• Title/Summary/Keyword: Total hydrocarbon

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Potential Utilization of Concentrated Oyster Cooker Effluent for Seafood Flavoring Agent (수산식품 조미제 개발을 위한 굴 자숙 농축액의 이용)

  • KIM Jeong Han
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.33 no.1
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    • pp.79-85
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    • 2000
  • Proximate composition of concentrated oyster cooker effluent (COCE) was $70{\%}$ moisture, $8.55{\%}$ total nitrogen, and $18.6{\%}$ ash. Optimum conditions for enzymatic hydrolysis of COCE ($200 ml$) weve $pH 7.0{\~}7.5\;and 50{\~}60{\circ}C$ for 8 h reaction time with 0.128 U of Aspergillus oryzae PE protease(AOP), Hydrolysis of COCE led to an increase in free amino acids to 1.41 fold, with taurine comprising about $17.62{\%}$ of the total free amino acid. Fifty volatile flavor components were identified in COCE and 63 in enzyme treated COCE (HCOCE). Volatile flayer compounds we increased significantly in HCOCE when compared with untreated COCE. Results of this study might help to alleviate the current wastewater disposal problem caused by oyster cooker effluent.

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Effect of the Intake Valve Opening Timings and Fuel Injection Pressures on the Exhaust Emission Characteristics of a Gasoline Engine at Part Load Condition

  • Lee, Hyung-Min;Jeong, Yeon-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.3
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    • pp.317-322
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    • 2011
  • This work has investigated the exhaust emissions such as Total Hydrocarbon (THC), Nitrogen Oxides(NOx), and Particulate Matter (PM) characteristics emitted from the tail-pipe of a continuously variable valve timing (CVVT) gasoline-fueled engine with different intake valve opening timings and injection pressures at the part load condition. Valve overlap period was varied from $40^{\circ}CA$ to $10^{\circ}CA$ and fuel injection pressure was increased from 3.5 bar to 5.0 bar. THC and NOx emissions decreased as intake valve opening timing was advanced regardless of fuel injection pressure. When the fuel was injected with the condition of 5.0 bar at all of valve overlap ranges, THC levels were reduced by 55%. NOx concentrations were diminished about 75% as valve overlap increased. PM size distributions were analyzed as bi-modal type of the nucleation and accumulation mode. Comparing with fuel injection pressures, PM emission levels were decreased at high pressure injection of 5.0 bar condition.

A Case Study on the Measurement Volatile Organic Compounds and Total Hydrocarbon Concentrations in Block Paint-Shops at a Shipyard (조선소 블록 도장시설에서의 휘발성 유기화합물과 총 탄화수소 농도측정 사례)

  • Yang, Sung-Bong;Yu, Mee Seon;Woo, Kyung-Bin
    • Journal of Environmental Science International
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    • v.25 no.8
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    • pp.1177-1189
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    • 2016
  • In order to prepare the information needed to construct a reduction system for volatile organic compounds (VOCs) exhausted from ship-block paint-booths in a giant shipyard, VOCs in paint-shop airs were analyzed and compared to the components in paint thinners. Aromatic hydrocarbons containing eight and nine carbon atoms are known to be major VOC compounds found in shipyard paint-shops. The total hydrocarbon (THC(C7)) concentrations calibrated using toluene gas, were measured in block paint-shops with two photo-ionization detector (PID) meters, and the resulting THC(C7) data were converted to THC(C1) concentrations according to the Standard Methods for the Measurements of Air Pollution in South Korea. THC(C1) concentrations near the spray site ranged from 10 to 2,000 ppm, but they were less than 400 ppm near the walls of the paint-booth. The measurements of THC concentrations, based on the height of the monitoring sites, were related to the height of the target to which the spray paints were applied. The maximum concentrations occurred at almost the same height as the spray targets. When painted blocks had been dried-by warming with no spraying, the THC concentrations were 80~100 ppm.

Comparative Study of Rhizobacterial Community Structure of Plant Species in Oil-Contaminated Soil

  • Lee, Eun-Hee;Cho, Kyong-Suk;Kim, Jai-Soo
    • Journal of Microbiology and Biotechnology
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    • v.20 no.9
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    • pp.1339-1347
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    • 2010
  • In this study, the identity and distribution of plants and the structure of their associated rhizobacterial communities were examined in an oil-contaminated site. The number of plant species that formed a community or were scattered was 24. The species living in soil highly contaminated with total petroleum hydrocarbon (TPH) (9,000-4,5000 mg/g-soil) were Cynodon dactylon, Persicaria lapathifolia, and Calystegia soldanella (a halophytic species). Among the 24 plant species, the following have been known to be effective for oil removal: C. dactylon, Digitaria sanguinalis, and Cyperus orthostachyus. Denaturing gradient gel electrophoresis (DGGE) profile analysis showed that the following pairs of plant species had highly similar (above 70%) rhizobacterial community structures: Artemisia princeps and Hemistepta lyrata; C. dactylon and P. lapathifolia; Carex kobomugi and Cardamine flexuosa; and Equisetum arvense and D. sanguinalis. The major groups of rhizobacteria were Beta-proteobacteria, Gamma-proteobacteria, Chloroflexi, Actinobacteria, and unknown. Based on DGGE analysis, P. lapathifolia, found for the first time in this study growing in the presence of high TPH, may be a good species for phytoremediation of oil-contaminated soils and in particular, C. soldanella may be useful for soils with high TPH and salt concentrations. Overall, this study suggests that the plant roots, regardless of plant species, may have a similar influence on the bacterial community structure in oil-contaminated soil.

Feasibility study on remediation for railway contaminated soil with waste-lubricant (윤활유 유래 철도오염 토양의 정화 타당성 연구)

  • Baek, Ki-Tae;Shin, Min-Chul;Park, Sung-Woo;Ryu, Byung-Gon;Lee, Jae-Young
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.1229-1235
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    • 2007
  • Railway-contaminated soil is categorized by total petroleum hydrocarbon(TPH)-related contamination and heavy-metal contamination. The sources of TPH are diesel and lubricant. In this study, the feasibility of soil washing, chemical oxidation and ultra-sonication were investigated to treat lubricant-contaminated railway soil. tergitol, a non-ionic surfactant, was investigated as a washing agent. However, it is not effective to remove lubricant from soil even though tergitol is most effective washing agent for diesel-contaminated soil. Addition of alcohols with surfactant enhanced slightly washing efficiency of the lubricant-contaminated soil. To remediate railway-contaminated soil, source of pollution should be considered.

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The Study of Crude Oil Contaminated Soil Remediation by Indirect Thermal Desorption (간접열탈착방식을 이용한 원유오염토양 정화효율 평가)

  • Lee, In;Kim, Jong-Sung;Jung, Tae-Yang;Oh, Seung-Taek;Kim, Guk-Jin
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.14-20
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    • 2016
  • Remediation of crude oil contaminated soil is complicate and hard to apply traditional methods because of its persistency, durability, and high viscosity. Therefore, in this study, the efficiency of crude oil contaminated soil remediation was tested by developing a pilot-scale thermal desorption system using the indirect heating method with an exhaust gas treatment. Under optimal condition drawed by temperature and retention time, the remedial efficiency of crude oil contaminated soil and treatability of exhaust gas were analyzed. Total Petroleum Hydrocarbon (TPH) concentration of crude oil contaminated soil was decreased to 69.7 mg/kg on average and the remedial efficiency was measured at 99.60%. Through the exhaust gas, 86.0% of Volatile Organic Compounds (VOC) was degraded and 97.16% of complex malodor was reduced under the suggested optimum operation condition. This study provides important basic data to be useful in scaling up of the indirect thermal desorption system for the remediation of crude oil contaminated soil.

A Study of a Combined Microwave and Thermal Desorption Process for Contaminated Soil

  • Ha, Sang-An;Choi, Kyoung-Sik
    • Environmental Engineering Research
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    • v.15 no.4
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    • pp.225-230
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    • 2010
  • In order to treat soil contaminated with high percentages of water and petroleum, the combined microwave and thermal desorption process was studied, which was composed of the consecutive connection of two pre-treatment processes. For the thickness of the contaminated soil layer on the transfer conveyor belt, the optimal total petroleum hydrocarbon (TPH) removal rate was studied with respect to the duration of microwave exposure in the consecutive process combined with thermal desorption. The TPH removal rate when the contaminated soil layer thickness was 1 cm at 6 kW of microwave power was 80%. The removals rates for 2 and 3 cm soil layer thicknesses were both 70%. Under identical experimental conditions, the TPH removal rate for the microwave pre-treatment, when considering the soil particle size, was over 70%. The lowest TPH removal rate was achieved with a particle diameter of 2.35 mm. For contaminated soil with 30% water content, 6 kW and a thermal desorption temperature of $600^{\circ}C$ were the optimal operational conditions for the removal of THP. However, considering the fuel consumption cost, 4 kW and a thermal desorption temperature of $300^{\circ}C$ would be the most economic conditions.

Atmospheric Behaviors of Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in East Asia

  • Hayakawa, Kazuichi;Tang, Ning;Kameda, Takayuki;Toriba, Akira
    • Asian Journal of Atmospheric Environment
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    • v.1 no.1
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    • pp.19-27
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    • 2007
  • Hazardous polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) are mainly originated from imperfect combustion of fossil fuels such as petroleum and coal. The consumptions of not only petroleum but also coal have been increasing in the East Asian countries. This review describes the result of international collaboration research concerning characteristics and major contributors of atmospheric PAHs and NPAHs in cities in Japan, Korea, China and Russia. We collected airborne particulates in ten cities in the above countries and six PAHs and eleven NPAHs were determined by HPLC methods using fluorescence and chemiluminescence detections. The total PAH concentrations were much higher in Chinese cities (Fushun, Tieling, Shenyang and Beijing) than those in other cities (Vladivostok, Busan, Kanazawa, Kitakyushu, Sapporo and Tokyo). The total NPAH concentrations were also higher in Chinese cities than those in the other cities. The [NPAH]/[corresponding PAH] ratios are much larger in diesel-engine exhaust particulates than those in coal-burning particulates. The [1-nitropyrene]/[pyrene] ratio of airborne particulates was much smaller in the four Chinese cities, suggesting that coal combustion systems such as coal heaters were the main contributors. On the other hand, the ratios were larger in Korean and Japanese cities, suggesting the large contribution of diesel-engine vehicles.

Potential of gas generation and natural gas hydrate formation in the near seafloor sediment of the Ulleung Basin (울릉분지 천부 퇴적층에서의 가스 생성과 천연가스 하이드레이트 형성 잠재력)

  • Ryu, Byong-Jae;Lee, Young-Joo;Kim, Ji-Hoon;Kim, Il-Soo;Park, Myong-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.419-423
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    • 2006
  • Basic studies on natural gas hydrates in the East Sea were been carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM) from 2000 to 2004 involving 2D multichannel seismic lines and piston coring. 27 piston cores recovered from the deed-water Ulleung Basin of the East Sea were analyzed in this study. In piston cores cracks generally developed parallel to bedding suggest significant gas content. The core analyses showed high total organic carbon (TOC) content, sedimentation rate and heat flow of sediments. The cores recovered from the southern study area show also high residual hydrocarbon gas concentrations for the formation of natural gas hydrates. This study indicates that there is the potential for the generation of biogenic gas and the formation of natural gas hydrates in the near seafloor sediments of the study area.

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Geochemical and Geophysical Characteristics of Shallow Gases in the Deep Sea Sediments, Southwestern Ulleung Basin (울릉분지 남서부 심해저 퇴적층에 분포하는 천부 가스의 지화학 및 지구물리 특성)

  • 김일수;이영주;유동근;류병재
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.149-157
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    • 2003
  • Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.