn과 Cu의 흡수를 알기 위하여 온실에서 수경재배(水耕栽培)로 시험을 수행하였다. 공급 인산 수준은 0, 0.2, 0.5, 2.0, 5.0mM의 5수준(水準)이었으며, 개량뽕(Morus alva L.)을 공시품종으로 2.5개월을 재배한 후, 식물체를 수확(收穫)하여 분석(分析)하였다. 건물중(乾物重)은 2.0mM 인산수준까지 계속 증가(增加)한 후 감소(減少)하였다. 잎의 수분함량(水分含量), total-N, P, K, Fe 등은 인산 공급수준과 비례(比例)하여 증가하였다. Total-Zn 함량은 인산수준에 따라 큰 차를 보이지 않았으나, 수용성(水溶性) Zn은 증가하는 반면 Cu는 감소하였다. 인산수준(燐酸水準)의 증가에 따라 $SO_4$와 Cl는 감소하다가 인산 2.0mM 이상에서 현저히 증가하였다. 인산 축적(蓄積) 뽕밭에서의 뽕잎 감소는 Cu의 흡수 저하와 $SO_4$와 Cl의 현저할 흡수(吸收) 증가에서 오는 것으로 추정(推定)되었다.

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호수(湖水)의 부영양화(富營養化) 예측(豫測)을 위(爲)한 적정(適正) 총린(總燐) 모형(模型)의 선정(選定) 기준(基準)에 관(關)한 연구(硏究)(II) (Selection Criteria of Optimal Total Phosphorus Models for Lake Eutrophication Predictions(II))

  • 서동일
    • 상하수도학회지
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    • 제8권1호
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    • pp.9-17
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    • 1994
  • The study of lake pollution problems is often related to the dynamic behavior of phosphorus. Several phosphorus models are available that may be suitable to study these problems. Depending on the the management objectives and data availability, some models may be more appropriate than others. Criteria are defined to help modelers choose the most appropriate total phosphorus models for different lakes. These criteria consider in-lake processes such as sediment feedback, stratification, and algal uptake and recycle.

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총 인 분석을 위한 자동 전처리 시스템 (Automated On-Line Digestion System for the Determination of Total Phosphorus)

  • 정형근;조영일;김범식;박주형
    • 한국환경과학회지
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    • 제10권1호
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    • pp.13-19
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    • 2001
  • An on-line digestion system based on the flow injection analysis technique was presented for the determination of total phosphorus. The system converts condensed and organic phosphoruses into orthophosphate that can be analyzed spectrophotometically. The reaction between orthophosphate and ammonium molybdate in a strong acid medium forms the yellow complex of phosphomolybdate which is next reduced to a molybdic blue complex by stannous chloride. The quantitation of orthophosphate is based on the absorbance of the molybdic blue. To determine total phosphorus, the digestion system was installed between the sample injector and the reaction coil with the added lines of digestion solution(potassium persulfate+sulfuric acid) and the $H_2O$ carrier. The system has shown that the digestion efficiencies were greater than 95% for the typical condensed and organic phosphoruses. When tripolyphosphate standards were used, the calibration data showed that the linear dynamic range extended to a concentration of 1.5ppm with the detection limit of 25ppb total phosphorus. The typical relative standard deviation was less than 2%. The proposed system was successfully applied to lake water, wastewater, and streamwater. The analytical variables such as digestion efficiency, analysis time, and reproducibility were evaluated and compared with the manual digestion method.

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Serial Particle Size Fractionation and Water Quality in a Recirculating Aquaculture System for Eel

  • Lee, Jin-Hwan
    • Fisheries and Aquatic Sciences
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    • 제13권2호
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    • pp.133-139
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    • 2010
  • The effects of suspended solids size on culture water quality were determined in a commercial recirculating aquaculture system (RAS) for Japanese eel, Anguilla japonica. The particulate phase of the culture water was serially divided into six size fractions using 300, 200, 100, 75, 45, and 26 ${\mu}m$ pore size stainless sieves. The total, dissolved, and particulate nitrogen and phosphorus, and suspended solids for each fraction were determined. The concentration ranges in the fractions were: total nitrogen, 164-148 mg $L^{-1}$; total phosphorus, 20.4-15.5 mg $L^{-1}$; and total suspended solids, 8.1-6.1 mg $L^{-1}$. The concentration of total nitrogen and total phosphorus decreased significantly (P<0.05) with a 26 ${\mu}m$ and 200 ${\mu}m$ filter pore size, respectively. Nutrients from dissolved organic substances were much higher than from particulates. Analysis of particle size fractionation and its effects on water quality is useful to estimate removal efficiencies of a commercial effluent screening device for solid management and development of solid removal systems.

A/O 및 A2/O공정의 생물학적 인제거 특성비교 (Comparison of Biological Phosphorus Removal Characteristics between A/O and A2/O Process)

  • 김광수;서규태;이경호;김낙주
    • 한국물환경학회지
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    • 제18권2호
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    • pp.123-130
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    • 2002
  • Bench scale experiments were carried out with two biological nutrient removal(BNR) units, A/O and $A^2O$ processes, to investigate the behavior of phosphorus in the system and to compare the characteristics of phosphorus removal in two BNR processes. To achieve this goal, COD/T-P and COD/TKN ratios of the influent was varied in the range of 23~64 and 5~24, respectively. In A/O process, influent COD/T-P ratio should be kept higher than 44mg/L to meet the final effluent T-P concentration lower than 1mg/L and in $A^2/O$ process, influent COD/T-P and COD/TKN ratios higher than 56 and 10, respectively, were required for good phosphorus release and uptake with no influence of nitrate nitrogen in return sludge. At this conditions, the rate of phosphorus release in the anaerobic basin should be kept higher than 0.1 kg S-P/kg MLVSS d In A/O process, the phosphorus content of anaerobic and aerobic sludges was increased as SRT of total system was becoming longer resulting in decreasing the difference of phosphorus content between two sludges while phosphorus release in anaerobic basin and phosphorus uptake in aerobic basin was not incident. In $A^2/O$ process, the phosphorus content of anaerobic and aerobic sludges were not increased with higher SRT of total system due to the relatively high nitrate concentration in return sludge. However, the difference of phosphorus content between anaerobic and aerobic sludges was incident when phosphorus release and uptake was observed.

대기 $CO_2$ 상승시 인산공급이 식물체의 광합성 및 질소고정에 미치는 영향 (Effect of Phosphorus Stress on Photosynthesis and Nitrogen Fixation of Soybean Plant under $CO_2$ Enrichment)

  • 사동민
    • Applied Biological Chemistry
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    • 제40권2호
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    • pp.134-138
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    • 1997
  • 대기 $CO_2$ 상승시 인산공급이 대두식물체의 광합성 및 질소고정에 미치는 영향을 살펴보고저 Bradyrhizobium japonicum MN110을 접종한 대두 식물체를 인산결핍구(0.05 m-P) 및 대조구(1.0 mM-P)를 처리하여 정상 $CO_2(400\;{\mu}l/L)$와 상승 $CO_2(800\;{\mu}l/L)$의 조건인 phytotron에서 35일 동안 재배하였다. 인산결핍은 건물량을 정상 $CO_2$ 처리시 51%, 상승 $CO_2$ 처리시 64%를 감소시켰고 총 엽면적도 유의성있게 감소시켰으나 specific leaf weight는 증가시켰다. 광합성 속도 및 잎내부의 $CO_2$농도는 인산결집구에서 감소하였고 그 정도는 $CO_2$ 상승처리시 더욱 컸으며 질소고정능과 근류생체량도 인산결핍시 감소하였으나 잎의 질소농도는 인산대조구가 30% 감소하였다. 이러한 결과는 $CO_2$ 상승조건에서도 인산이 결핍될 경우 식물생육을 촉진시키지 못하며 인산은 정상 $CO_2$ 농도시 보다 $CO_2$ 상승조건에서 근류의 성장과 작용에 더욱 중요한 역할을 하는것으로 유추된다.

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토양의 총인산과 유효인산함량을 측정하기 위한 근적외 기술의 이용 (Use of NIR Technique for Determination of Total Phosphorus and Available Phosphorus in Korean Soils)

  • 유관식;박진숙
    • 한국토양비료학회지
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    • 제41권1호
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    • pp.50-54
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    • 2008
  • 근적외선스펙트로메타는 토양의 성분을 측정하는 새로운 기술로 발전하고 있다. 작물이 요구하는 토양의 인산 함량을 측정하는 데는 시간이 많이 소요되며, 침출액과 침출조건에 따라서 다르기 때문에 어려운 성분이다. 그러나 근적외선 방법을 이용하여 표준곡선을 정확하게만 만들어, 표준곡선 작성 시 Wiliams의 상관계수안내를 이용하면 상관계수의 수치에 따라서 토양의 총인산과 유효인산을 측정하는데 간편하게 이용할 수 있다. 또한 근적외 기술은 정밀도를 향상하면 포장 현지에서의 토양검정에도 쉽게 이용할 수 있는 쉬운 기술로 생각된다.

인산결핍이 대두근류의 bacteroid 함량과 energy 상태에 미치는 영향 (The effect of phosphorus stress on the energy status and bacteroid content in soybean nodules)

  • 사동민;임선욱
    • Applied Biological Chemistry
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    • 제35권6호
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    • pp.449-456
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    • 1992
  • 인산처리가 근류의 bacteroid 함량과 energy 상태에 미치는 영향을 살펴보기 위하여 Bradyrhizobium japonicum MN10을 접종한 대두식물(Glycine max [L.] Merr.)에 저해농도(0.05 mM-P)와 정상농도(1.0 mM-P)를 처리하여 온실에서 재배하였다. 인산결핍은 식물체의 근류량과 근류량 식물체량의 비에 유의성있는 감소를 보였다. 잎, 줄기, 뿌리의 인산농도는 인산결핍에 의하여 75%가 감소하였으나 근류의 인산농도는 40%만 감소하였다. 근류의 bacteroid 함량과 근류에서 전인산, 전질소의 bacteroid와 식물세포로의 분배는 인산결핍의 영향을 받지 않았으며 전질소의 22%, 전인산의 27%가 bacteroid에 존재하였다. 근류의 ATP농도, 전 adenylate 농도와 energy charge는 인산결핍에 의하여 각각 77%, 46%, 37%가 감소되었다. 인산결핍은 근류내 식물세포의 ATP 농도와 energy charge를 각각 86%, 59%를 감소시켰으나 bacteroid의 ATP농도와 energy charge에는 영향을 미치지 않았다. 이러한 결과는 근류가 인산의 강한 보유원이며, 기주식물에 대한 인산결핍조건하에서 bacteroid는 정상적인 인산 농도와 energy양을 함유한다는 것을 나타낸다.

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